Advanced Test Reactor Research Articles

Observed Changes in As-Fabricated U-10Mo Monolithic Fuel Microstructures After Irradiation in the Advanced Test Reactor

A low-enriched uranium U-10Mo monolithic nuclear fuel is being developed by the Material Management and Minimization Program, earlier known as the Reduced Enrichment for Research and Test Reactors Program, for utilization in research and test reactors around the world that currently use high-enriched uranium fuels. As part of this program, reactor experiments are being performed in the Advanced Test Reactor. It must be demonstrated that this fuel type exhibits mechanical integrity, geometric stability, and predictable behavior to high powers and high fission densities in order for it to be a viable fuel for qualification. This paper provides an overview of the microstructures observed at different regions of interest in fuel plates before and after irradiation for fuel samples that have been tested. These fuel plates were fabricated using laboratory-scale fabrication methods. Observations regarding how microstructural changes during irradiation may impact fuel performance are discussed.

Post-Irradiation Non-Destructive Analyses of the AFIP-7 Experiment

This article reports the results and interpretation of post-irradiation non-destructive examinations performed on four curved full-size fuel plates that comprise the AFIP-7 experiment. These fuel plates, having a U-10 wt.%Mo monolithic design, were irradiated under moderate operating conditions in the Advanced Test Reactor to assess fuel performance for geometries that are prototypic of research reactor fuel assemblies. Non-destructive examinations include visual examination, neutron radiography, profilometry, and precision gamma scanning. This article evaluates the qualitative and quantitative data taken for each plate, compares corresponding data sets, and presents the results of swelling analyses. These characterization results demonstrate that the fuel meets established irradiation performance requirements for mechanical integrity, geometric stability, and stable and predictable behavior.

Extension of the Advanced Test Reactor Operating Envelope Via Enhanced Reactor Physics Validation Techniques

The Korea Atomic Energy Research Institute is currently in the process of qualifying a low-enriched-uranium fuel element design for the new Ki-Jang Research Reactor (KJRR). As part of this effort, a prototype KJRR fuel element was irradiated for several operating cycles in the northeast flux trap of the Advanced Test Reactor (ATR) at the Idaho National Laboratory. The KJRR fuel element contained a very large quantity of fissile material (618 g 235U) in comparison with historical ATR experiment standards (<1 g 235U), and its presence in the ATR flux trap was expected to create a neutronic configuration that would be well outside of the approved validation envelope for the reactor physics analysis methods used to support ATR operations.Accordingly, it was necessary to conduct an extensive set of new low-power physics measurements in the ATR Critical Facility (ATRC), a companion facility to the ATR, located in an immediately adjacent building and sharing the same fuel storage canal. The new measurements included fission power distributions, reactivity, and measurements related to the calibration of the in-core online instrumentation. The effort was focused on the objective of expanding the validation envelope for the computational reactor physics tools used to support ATR operations and safety analysis to include the planned KJRR irradiation in the ATR and similar experiments that are anticipated in the future.The computational and experimental results have demonstrated that the neutronic behavior of the KJRR fuel element in the ATRC is well understood in terms of its general effects on ATRC core reactivity and fission power distributions and its effects on the calibration of the ATR Lobe Power Calculation and Indication System, as well as in terms of its own internal fission rate distribution and total fission power per unit ATRC core power. Taken as a whole, these results have significantly extended the ATR physics validation envelope, thereby enabling an entire new class of irradiation experiments.

Evaluation of Corrosion in YA-Type ATR Fuel Element During Reactor PALM Cycle 153B

Two types of flow-assisted corrosion were observed at advanced test reactor (ATR) during PALM Cycle 153B-1 (April 2013): pitting corrosion and flow-assisted erosion corrosion. In this paper, a description of the corrosion is provided along with the results of thermodynamic, kinetic, neutronic, and thermohydraulic modeling. Together, these results provide a plausible explanation and means of corrosion remediation in the future. Cycle 153B-1 was a typical operating cycle for the ATR and did not result in any unusual plant transients. However, when the fuel elements were removed from the core and inspected, several thousand flow-assisted corrosion pits and “horseshoeing” defects (erosion corrosion) were readily observed on the surface of the several YA-type fuel elements. A thermohydraulic model of coolant in channel 20 (near a YA fuel element and the Be neutron reflector) was generated and helped to establish that the horizontal saw cuts in the Be neutron reflector had a significant effect on the temperature of the coolant. Horizontal cuts in the beryllium reflector block were created to arrest the propagation of large vertical crack(s) in Be. The flow was turbulent, rather than varying linearly with gradual heating of the coolant as it passed through the channel. The temperature rise was represented by a series of “humps,” which occurred at each horizontal saw cut in the beryllium reflector block. Each of the 13 saw cuts had a chamfered edge which resulted in the coolant flow being redirected as a jet across the coolant channel into the surface of the EE (i.e., a plate without nuclear fuel) plate. This explained the temperature rise and the observed scalloping and pitting degradation on the YA-M fuel elements. In the case of scalloping (horseshoeing), a surprising similarity of this defect to those appearing on aluminum plates rolled in overlubrication conditions was established. The neutronics data for modeling were provided using advanced irradiation simulations (MCNP, HELIOS). The following corrective measures were proposed based upon the results of JMatPro v.8.2 modeling (TTT and CCT diagrams): change the fabrication process by adding blister anneal before program anneal immediately after cold rolling of AA6061 plate. This step allows achieving complete recrystallization and eliminates strengthening due to metastable precipitates.

Thermal Predictions of the AGR-3/4 Experiment With Post Irradiation Examination Measured Time-Varying Gas Gaps

A thermal analysis was performed for the advanced gas reactor test experiment (AGR-3/4) with post irradiation examination (PIE) measured time (fast neutron fluence) varying gas gaps. The experiment was irradiated at the advanced test reactor (ATR) at the Idaho National Laboratory (INL). Several fuel irradiation experiments are planned for the AGR Fuel Development and Qualification Program, which supports the development of the very high-temperature gas-cooled reactor under the advanced reactor technologies project. The AGR-3/4 test was designed primarily to assess fission product transport through various graphite materials. Irradiation in the ATR started in December 2011 and finished in April 2014. Forty-eight (48) tristructural-isotropic-fueled compacts were inserted into 12 separate capsules for the experiment. The purpose of this analysis was to calculate the temperatures of each compact and graphite layer to obtain daily average temperatures using PIE-measured time (fast neutron fluence) varying gas gaps and compare with experimentally measured thermocouple (TC) data. PIE-measured experimental data were used for the graphite shrinkage versus fast neutron fluence. PIE dimensional measurements were taken on all the fuel compacts, graphite holders, and all of the graphite rings used. Heat rates were input from a detailed physics analysis for each day during the experiment. Individual heat rates for each nonfuel component were input as well. A steady-state thermal analysis was performed for each daily calculation. A finite element model was created for each capsule.

Detailed measurements of local thickness changes for U-7Mo dispersion fuel plates with Al-3.5Si matrix after irradiation at different powers in the RERTR-9B experiment

The Materials Management and Minimization program is developing fuel designs to replace highly enriched fuel with fuels of low enrichment. Swelling is an important irradiation behavior that needs to be well understood. Data from high resolution thickness measurements performed on U-7Mo dispersion fuel plates with Al-Si alloy matrices that were irradiated at high power is sparse. This paper reports the results of detailed thickness measurements performed on two dispersion fuel plates that were irradiated at relatively high power to high fission densities in the Advanced Test Reactor in the same RERTR-9B experiment. Both plates were irradiated to similar fission densities, but one was irradiated at a higher power than the other. The goal of this work is to identify any differences in the swelling behavior when fuel plates are irradiated at different powers to the same fission densities. Based on the results of detailed thickness measurments, more swelling occurs when a U-7Mo dispersion fuel with Al-3.5Si matrix is irradiated to a high fission density at high power compared to one irradiated at a lower power to high fission density.

TEM characterization of irradiated U-7Mo/Mg dispersion fuel

This paper presents the results of transmission electron microscopy (TEM) characterization on neutron-irradiated samples taken from the low-flux and high-flux sides of the same fuel plate with U-7Mo fuel particles dispersed in Mg matrix with aluminum alloy Al6061 as cladding material that was irradiated edge-on to the core in the Advanced Test Reactor. The corresponding local fission density and fission rate of the fuel particles and the average fuel-plate centerline temperature for the low-flux and high-flux samples are estimated to be 3.7 × 1021 f/cm3, 7.4 × 1014 f/cm3/s and 123 °C, and 5.5 × 1021 f/cm3, 11.0 × 1014 f/cm3/s and 158 °C, respectively. Complex interaction layers developed at the Al-Mg interface, consisting of Al3Mg2 and Al12Mg17 along with precipitates of MgO, Mg2Si and FeAl5.3. No interaction between Mg matrix and U-Mo fuel particle was identified. For the U-Mo fuel particles, at low fission density, small elongated bubbles wrapped around the clean areas with a fission gas bubble superlattice, which suggests that bubble coalescence is an important mechanism for converting the fission gas bubble superlattice to large bubbles. At high fission density, no bubbles or porosity were observed in the Mg matrix, and pockets of residual fission gas bubble superlattice were observed in the U-Mo fuel particle interior.

A Summary of the Department of Energy’s Advanced Demonstration and Test Reactor Options Study

An assessment of advanced reactor technology options was conducted to provide a sound comparative technical context for future decisions by the U.S. Department of Energy (DOE) concerning these technologies. Strategic objectives were established that span a wide variety of important missions, and advanced reactor technology needs were identified based on recent DOE and international studies. A broad team of stakeholders from industry, academia, and government was assembled to develop a comprehensive set of goals, criteria, and metrics to evaluate advanced irradiation test and demonstration reactor concepts. Point designs of a select number of concepts were commissioned to provide a deeper technical basis for evaluation. The technology options were compared on the bases of technical readiness and the ability to meet the different strategic objectives. Using the study’s evaluation criteria and metrics, an independent group of experts from industry, universities, and national laboratories scored each of the point designs. Pathways to deployment for concepts of varying technical maturities were estimated for the different demonstration systems with regard to cost, schedule, and possible licensing approaches. This study also presents the trade-offs that exist among the different irradiation test reactor options in terms of the ability to conduct irradiations in support of advanced reactor research and development and to serve potential secondary missions.The main findings of the study indicate the following: (1) for industrial process heat supply, a high-temperature gas-cooled reactor is the best choice because of the high outlet temperature of the reactor and its strong passive and inherent safety characteristics; (2) for resource utilization and waste management, a sodium-cooled fast reactor (SFR) is best because of the use of a fast flux to destroy actinides; (3) to realize the advantages of a promising but less-mature technology, a fluoride salt-cooled high-temperature reactor and a lead-cooled fast reactor fare about the same; (4) for fulfilling the needs of a materials test reactor, a SFR is considered best because of its ability to produce high fast flux, incorporate test loops, and provide additional large volumes for testing.

Microstructural evolution of neutron-irradiated T91 and NF616 to ∼4.3 dpa at 469 °C

Ferritic-martensitic steels such as T91 and NF616 are candidate materials for several nuclear applications. This study evaluates radiation resistance of T91 and NF616 by examining their microstructural evolutions and hardening after the samples were irradiated in the Advanced Test Reactor to ∼4.3 displacements per atom (dpa) at an as-run temperature of 469 °C. In general, this irradiation did not result in significant difference in the radiation-induced microstructures between the two steels. Compared to NF616, T91 had a higher number density of dislocation loops and a lower level of radiation-induced segregation, together with a slightly higher radiation-hardening. Unlike dislocation loops developed in both steels, radiation-induced cavities were only observed in T91 but remained small with sub-10 nm sizes. Other than the relatively stable M23C6, a new phase (likely Sigma phase) was observed in T91 and radiation-enhanced MX → Z phase transformation was identified in NF616. Laves phase was not observed in the samples.

Irradiated microstructure of U-10Mo monolithic fuel plate at very high fission density

Monolithic U-10Mo alloy fuel plates with Al-6061 cladding are being developed for use in research and test reactors as low enrichment fuel (<20% U-235 enrichment) as a result of its high uranium loading capacity compared to that of U-7Mo dispersion fuel. These fuel plates contain a Zr diffusion barrier between the U-10Mo fuel and Al-6061 cladding that suppresses the interaction between the U-Mo fuel foil and Al alloy cladding that is known to be problematic under irradiation. Different methods have been employed to fabricate monolithic fuel plates, including hot-rolling with no cold-rolling. L1P09T is a hot-rolled fuel plate irradiated to high fission density in the RERTR-9B experiment. This paper discusses the TEM characterization results for this U-10Mo/Zr/Al6061 monolithic fuel plate (∼59% U-235 enrichment) irradiated in Advanced Test Reactor at Idaho National Laboratory with an unprecedented high local fission density of 9.8E+21 fissions/cm3. The calculated fuel foil centerline temperature at the beginning of life and the end of life is 141 and 194 °C, respectively. TEM lamellas were prepared using focus ion beam lift-out technique. The estimated U-Mo fuel swelling, based on the fuel foil thickness change from SEM, is approximately 76%. Large bubbles (>1 μm) are distributed evenly in U-Mo and interlink of these bubbles is evident. The average size of subdivided grains at this fission density appears similar to that at 5.2E+21 fissions/cm3. The measured average Mo and Zr content in the fuel matrix is ∼30 at% and ∼7 at%, respectively, in general agreement with the calculated Mo and Zr from fission density.

Micro to nanostructural observations in neutron irradiated nuclear graphites PCEA and PCIB

The neutron irradiation-induced structural changes in nuclear grade graphites PCEA and PCIB were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), selected area electron diffraction (SAED) and electron energy loss spectroscopy (EELS). The graphite samples were irradiated at the Advanced Test Reactor at the Idaho National Laboratory. Received doses ranged from 1.5 to 6.8 displacements per atom and irradiation temperatures varied between 350 °C and 670 °C.XRD and Raman measurements provided evidence for irradiation induced crystallite fragmentation, with crystallite sizes reduced by 39–55%. Analysis of TEM images was used to quantify fringe length, tortuosity, and relative misorientation of planes, and indicated that neutron irradiation induced basal plane fragmentation and curvature. EELS was used to quantify the proportion of sp2 bonding and specimen density; a slight reduction in planar-sp2 content (due to the buckling basal planes and the introduction of non-six-membered rings) agreed with the observations from TEM.

Acoustic measurement infrastructure to enable the enhancement of nuclear reactor efficiency and safety

Nuclear research reactors are used to test efficiency and safety of new technology, such as material or fuel samples under prototypic commercial conditions, operation of reactor prototypes, safety studies, assessment of neutron parameters, etc. Many experiments performed in research reactors require in-situ measurements to monitor the progress and performance of conducted tests. The core of any nuclear reactor presents a particularly harsh environment for sensors and instrumentations. The reactor core also imposes challenging constraints on signal transmission from inside the reactor core to outside of the reactor vessel. In this paper, an acoustic measurement infrastructure (AMI) installed at the Advanced Test Reactor (ATR), located at Idaho National Laboratory, is presented. The AMI consists of ATR in-pile structural components, coolant, acoustic receivers, primary coolant pumps, a data-acquisition system, and signal processing algorithms. Intrinsic and cyclic acoustic signals generated by the operation of the primary coolant pumps are collected using acoustic receivers and processed. The characteristics of the intrinsic signal can indicate the process state of the ATR during operation (i.e., real-time measurement). The innovation of AMI can be extended to collect information on other phenomena, such as fuel motion, individual fuel rod vibration, loose parts, thermal expansion, and flow blockage, that occur inside an operating nuclear reactor.

Deciding with Thresholds: Importance Measures and Value of Information

Risk-informed decision making is often accompanied by the specification of an acceptable level of risk. Such target level is compared against the value of a risk metric, usually computed through a probabilistic safety assessment model, to decide about the acceptability of a given design, the launch of a space mission, etc. Importance measures complement the decision process with information about the risk/safety significance of events. However, importance measures do not tell us whether the occurrence of an event can change the overarching decision. By linking value of information and importance measures for probabilistic risk assessment models, this work obtains a value-of-information-based importance measure that brings together the risk metric, risk importance measures, and the risk threshold in one expression. The new importance measure does not impose additional computational burden because it can be calculated from our knowledge of the risk achievement and risk reduction worth, and complements the insights delivered by these importance measures. Several properties are discussed, including the joint decision worth of basic event groups. The application to the large loss of coolant accident sequence of the Advanced Test Reactor helps us in illustrating the risk analysis insights.

Uncertainty Quantification of Calculated Temperatures for Advanced Gas Reactor Fuel Irradiation Experiments

This paper presents the quantification of uncertainty of the calculated temperature data for the Advanced Gas Reactor (AGR) fuel irradiation experiments conducted in the Advanced Test Reactor at Idaho National Laboratory in support of the Advanced Reactor Technologies Fuel Development and Qualification Program. The predicted temperatures with associated uncertainty for AGR tests using the ABAQUS finite element heat transfer code are used to validate the fission product transport and fuel performance simulation models. To quantify the uncertainty of calculated temperatures, this study identifies and analyzes model parameters of potential importance to the predicted fuel temperatures. The selection of input parameters for uncertainty quantification is based on the ranking of their influence on the variation of temperature predictions. Thus, selected input parameters include those with high sensitivity and those with large uncertainty. The propagation of model parameter uncertainty and sensitivity is then used to quantify the overall uncertainty of the calculated temperatures. The sensitivity analysis performed in this work went beyond the traditional local sensitivity. Using an experimental design, an analysis of pairwise interactions of model parameters was performed to establish the sufficiency of the first-order (linear) expansion terms in constructing the response surface. To achieve completeness, the uncertainty propagation made use of pairwise noise correlations of model parameters. The AGR-2 overall fuel temperature uncertainties reported here are less than 5% (or 60°C).

Fabrication and testing of U–7Mo monolithic plate fuel with Zircaloy cladding

Nuclear fuel designs are being developed to replace highly enriched fuel used in research and test reactors with fuels of low enrichment. In the most challenging cases, U–(7–10 wt%)Mo monolithic plate fuels are proposed. One of the considered designs includes aluminum-alloy cladding, which provides some challenges in fabrication and fuel/cladding interaction during service. Zircaloy cladding, specifically Zry–4, was investigated as an alternative cladding, and development of a fabrication method was performed by researchers with the Comisión Nacionalde Energia Atómica (CNEA) in Argentina, resulting in test fuel plates (Zry–4 clad U–7Mo) which were subsequently tested in the Advanced Test Reactor in Idaho. Because Zry–4 and U–(7–10)Mo have similar high-temperature mechanical properties, fabrication was simplified in that the fuel foil and cladding could be co-rolled and bonded. The challenge was to prevent a thermal-expansion mismatch, which could destroy the fuel/cladding bond before complete bonding was achieved; the solution was to prevent the composites from cooling significantly during or between roll passes. The final product performed very well in-reactor, showing good bonding, very little fuel/cladding interaction—either from fabrication or in-reactor testing—and little swelling, especially no detectable heterogeneous bubble formation at the fuel/cladding interface tested to a fission density of up to 2.7E+21 (average) fissions/cm3, 3.8E+21 (peak).

Microstructural Characterization of a Mg Matrix U-Mo Dispersion Fuel Plate Irradiated in the Advanced Test Reactor to High Fission Density: SEM Results

Low-enriched (U-235 <20 pct) U-Mo dispersion fuel is being developed for use in research and test reactors. In most cases, fuel plates with Al or Al-Si alloy matrices have been tested in the Advanced Test Reactor to support this development. In addition, fuel plates with Mg as the matrix have also been tested. The benefit of using Mg as the matrix is that it potentially will not chemically interact with the U-Mo fuel particles during fabrication or irradiation, whereas with Al and Al-Si alloys such interactions will occur. Fuel plate R9R010 is a Mg matrix fuel plate that was aggressively irradiated in ATR. This fuel plate was irradiated as part of the RERTR-8 experiment at high temperature, high fission rate, and high power, up to high fission density. This paper describes the results of the scanning electron microscopy (SEM) analysis of an irradiated fuel plate using polished samples and those produced with a focused ion beam. A follow-up paper will discuss the results of transmission electron microscopy (TEM) analysis. Using SEM, it was observed that even at very aggressive irradiation conditions, negligible chemical interaction occurred between the irradiated U-7Mo fuel particles and Mg matrix; no interconnection of fission gas bubbles from fuel particle to fuel particle was observed; the interconnected fission gas bubbles that were observed in the irradiated U-7Mo particles resulted in some transport of solid fission products to the U-7Mo/Mg interface; the presence of microstructural pathways in some U-9.1 Mo particles that could allow for transport of fission gases did not result in the apparent presence of large porosity at the U-7Mo/Mg interface; and, the Mg-Al interaction layers that were present at the Mg matrix/Al 6061 cladding interface exhibited good radiation stability, i.e. no large pores.

Using a spherical crystallite model with vacancies to relate local atomic structure to irradiation defects in ZrC and ZrN

Zirconium carbide and zirconium nitride are candidate materials for new fuel applications due to several favorable physicochemical properties. ZrC and ZrN samples were irradiated at the Advanced Test Reactor National Scientific User Facility with neutrons at 800 °C to a dose of 1 dpa. Structural examinations have been made of the ZrC samples using high resolution transmission electron microscopy, and the findings compared with a previous study of ZrC irradiated with protons at 800 °C. The use of X-ray absorption fine structure spectroscopy (XAFS) to characterize the radiation damage was also explored including a model based on spherical crystallites that can be used to relate EXAFS measurements to microscopy observations. A loss of coordination at more distant coordination shells was observed for both ZrC and ZrN, and a model using small spherical crystallites suggested this technique can be used to study dislocation densities in future studies of irradiated materials.

Aluminum cladding oxidation of prefilmed in-pile fueled experiments

A series of fueled irradiation experiments were recently completed within the Advanced Test Reactor Full size plate In center flux trap Position (AFIP) and Gas Test Loop (GTL) campaigns. The conduct of the AFIP experiments supports ongoing efforts within the global threat reduction initiative (GTRI) to qualify a new ultra-high loading density low enriched uranium-molybdenum fuel. This study details the characterization of oxide growth on the fueled AFIP experiments and cross-correlates the empirically measured oxide thickness values to existing oxide growth correlations and convective heat transfer correlations that have traditionally been utilized for such an application. This study adds new and valuable empirical data to the scientific community with respect to oxide growth measurements of highly irradiated experiments, of which there is presently very limited data. Additionally, the predicted oxide thickness values are reconstructed to produce an oxide thickness distribution across the length of each fueled experiment (a new application and presentation of information that has not previously been obtainable in open literature); the predicted distributions are compared against experimental data and in general agree well with the exception of select outliers.

Evaluations of Mo-alloy for light water reactor fuel cladding to enhance accident tolerance

Molybdenum based alloy is selected as a candidate to enhance tolerance of fuel to severe loss of coolant accidents due to its high melting temperature of ∼2600 °C and ability to maintain sufficient mechanical strength at temperatures exceeding 1200 °C. An outer layer of either a Zr-alloy or Al-containing stainless steel is designed to provide corrosion resistance under normal operation and oxidation resistance in steam exceeding 1000 °C for 24 hours under severe loss of coolant accidents. Due to its higher neutron absorption cross-sections, the Mo-alloy cladding is designed to be less than half the thickness of the current Zr-alloy cladding. A feasibility study has been undertaken to demonstrate (1) fabricability of long, thin wall Mo-alloy tubes, (2) formability of a protective outer coating, (3) weldability of Mo tube to endcaps, (4) corrosion resistance in autoclaves with simulated LWR coolant, (5) oxidation resistance to steam at 1000–1500 °C, and (6) sufficient axial and diametral strength and ductility. High purity Mo as well as Mo + La2 O3 ODS alloy have been successfully fabricated into ∼2-meter long tubes for the feasibility study. Preliminary results are encouraging, and hence rodlets with Mo-alloy cladding containing fuel pellets have been under preparation for irradiation at the Advanced Test Reactor (ATR) in Idaho National Laboratory. Additional efforts are underway to enhance the Mo cladding mechanical properties via process optimization. Oxidation tests to temperatures up to 1500 °C, and burst and creep tests up to 1000 °C are also underway. In addition, some Mo disks in close contact with UO2 from a previous irradiation program (to >100 GWd/MTU) at the Halden Reactor have been subjected to post-irradiation examination to evaluate the chemical compatibility of Mo with irradiated UO2 and fission products. This paper will provide an update on results from the feasibility study and discuss the attributes of the coated Mo cladding design to meet the challenging requirements for improving fuel tolerance to severe loss of coolant accidents.

High-energy synchrotron study of in-pile-irradiated U–Mo fuels

Here synchrotron scattering analysis results on U–7wt.%Mo fuel specimens irradiated in the Advanced Test Reactor to three burnup levels (3.0, 5.2, and 6.3×1021fission/cm3) are reported. Mature fission gas bubble superlattice was observed to form at intermediate burnup. The superlattice constant was determined to be 11.7 and 12.0nm by wide-angle and small-angle scattering respectively. Grain sub-division takes place throughout the irradiation and causes the collapse of the superlattice at high burnup. The bubble superlattice expands the U–Mo lattice and acts as strong sink for radiation-induced defects. The evolution of dislocation loops was, therefore, suppressed until the bubble superlattice collapsed.