Advanced Conductors Research Articles

Accelerating transmission capacity expansion by using advanced conductors in existing right-of-way

As countries pursue decarbonization goals, the rapid expansion of transmission capacity for renewable energy (RE) integration poses a significant challenge due to hurdles such as permitting and cost allocation. However, we find that large-scale reconductoring with advanced composite-core conductors can cost-effectively double transmission capacity within existing right-of-way, with limited additional permitting. This strategy unlocks a high availability of increasingly economically viable RE resources in close proximity to the existing network. We implement reconductoring in a model of the US power system, showing that reconductoring can help meet over 80% of the new interzonal transmission needed to reach over 90% clean electricity by 2035 given restrictions on greenfield transmission build-out. With $180 billion in system cost savings by 2050, reconductoring presents a cost-effective and time-efficient, yet underutilized, opportunity to accelerate global transmission expansion.

Polyfunctional and Multisensory Bio-Ionoelastomers Enabled by Covalent Adaptive Networks With Hierarchically Dynamic Bonding.

Developing versatile ionoelastomers, the alternatives to hydrogels and ionogels, will boost the advancement of high-performance ionotronic devices. However, meeting the requirements of bio-derivation, high toughness, high stretchability, autonomous self-healing ability, high ionic conductivity, reprocessing, and favorable recyclability in a single ionoelastomer remains a challenging endeavor. Herein, a dynamic covalent and supramolecular design, lipoic acid (LA)-based dynamic covalent ionoelastomer (DCIE), is proposed via melt building covalent adaptive networks with hierarchically dynamic bonding (CAN-HDB), wherein lithium bonds aid in the dissociation of ions and the integration of dynamic disulfide metathesis, lithium bonds, and binary hydrogen bonds enhances the mechanical performances, self-healing capability, reprocessing, and recyclability. Therefore, the trade-off among mechanical versatility, ionic conductivity, self-healing capability, reprocessing, and recyclability is successfully handled. The obtained DCIE demonstrates remarkable stretchability (1011.7%), high toughness (3877kJm-3), high ionic conductivity (3.94×10-4Sm-1), outstanding self-healing capability, reprocessing for 3D printing, and desirable recyclability. Significantly, the selective ion transport endows the DCIE with multisensory feature capable of generating continuous electrical signals for high-quality sensations towards temperature, humidity, and strain. Coupled with the straightforward methodology, abundant availability of LA and HPC, as well as multifunction, the DCIEs present new concept of advanced ionic conductors for developing soft ionotronics.

Effects of Graphene Doping on the Electrical Conductivity of Copper

AbstractThere is great interest in developing advanced electrical conductors with higher conductivity, lighter weight, and higher mechanical strength than copper (Cu). One promising candidate is copper‐graphene (Cu‐Gr) composite, which is hypothesized to have a higher electrical conductivity than Cu. In this work, it is shown that this is not true, supported by state‐of‐the‐art first‐principles calculations of electron transport. Particularly, contrary to the belief that graphene in the composite is more conductive than pristine Cu, it is less conductive due to increased scattering despite increased carrier concentration. On the other hand, it is found that compressive strain along the (111) plane increases the conductivity, which is confirmed experimentally, while tensile strain has little effect. The work offers new insights into understanding and developing advanced conductors.

Advanced conductors could double power flows on the grid

Widespread reconductoring of the US transmission system could ease bottlenecks that are preventing renewable energy sources from hooking up to power grids.

Copper–Carbon Nanotube Composites Enabled by Brush Coating for Advanced Conductors

Copper–Carbon Nanotube Composites Enabled by Brush Coating for Advanced Conductors

Polyoxometalate-based reticular materials for proton conduction: from rigid frameworks to flexible networks.

Proton conductors play a crucial role in energy and electronic technologies, thus attracting extensive research interest. Recently, reticular chemistry has propelled the development of reticular materials with framework or network structures, which can offer tunable proton transport pathways to achieve optimal conducting performance. Polyoxometalates (POMs), as a class of highly proton-conducting units, have been integrated into these reticular materials using various linkers. This leads to the creation of hybrid proton conductors with structures varying from rigid crystalline frameworks to flexible networks, showing adjustable proton transport behaviors and mechanical properties. This Frontier article highlights the advancements in POM-based reticular materials for proton conduction and provides insights for designing advanced proton conductors for practical applications.

Research and Analysis of the Cost of Right of Way for Conventional Overhead Transmission Lines and Power Transmission Cable

The study explores the pros and cons of adding these advanced conductors to transmission lines. This study examines the costs of procuring RoW for standard overhead transmission lines and power transmission cables. The report details the costs and considerations of obtaining land for power transmission infrastructure. Research has two main parts. The document begins with transmission asset owner’s RoW acquisition methods and rules. It explains the regulatory framework and mechanisms for securing land rights for power transmission infrastructure. The second section analyses costs in detail. It compares the economics of installing overhead transmission lines with power transmission cables, focusing on subsurface XLPE cables. The study examines how RoW acquisition affects adjacent land prices and the economic effects on TAOs and surrounding communities. The research also evaluates transmission line dismantling costs, including waste metal value, considering metal price changes. RoW costs persist after the transmission line's tenure. The paper also examines a replacement model that estimates RoW costs for switching from overhead transmission lines to underground XLPE cables for outmoded transmission infrastructure. This analysis seeks to illuminate RoW Acquisition's financial elements for power transmission decision-makers.

Ab initio investigations on the electronic properties and stability of Cu-substituted lead apatite (LK-99) family with different doping concentrations (x = 0, 1, 2)

The pursuit of room-temperature ambient-pressure superconductivity in novel materials has sparked interest, with recent reports suggesting such properties in Cu-substituted lead apatite, known as LK-99. However, these claims lack comprehensive experimental and theoretical support. In this study, we address this gap by conducting ab initio calculations to explore the impact of varying doping concentrations (x = 0, 1, 2) on the stability and electronic properties of five compounds in the LK-99 family. Our investigations confirm the isolated flat bands that intersect the Fermi level in LK-99 (Pb9Cu(PO4)6O:Cu<Pb(1)>). In contrast, the other four parent compounds exhibit insulating behavior with wide band gaps. X-ray diffraction spectra based on the DFT simulations at 0 K confirm the presence of Cu substitution on Pb(1) sites in the originally synthesized LK-99 sample, while an extra peak suggests potential alternative like Pb8Cu2(PO4)6 phases due to compositional variations in the original LK-99 samples. Furthermore, the LK-99 structure undergoes substantial lattice constriction, resulting in a significant 5.5% reduction in volume and 6.8% in area of two mutually inverted triangles formed by Pb(2) atoms. Meanwhile, energy calculations reveal a marginal energy preference for substituting Cu on Pb(2) sites over Pb(1) sites, with a difference of approximately 0.010 eV per atom (roughly 0.9645 kJ/mol). Intriguingly, at pressures exceeding 73 GPa, stability shifts towards LK-99 containing Cu substitutions on Pb(1) sites. Despite exhibiting higher electronic conductivity than parent compounds, Pb9Cu(PO4)6O:Cu<Pb(1)> falls short of the conductivity levels observed in metals or advanced oxide conductors with the simulation based on the Boltzmann transport theory.

Review of Technological Advances in High Temperature Overhead Line Composite Conductors

ACSR (Aluminium Conductor Steel Reinforced) conductors consisting of pure aluminum wires helically stranded around a core of high strength galvanized steel core wires are widely used in overhead transmission line applications. While the steel wires provides the required strength, the outer aluminium serves as electricity conducting member. The thermal rating or ampacity of conductors is the maximum current that a circuit can carry within the temperature limits as dictated by the allowable conductor sag or by the annealing onset temperature of the conductor, whichever is lower. On a continuous basis, ACSR may be operated at temperatures up to 100°C without any significant change in the conductor’s physical properties. Above 100°C, aluminum wires loses tensile strength over time and becomes "fully annealed" giving rise to increased thermal expansion of the conductor; this causes excessive sagging reducing the clearance between the ground and the energized conductors.&#x0D; While, the electric utilities are posed with increased challenges of production of additional capacities and building new transmission circuits to meet the ever growing demand and the high cost and environmental restrictions of constructing new lines, methods are being explored to increase their capacity with minimum changes in the existing towers. Replacement of the existing conductor with a advanced high temperature composite (HTC) conductors operating upto temperatures of 200°C with reduced sagging characteristics have been attempted and an increase in capacity of 30-80%, can be achieved through application of these composite conductors.&#x0D; The advanced HTC conductors with varied combinations of core material and outer conducting wires are being tried so as to achieve wide ranging properties. In general, HTC conductors features the combinations of either soft aluminum wires with ultra high strength steel or temperature resistant aluminium with or fiber reinforced metal/polymer matrix composites as the core. Both the alumina fiber reinforced temperature resistant aluminium metal matrix composite and the carbon fiber reinforced high temperature polymer resin composite wires as the core material appears to have favorable applications. The comparative performance of the HTC depends on the degree to which both outer aluminum strand and reinforcing core’s physical properties are stable at high temperature and on the elastic, plastic, and thermal elongation of the combined HTC.&#x0D; The summary of various developments realized in the area of composite conductors and their relative merits and demerits have been discussed in detail.

Potency of Severe Plastic Deformation Processes for Optimizing Combinations of Strength and Electrical Conductivity of Lightweight Al-Based Conductor Alloys

This paper presents an overview of fundamentals and potential applications of ultrafine-grained Al-based conductors developed with the help of severe plastic deformation (SPD) techniques. Based on deliberate formation of nanoscale features (such as nanoprecipitates, segregation of solutes along crystallographic defects and so on) within ultrafine grains, it is possible to optimise their mechanical and functional performance enhancing the combination of strength and electrical conductivity to produce advanced lightweight conductors required by modern industries. Guidelines related to SPD-driven development of Al alloys with properties superior to those exhibited by traditionally processed conductors are discussed.

Dynamic sustainable polyamide elastomer toward ultratough and fully recyclable self-healing ionic conductors

The development of flexible ionic conductors with extreme elasticity, high ionic conductivity, desirable self-healing capacity and recyclability is a pressing need while challenging because the regulating of these performances is generally mutually exclusive. Herein, we report a dynamic double-crosslinking bio-based ionic conductive elastomer (DBICE), designed via the introduction of reversible covalent Diels-Alder motifs into a furan-functionalized biobased polyamide matrix, which realizes an ultratough, outstanding mechanical versatility (170.1 MJ m−3 toughness and 1342% elongation), unique self-healability (∼100% within 6 h), and capability to completely recycle and facilely reprocess. The specifically tailored ether-rich segments in the polyamide backbones with long-range ordering and selectively entrapped lithium-ion (Li+) provided high-efficient ion transport pathways, gaining remarkable room-temperature ionic conductivity of 1.66 × 10–3 S m−1. The resultant DBICE is assembled into a proof-of-concept flexible ionotronic sensor, exhibiting reliable resistivity sensing quality with high sensitivity and robust mechanosensation capability, and excellent recovery for the polymeric matrices and electronic components. This work provides a new molecular design principle for the sustainable development of advanced ionic conductors holding a great promise in wearable electronics or all-solid-state batteries.

Lamellar Ionic Liquid Composite Electrolyte for Wide‐Temperature Solid‐State Lithium‐Metal Battery

AbstractElectrolytes that can work over a wide temperature range are crucial forsustainable advanced energy systems. Here, a kind of lamellar ionic liquid composite electrolyte (L‐ILCE) is explored through confining ionic liquids (ILs) in ordered interlayer nanochannels of 2D vermiculite framework. It is demonstrated that, within nanochannels, the finely tuned microstructure can induce the rearrangement and crystallinity of ILs, affording L‐ILCE the combined superiorities of liquid electrolyte and solid‐state electrolyte. L‐ILCE exhibits high ionic conductivities (0.09–1.35 × 10−3 S cm−1 at −40 to 100 °C), whereas polymer and inorganic electrolytes usually lose ionic conduction ability below 0 °C. Additionally, L‐ILCE exhibits high transference number (0.89, comparable with single‐ion conductors) and wide electrochemical window (0–5.3 V). LiFePO4||Li and high‐voltage LiNi0.8Mn0.1Co0.1O2||Li cells assembled from L‐ILCEs exhibit highly stable electrochemical performance in −20 to 60 °C. Furthermore, pouch cells (0.1 Ah) exhibit high capacity of 93.8 and 45.0 mAh after 50 cycles along with capacity retention of 97% and 98% at 60 and −20 °C, respectively, as well as excellent flexibility and safety. This study offers promise in the rational design of advanced ion conductors for lithium‐based batteries with wider operating temperatures.

Spacer-Engineered Ionic Channels in Covalent Organic Framework Membranes toward Ultrafast Proton Transport.

Side-chain engineering of covalent organic frameworks as advanced ion conductors is a critical issue to be explored. Herein, ionic covalent organic framework membranes (iCOFMs) with spacer-engineered ionic channel are de novo designed and prepared. The ionic channels are decorated with side chains comprising spacers having different carbon chain lengths and the -SO3 H groups at the end. Attributed to the synergistic contribution from the spacers and the -SO3 H groups, the iCOFM with moderate-length spacer exhibit the highest through-plane proton conductivity of 889 mS cm-1 at 90°C.

Recent advancements of covalent organic frameworks (COFs) as proton conductors under anhydrous conditions for fuel cell applications.

Recent electrochemical energy conversion devices require more advanced proton conductors for their broad applications, especially, proton exchange membrane fuel cell (PEMFC) construction. Covalent organic frameworks (COFs) are an emerging class of organic porous crystalline materials that are composed of organic linkers and connected by strong covalent bonds. The unique characteristics including well-ordered and tailorable pore channels, permanent porosity, high degree of crystallinity, excellent chemical and thermal stability, enable COFs to be the potential proton conductors in fuel cell devices. Generally, proton conduction of COFs is dependent on the amount of water (extent of humidity). So, the constructed fuel cells accompanied complex water management system which requires large radiators and airflow for their operation at around 80 °C to avoid overheating and efficiency roll-off. To overcome such limitations, heavy-duty fuel cells require robust proton exchange membranes with stable proton conduction at elevated temperatures. Thus, proton conducting COFs under anhydrous conditions are in high demand. This review summarizes the recent progress in emerging COFs that exhibit proton conduction under anhydrous conditions, which may be prospective candidates for solid electrolytes in fuel cells.

Surface Acidity Dictates Proton Transport in WO3/ZrO2: Proton-Conductive Behavior and Mechanistic Insight

Development of inorganic proton conductors that are applicable in a wide temperature range is crucial for applications such as fuel cells. Most of the reported proton conductors suffer from limited proton conductivity, especially at low temperature. In addition, the mechanism of proton conduction in the conductors is not fully understood, which limits the rational design of advanced proton conductors. In this work, we report the use of metal oxide solid acid as a promising proton conductor. WO3/ZrO2 (WZ) with different surface acidities is synthesized by controlling the content of WO3 on the surface of ZrO2. It is demonstrated that proton conductivity of WZ samples is closely related with their acidity. WZ with the strongest acidity exhibits the highest proton conduction performance at low temperatures, with a proton conductivity of 3.27 × 10-5 S cm-1 at 14 °C. The excellent performance of the WZ-type proton conductor is clarified with theoretical calculations. The results show that the enhanced water adsorption and the lowered activation barrier for breakage of the O-H bond in surface-adsorbed water are the key to the excellent proton-conductive performance of WZ. The experimental results and mechanistic insights gained in this work suggest that WZ is a promising proton conductor, and tailoring the surface acidity of metal oxides is an effective approach to regulate their proton-conductive performance.

Complex Oxide Nanoparticle Synthesis: Where to Begin to Do It Right?

Synthesis of advanced ceramics requires a high degree of control over the particle size and stoichiometry of the material. When choosing a synthesis method for complex oxides it is important to begin with the correct precursors and solvents to achieve high purity nanoparticles. Here, we detail the selection process for precursors and solvents for liquid-phase precipitation synthesis. Data for metal nitrate, chloride, acetate, and oxalate precursors has been compiled to assist future synthesis. The role of hydration within the precursors is discussed as it affects the final stoichiometry of the material. Melting temperatures are also compiled for these compounds to assist in material selection. The solubility of the precursors in different solvents is examined to determine the correct solvent during synthesis. As an example, using the methodology presented here, two different materials are synthesized based on commonly available precursors. A catalyst based on a quaternary perovskite and an advanced ionic conductor based on a high entropy fluorite oxide are synthesized using precipitation methods and their characterization is detailed.

Keeping Superprotonic Conductivity over a Wide Temperature Region via Sulfate Hopping Sites-Decorated Zirconium-Oxo Clusters.

Metal-oxo clusters have emerged as advanced proton conductors with well-defined and tunable structures. Nevertheless, the exploitation of metal-oxo clusters with high and stable proton conductivity over a relatively wide temperature range still remains a great challenge. Herein, three sulfate groups decorated zirconium-oxo clusters (Zr6 , Zr18 , and Zr70 ) as proton conductors are reported, which exhibit ultrahigh bulk proton conductivities of 1.71×10-1 , 2.01×10-2 , and 3.73×10-2 Scm-1 under 70°C and 98% relative humidity (RH), respectively. Remarkably, Zr6 and Zr70 with multiple sulfate groups as proton hopping sites show ultralow activation energies of 0.22 and 0.18eV, respectively, and stable bulk conductivities of >10-2 Scm-1 between 30 and 70°C at 98% RH. Moreover, a time-dependent proton conductivity test reveals that the best performing Zr6 can maintain high proton conductivity up to 15h with negligible loss at 70°C and 98% RH, representing one of the best crystalline cluster-based proton conducting materials.

HTS Cable Conductor for Compact Fusion Tokamak Solenoids

Significant progress has been made recently in the US fusion community to develop a strategic plan to enable engineering design and construction of a fusion pilot plant (FPP). Princeton Plasma Physics Laboratory (PPPL) is working on developing high current density HTS conductors for next fusion experiments. Partnering with the US industry, we are evaluating feasibility and affordability of Conductor on Round Core (CORC <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><tex-math notation="LaTeX">${}^\circledR$</tex-math></inline-formula> ) developed by Advanced Conductor Technologies (ACT) for the next compact fusion tokamak facility. High current density achieved by a CORC <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><tex-math notation="LaTeX">${}^\circledR$</tex-math></inline-formula> cable based on a four-layer model coil recently tested at National High Magnetic Field Laboratory (NHMFL) motivated its consideration for low cost, reduced size fusion magnet application. This is of interest to PPPL because of its scalability to tokamak central solenoid (CS) coils in terms of required flux swings for plasma startup operations. Partnering with ACT, we designed and built a two-layer model coil solenoid directly wound with CORC to demonstrate its applicability for compact solenoids such as that used in the national spherical torus experiment (NSTX), NSTX-upgrade (NSTX-U) and the US sustained high-power density test facility (SHPD). The ∼160 mm diameter solenoid wound by a two-layer CORC is being tested in early 2022 under electromagnetic cyclic loading at NHMFL in a unique 160 mm bore, 14 T background field magnet facility.

Phase-locked constructing dynamic supramolecular ionic conductive elastomers with superior toughness, autonomous self-healing and recyclability

Stretchable ionic conductors are considerable to be the most attractive candidate for next-generation flexible ionotronic devices. Nevertheless, high ionic conductivity, excellent mechanical properties, good self-healing capacity and recyclability are necessary but can be rarely satisfied in one material. Herein, we propose an ionic conductor design, dynamic supramolecular ionic conductive elastomers (DSICE), via phase-locked strategy, wherein locking soft phase polyether backbone conducts lithium-ion (Li+) transport and the combination of dynamic disulfide metathesis and stronger supramolecular quadruple hydrogen bonds in the hard domains contributes to the self-healing capacity and mechanical versatility. The dual-phase design performs its own functions and the conflict among ionic conductivity, self-healing capability, and mechanical compatibility can be thus defeated. The well-designed DSICE exhibits high ionic conductivity (3.77 × 10−3 S m−1 at 30 °C), high transparency (92.3%), superior stretchability (2615.17% elongation), strength (27.83 MPa) and toughness (164.36 MJ m−3), excellent self-healing capability (~99% at room temperature) and favorable recyclability. This work provides an interesting strategy for designing the advanced ionic conductors and offers promise for flexible ionotronic devices or solid-state batteries.

A Reel-to-Reel Scanning Hall Probe Microscope for Characterizing Long REBCO Conductor in Magnetic Fields Up to 5 Tesla

We have developed and routinely used a reel-to-reel (R2R) scanning Hall-probe microscopy (SHPM) system to characterize REBCO conductors developed at the University of Houston. By mapping the screening-current-induced field of a magnetized REBCO conductor, the SHPM system enables 2-dimensional imaging of critical current density (<i>J</i>_c) distribution in a contact-free, non-destructive approach. Most existing SHPM systems investigate the magnetized REBCO conductors at remnant state without external background field. However, because of the inhomogeneity in the distribution of nanoscale artificial pinning centers in advanced REBCO conductors, there is a demand for reel-to-reel in-field examination over long conductor lengths. We have been developing a new R2R SHPM, capable of measuring the <i>J</i>_c profile of long REBCO conductors at the temperature of 63.5&#x2013;77 K and in an applied field up to 5 T. With optimal data acquisition and processing techniques, we overcame the challenge of measuring weak screening-current-field signals in a strong background field. R2R <i>J</i>_c mapping has been performed on long REBCO conductors with a spatial resolution as low as 0.15 mm² and a longitudinal scanning speed comparable with our existing system. Our previous study revealed a good correlation between the REBCO conductors&#x2019; 65-K in-field <i>J</i>_c and their <i>J</i>_c over a wide span of temperatures and fields. Using this correlation, the in-field R2R SHPM will serve not only as a means of quality control, but also provide insight into high-field performance of advanced REBCO conductors at low temperatures.