Adiabatic Transfer Research Articles

Long-distance adiabatic wireless energy transfer via multiple coils coupling

Recently, the evolution of wireless energy transfer can be described as Schrodinger equation. Thus, the transfer protocol of wireless energy transfer can be designed by coherent quantum control techniques, which can achieve efficient and robust energy transfer from transmitter to receiver. In this paper, we propose a novel design of wireless energy transfer which obtains the longer distance, efficient and robust schematic of power transfer, via multiple states of triangle crossing pattern. After our calculations, we demonstrate that our design can provide much longer transfer distance with relatively smaller decreasing transfer efficiency.

Speeding up particle slowing using shortcuts to adiabaticity

We propose a method for slowing particles by laser fields that potentially has the ability to generate large forces without the associated momentum diffusion that results from the random directions of spontaneously scattered photons. In this method, time-resolved laser pulses with periodically modified detunings address an ultranarrow electronic transition to reduce the particle momentum through repeated absorption and stimulated emission cycles. We implement a shortcut to adiabaticity approach that is based on Lewis-Riesenfeld invariant theory. This affords our scheme the advantages of adiabatic transfer, where there can be an intrinsic insensitivity to the precise strength and detuning characteristics of the applied field, with the advantages of rapid transfer that is necessary for obtaining a short slowing distance. For typical parameters of a thermal oven source that generates a particle beam with a central velocity on the order of meters per second, this could result in slowing the particles to near stationary in less than a millimeter. We compare the slowing scheme to widely-implemented slowing techniques that rely on radiation pressure forces and show the advantages that potentially arise when the excited state decay rate is small. Thus, this scheme is a particularly promising candidate to slow narrow-linewidth systems that lack closed cycling transitions, such as occurs in certain molecules.

Coherent transport of spin by adiabatic passage in quantum dot arrays

We introduce an adiabatic transfer protocol for spin states in large quantum dot arrays that is based on time-dependent modulation of the Heisenberg exchange interaction in the presence of a magnetic field gradient. We refer to this protocol as spin-CTAP (coherent transport by adiabatic passage) in analogy to a related protocol developed for charge state transfer in quantum dot arrays. The insensitivity of this adiabatic protocol to pulse imperfections has potential advantages for reading out extended spin qubit arrays. When the static exchange interaction varies across the array, a quantum-controlled version of spin-CTAP is possible, where the transfer process is conditional on the spin states in the middle of the array. This conditional operation can be used to generate N-qubit entangled GHZ states. Using a realistic noise model, we analyze the robustness of the spin-CTAP operations and find that high-fidelity (>95%) spin eigenstate transfer and GHZ state preparation is feasible in current devices.

Perspectives on Dye Sensitization of Nanocrystalline Mesoporous Thin Films.

Recent advances in our mechanistic understanding of dye-sensitized electron transfer reactions occurring at metal oxide interfaces are described. These advances were enabled by the advent of mesoporous thin films, comprised of anatase TiO2 nanocrystallites, that are amenable to spectroscopic and electrochemical characterization in unprecedented molecular-level detail. The metal-to-ligand charge transfer (MLCT) excited states of Ru polypyridyl compounds serve as the dye sensitizers. Excited-state injection often occurs on ultrafast time scales with yields that can be tuned from unity to near zero through modification of the sensitizer or the electrolyte composition. Transport of the injected electron and the oxidized sensitizer (hole hopping) are both operative in the composite mechanism for charge recombination between the injected electron and the oxidized sensitizer. Sensitizers that contain a pendant electron donor, as well as core/shell SnO2/TiO2 nanostructures, often prolong the lifetime of the injected electron and provide fundamental insights into adiabatic and nonadiabatic electron transfer mechanisms. Regeneration of the oxidized sensitizer by iodide is enhanced through halogen bonding, orbital pathways, and ion pairing. A substantial ∼10 MV cm-1 electric field is created by electron injection into TiO2 nanocrystallites that induces ion migration, reports on the sensitizer dipole orientation, and (in some cases) reorients or flips the sensitizer. Dye-sensitized conductive oxides also promote long-lived charge separation with bias dependent kinetics that provide insights into the reorganization energies associated with electron and proton-coupled electron transfer in the electric double layer.

High-fidelity multistate stimulated Raman adiabatic passage assisted by shortcut fields

Multistate stimulated Raman adiabatic passage (STIRAP) is a process which allows for adiabatic population transfer between the two ends of a chainwise-connected quantum system. The process requires large temporal areas of the driving pulsed fields (pump and Stokes) in order to suppress the nonadiabatic couplings and thereby to make adiabatic evolution possible. To this end, in the present paper a variation of multistate STIRAP, which accelerates and improves the population transfer, is presented. In addition to the usual pump and Stokes fields it uses shortcut fields applied between the states, which form the dark state of the system. The shortcuts cancel the couplings between the dark state and the other adiabatic states thereby resulting (in the ideal case) in a unit transition probability between the two end states of the chain. Specific examples of five-state systems formed of the magnetic sublevels of the transitions between two degenerate levels with angular momenta $J_g=2$ and $J_e=1$ or $J_e=2$ are considered in detail, for which the shortcut fields are derived analytically. The proposed method is simpler than the usual "shortcuts to adiabaticity" recipe, which prescribes shortcut fields between all states of the system, while the present proposal uses shortcut fields between the sublevels forming the dark state only. The results are of potential interest in applications where high-fidelity quantum control is essential, e.g. quantum information, atom optics, formation of ultracold molecules, cavity QED, etc.

Stimulated Raman adiabatic passage-like protocols for amplitude transfer generalize to many bipartite graphs

Adiabatic passage techniques, used to drive a system from one quantum state into another, find widespread applications in physics and chemistry. We focus on techniques to spatially transport a quantum amplitude over a strongly coupled system, such as STImulated Raman Adiabatic Passage (STIRAP) and Coherent Tunneling by Adiabatic Passage (CTAP). Previous results were shown to work on certain graphs, such as linear chains, square and triangular lattices, and branched chains. We prove that similar protocols work much more generally in a large class of (semi-)bipartite graphs. In particular, under random couplings, adiabatic transfer is possible on graphs that admit a perfect matching both when the sender is removed and when the receiver is removed. Many of the favorable stability properties of STIRAP/CTAP are inherited, and our results readily apply to transfer between multiple potential senders and receivers. We numerically test transfer between the leaves of a tree and find surprisingly accurate transfer, especially when straddling is used. Our results may find applications in short-distance communication between multiple quantum computers and open up a new question in graph theory about the spectral gap around the value 0.

Remote Entanglement via Adiabatic Passage Using a Tunably Dissipative Quantum Communication System.

Effective quantum communication between remote quantum nodes requires high fidelity quantum state transfer and remote entanglement generation. Recent experiments have demonstrated that microwave photons, as well as phonons, can be used to couple superconducting qubits, with a fidelity limited primarily by loss in the communication channel [P. Kurpiers etal., Nature (London) 558, 264 (2018)NATUAS0028-083610.1038/s41586-018-0195-y; C. J. Axline etal., Nat. Phys. 14, 705 (2018)NPAHAX1745-247310.1038/s41567-018-0115-y; P. Campagne-Ibarcq etal., Phys. Rev. Lett. 120, 200501 (2018)PRLTAO0031-900710.1103/PhysRevLett.120.200501; N. Leung etal., npj Quantum Inf. 5, 18 (2019)2056-638710.1038/s41534-019-0128-0; Y. P. Zhong etal., Nat. Phys. 15, 741 (2019)NPAHAX1745-247310.1038/s41567-019-0507-7; A. Bienfait etal., Science 364, 368 (2019)SCIEAS0036-807510.1126/science.aaw8415]. Adiabatic protocols can overcome channel loss by transferring quantum states without populating the lossy communication channel. Here, we present a unique superconducting quantum communication system, comprising two superconducting qubits connected by a 0.73m-long communication channel. Significantly, we can introduce large tunable loss to the channel, allowing exploration of different entanglement protocols in the presence of dissipation. When set for minimum loss in the channel, we demonstrate an adiabatic quantum state transfer protocol that achieves 99% transfer efficiency as well as the deterministic generation of entangled Bell states with a fidelity of 96%, all without populating the intervening communication channel, and competitive with a qubit-resonant mode-qubit relay method. We also explore the performance of the adiabatic protocol in the presence of significant channel loss, and show that the adiabatic protocol protects against loss in the channel, achieving higher state transfer and entanglement fidelities than the relay method.

Computational Analysis of Electron Transfer Kinetics for CO2 Reduction with Organic Photoredox Catalysts.

We present a fundamental description of the electron transfer (ET) step from substituted oligo(p-phenylene) (OPP) radical anions to CO2, with the larger goal of assessing the viability of underexplored, organic photoredox routes for utilization of anthropogenic CO2. This work varies the electrophilicity of para-substituents to OPP and probes the dependence of rate coefficients and interfragment interactions on the substituent Hammett parameter, σp, using constrained density functional theory (CDFT) and energy decomposition analysis (EDA). Large electronic couplings across substituents indicates an adiabatic electron transfer process for reactants at contact. As one might intuitively expect, free energy changes dominate trends in ET rate coefficients in most cases, and rates increase with substituent electron-donating ability. However, we observe an unexpected dip in rate coefficients for the most electron-donating groups, due to the combined impact of flattening free energies and a steep increase in reorganization energies. Our analysis shows that, with decreasing σp, flattening OPP LUMO levels lower the marginal increase in free energy. EDA reveals trends in electrostatics and charge transfer interactions between the catalyst and substrate fragments that influence free energy changes across substituents. Reorganization energies do not exhibit a direct dependence on σp and are largely similar across systems, with the exception of substituents containing lone pairs of electrons that exhibit significant deformation upon electron transfer. Our study therefore suggests that while a wide range of ET rates are observed, there is an upper limit to rate enhancements achievable by only tuning the substituent electrophilicity.

High-fidelity quantum state transfer through a dissipative quantum data bus**Supported by the Shandong Provincial Natural Science Foundation under Grant No. ZR2016AM18 and the National Natural Science Foundation of China under Grant No. 61675118.

We propose and analyze a robust quantum state transfer protocol through a scalable quantum data bus that consists of a network of controlled dissipative modules. In particular, we first demonstrate the ability to achieve perfect state transfer between two distinct quantum sites which are adiabatically coupled to the data bus in non-dissipative situation. We then consider the role of dissipation in adiabatic quantum state transfer via using Born–Markov master equation in the standard Lindblad form. Numerical simulation shows that the dissipation effect on the quality of transmission can be suppressed by engineering the network couplings of data bus properly.

Accelerating adiabatic light transfer and split in three-waveguide couplers via dressed state

We theoretically perform a dressed state approach to investigate a fast adiabatic light transfer and split in the three-waveguide coupled system. We compare the performance of the waveguide couplers based on the dressed-state method with the stimulated Raman adiabatic passage (STIRAP) couplers. We find that the dressed-state couplers can achieve a higher fidelity at a shorter device length and can be more robust against various uncertainties than the original STIRAP couplers.

Speeding up the Generation of Entangled State between a Superconducting Qubit and Cavity Photons via Counterdiabatic Driving

AbstractOptimal generation of entangled states is of critical significance for robust quantum information processing. An effective scheme is presented for speeding up the generation of an entangled state between a superconducting qubit and microwave photons via counterdiabatic driving. At a magic bias point, the first three levels of a charge‐phase quantum circuit constitute an effective qutrit. An entangled state based on adiabatic population transfer is first achieved. By the technique of shortcuts to adiabaticity, a counterdiabatic driving is applied to the qutrit, which then accelerates the entanglement generation significantly. Moreover, with the accessible decoherence rates, the rapid operations in a shortcut way are highly robust when compared with adiabatic manipulations. The scheme could offer a promising approach toward optimal preparation of entangled states with superconducting artificial atoms in circuit quantum electrodynamics, experimentally.

Electron Transfer Kinetics in a Deep Eutectic Solvent.

Electron transfer (ET) kinetic rate constants ks in Ethaline (1:2 choline chloride + ethylene glycol) have been measured for two common redox couples (ferrocene/ferrocenium and ferrocyanide/ferricyanide) on a glassy carbon electrode and compared with ET kinetics in ionic liquids and classical organic solvents in the same conditions (acetonitrile and water). Particular care has been taken to treat ohmic drop in DES. For both couples, we found that ET rate constants are just a little lower than those measured in classical solvents (around 50% or less). These results contrast with ET rates in ionic liquids where electron transfers are considerably slower (100 times lower). Data are discussed as a function of the solvent relaxation time using Marcus Theory for an adiabatic electron transfer.

Adiabatic electron charge transfer between two quantum dots in presence of 1/f noise

Controlled adiabatic transfer of a single electron through a chain of quantum dots has been recently achieved in GaAs and Si/SiGe based quantum dots, opening prospects for turning stationary spin qubits into mobile ones, and solving in this way the problem of long-distance communication between quantum registers in a scalable quantum computing architecture based on quantum dots. We consider theoretically the process of such an electron transfer between two tunnel-coupled quantum dots, focusing on control by slowly varying the detuning of energy levels in the dots. We take into account the fluctuations in detuning caused by $1/f$-type noise that is ubiquitous in semiconductor nanostructures, and analyze their influence on probability of successful transfer of an electron in a spin eigenstate. With numerical and analytical calculations we show that probability of electron not being transferred due to $1/f^\beta$ noise in detuning is $\propto \sigma^2 t^{\beta-1}/v$, where $\sigma$ characterizes the noise amplitude, $t$ is the interdot tunnel coupling, and $v$ is the detuning sweep rate. Interestingly, this means that the noise-induced errors in charge transfer are independent of $t$ for $1/f$ noise. For realistic parameters taken from experiments on silicon-based quantum dots, we obtain the minimal probability of charge transfer failure between a pair of dots is limited by $1/f$ noise in detuning to be the on order of $0.01$. This means that in order to reliably transfer charges across many quantum dots, charge noise in the devices should be further suppressed, or tunnel couplings should be increased, in order to allow for faster transfer (and less exposure to noise), while not triggering the deterministic Landau-Zener excitation.

Adiabatic logic based circuit optimization for ultra low power applications

In this paper authors have presented a design and experimentation evaluation of circuit optimization inspired by adiabatic logic processing. The reported work inherent the power benefits associated with adiabatic charge transfer process. Simultaneously it also addresses an important issue of optimizing the high transistor count as required in traditional adiabatic logic families. Therefore the proposed hybrid adiabatic logic family not-only optimize the circuit area along with power but also it removes the requirement of dual polarity inputs for circuit actuation. Different circuits are optimized and implemented using the reported work in 180nm technology with trapezoidal power clock. The results obtained are compared with circuits available in previous works. The functional verification and result measurements proved the advantages associated with the proposed circuit optimization for energy efficient implementation for very-large scale integrated (VLSI) circuits

Broadband integrated polarization beam splitting based on anisotropic adiabatic transfer of light

A concept for the realization of waveguide-based polarization beam splitters working over a wide spectral range is presented. The adiabatically evolving three-waveguide system is inspired by the quantum-mechanical stimulated Raman adiabatic passage process and involves waveguides with an anisotropic refractive index contrast. It is shown that an index contrast ratio of 5 is sufficient to obtain excellent efficiency and output polarization purity over a spectral range approximately equal to $350$ nm centered at a wavelength of 1550 nm. The center wavelength can be easily modified by tuning the parameters of the waveguides.

Why Silicon Doping Accelerates Electron Polaron Diffusion in Hematite.

It is common that dopants enhance the conductivity of hematite Fe2O3, a popular photoanode, but the origin of the enhancement remains unclear. We establish the detailed mechanism by performing ab initio molecular dynamics simulations on electron polarons (EPs) in Fe2O3, obtained by an excess electron (e@EP) and a substitutional Si doping (Si@EP). For the first time, we observe EP hopping in both pristine and doped Fe2O3. We find that the neighboring Fe-Fe distance is the main driving force for the EP hopping, which occurs by the adiabatic charge transfer mechanism. The EP transport is determined by interplay of probabilities to reach a favorable configuration and to hop in that configuration. The hopping barrier decreases as the Fe-Fe distance decreases; however, hops can take place at larger Fe-Fe distances, because such configurations are easier to achieve. Importantly, we demonstrate that the Si dopant speeds up the EP transfer process by increasing the EP mobility. The origin can be ascribed to the following three factors: longer Fe-O bonds, smaller activation energies, and creation of low energy metastable EP states, in Si@EP Fe2O3 compared to e@EP Fe2O3. Interestingly, the EP hopping is random in e@EP Fe2O3, but quasi-random in Si@EP Fe2O3 with specific pathways promoting efficient EP transfer. These new findings greatly enrich the understanding of charge transport in Fe2O3 photoanodes.

Shortcut to adiabatic light transfer in waveguide couplers with a sign flip in the phase mismatch

Employing counterdiabatic shortcut to adiabaticity (STA), we design short and robust achromatic two- and three- waveguide couplers. We assume that the phase mismatch between the waveguides has a sign flip at maximum coupling, while the coupling between the waveguides has a smooth spatial shape. We show that the presented coupler operates as a complete achromatic optical switch for two coupled waveguides and as an equal superposition beam splitter for three coupled waveguides. An important feature of our devices is that they do not require larger coupling strength as compared to previous designs, which makes them easier to realize in an experimental setting. Additionally, we show that the presented waveguide couplers operate at a shorter device length and are robust against variations in the coupling strength and the phase mismatch.

Large Current Driven Domain Wall Mobility and Gate Tuning of Coercivity in Ferrimagnetic Mn4N Thin Films.

Spintronics, which is the basis of a low-power, beyond-CMOS technology for computational and memory devices, remains up to now entirely based on critical materials such as Co, heavy metals and rare-earths. Here, we show that Mn4N, a rare-earth free ferrimagnet made of abundant elements, is an exciting candidate for the development of sustainable spintronics devices. Mn4N thin films grown epitaxially on SrTiO3 substrates possess remarkable properties, such as a perpendicular magnetization, a very high extraordinary Hall angle (2%) and smooth domain walls at the millimeter scale. Moreover, domain walls can be moved at record speeds by spin-polarized currents, in absence of spin-orbit torques. This can be explained by the large efficiency of the adiabatic spin transfer torque, due to the conjunction of a reduced magnetization and a large spin polarization. Finally, we show that the application of gate voltages through the SrTiO3 substrates allows modulating the Mn4N coercive field with a large efficiency.

Production of ultracold 85Rb133Cs molecules in the lowest ground state via the B1Π1 short-range state.

We investigate the production of cold 85Rb133Cs molecules in the lowest vibronic level of the ground electronic state via the B1Π1 short-range state. The photoassociation (PA) spectra of the B1Π1 state, including newly observed transition to 2 vibronic levels, are obtained by high sensitivity time-of-flight mass spectrometry. Based on these PA spectra, the harmonic and anharmonic constants of vibronic states are obtained, resulting in predicted vibronic energies with an uncertainty of 1-2 cm-1. The B1Π1 (v = 3) state is found to have the maximum production rate for ground-state molecules with a value of 3(1) × 104 s-1, which is 3 times larger than the value via the previously studied 23Π0+ (v = 10, J = 0) state with two-photon cascade decay. The populations of J = 0, 1, and 2 rotational levels of X1Σ+ (v = 0) state molecules formed via the B1Π1 (v = 3, J = 1) state are measured to be around 20%, 40%, and 20%. To quantify the coupling strength between the B1Π1 (v = 3) state and X1Σ+ (v = 0) state, the transition dipole moment between them is measured to be 7.2(2) × 10-3ea0, which is also 3 times larger than the value between the 23Π0+ (v=10) state and X1Σ+ (v = 0) state, meaning the B1Π1 (v = 3) state has a stronger coupling with the X1Σ+ (v = 0) state. Our detailed measurements provide relevant parameters for investigation on direct stimulated Raman adiabatic passage transfer between the atomic scattering state and molecular bound state for 85Rb133Cs molecules.

Conservative and entropy stable solid wall boundary conditions for the compressible Navier–Stokes equations: Adiabatic wall and heat entropy transfer

We present a novel technique for the imposition of non-linear entropy conservative and entropy stable solid wall boundary conditions for the compressible Navier–Stokes equations in the presence of an adiabatic wall, or a wall with a prescribed heat entropy flow. The procedure relies on the formalism and mimetic properties of diagonal-norm, summation-by-parts and simultaneous-approximation-term operators, and is a generalization of previous works on discontinuous interface coupling [1] and solid wall boundary conditions [2]. Using the method of lines, a semi-discrete entropy estimate for the entire domain is obtained when the proposed numerical imposition of boundary conditions are coupled with an entropy-conservative or entropy-stable discrete interior operator. The resulting estimate mimics the global entropy estimate obtained at the continuous level. The boundary data at the wall are weakly imposed using a penalty flux approach and a simultaneous-approximation-term technique for both the conservative variables and the gradient of the entropy variables. Discontinuous spectral collocation operators (mass lumped nodal discontinuous Galerkin operators), on high-order unstructured grids, are used for the purpose of demonstrating the robustness and efficacy of the new procedure for weakly enforcing boundary conditions. Numerical simulations confirm the non-linear stability of the proposed technique, with applications to three-dimensional subsonic and supersonic flows. The procedure described is compatible with any diagonal-norm summation-by-parts spatial operator, including finite element, finite difference, finite volume, discontinuous Galerkin, and flux reconstruction schemes.