Energy storage capacitors are valued for their high power density and ultrafast discharging rates, positioning them as promising candidates for advanced electronic systems and pulse power technologies. This study developed a KBT-based solid solution composed of K0.5Bi0.5TiO3, Na0.5Bi0.5ZrO3, K0.5Bi0.5ZrO3, and Na0.5Bi0.5TiO3, located near a morphotropic relaxor boundary. This configuration results in a perovskite host with both high structural entropy and enhanced polarization capability. The incorporation of Bi(Zn2/3Nb1/3)O3 not only modifies the dynamic behavior of polar nanoregions but also increases the resistance contribution from the grain boundary, thereby improving the electrical breakdown strength Eb. Optimal polarization behavior and energy storage performance were achieved with 1.0 mol.% Bi(Zn2/3Nb1/3)O3 addition, resulting in a large field-induced polarization ΔP of 55.3 µC/cm2, a high recoverable energy density Wr of 6.52 J/cm3, and a high efficiency η of 80%. Overall, this work proposed a design strategy for developing KBT-based ceramics for energy storage capacitors.
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