Adiabatic Temperature Research Articles

Interplay of c- and a-domains on the anomalous electrocaloric effect in BaTiO3 (001) single crystals

Electrocaloric effects of adiabatic temperature change via the application of external electric fields are explored for energy-efficient solid-state refrigeration. These effects are typically estimated from the thermodynamic analyses of polarization and field in electrocaloric materials, which implies that higher field application gives larger temperature changes. However, this may not be always true. Here, using both indirect and direct methods, we report an anomalous effect where larger thermal changes occur by applications of lower fields in a multi-domain BaTiO3 (001) single crystal. A large temperature change of 1.9 K under a low field change of 8 kV/cm at 404 K is observed in a multi-domain BaTiO3 (001) single crystal in comparison to that of 1.4 K at a high field change of 30 kV/cm. We attribute this counterintuitive effect to the interplay of the c- and a-domains in the BaTiO3 (001) single crystal under the influence of temperature and field changes. This work provides a fundamental understanding of the complex role of domains in governing the electrocaloric response of ferroelectric materials which is often overlooked but critical for their practical applications.

Combustion and thermodynamics properties of erythritol tetranitrate-based energetic films composed by electrospinning nano fibers

ABSTRACT High energy composite films made from high explosives has important applications in pyrotechnics. In this study, electrostatic spraying was used to prepare energy-containing films based on 1,2,3,4-butanetetrol tetranitrate (ETN). The results show that all energy containing films are made of nanofibres. They have excellent hydrophobicity and combustion properties. In particular, monolayer films in which ETN is the main energy containing substance. Once ignited, the trace monolayer film generates a maximum pressure of 0.85 MPa and an adiabatic flame temperature of 2,855 °C. For single and double layer films, the heat of combustion can reach 9899 J/g and 11975 J/g respectively. The level of combustion heat can also be controlled by adjustment of the ETN content. The results of the thermo-properties performance evaluation show that by optimizing the nanostructure, the ETN-based energy-containing fiber membranes can meet the requirements of advanced pyrotechnic products. In particular, there is great potential in the metastable intermixed composites (MICs) field.

Convective heat transfer parameters in the film cooling with thermal radiation

Thermal radiation is a large contributor to the total heat transfer of combustion systems so that it cannot be neglected, with the improvement of gas temperature and infrared stealth requirements. This paper deeply investigated the convective parameters in film cooling with thermal radiation through theoretical analysis and numerical simulation. A method to obtain the convective driving temperature under radiation was proposed and demonstrated. Research found that the film cooling effectiveness with radiation should be expressed by the mixing temperature rather than the adiabatic wall temperature. Although heat transfer and mass transfer under radiation cannot be theoretically analogized due to the radiant source term in the energy equation, the concentration cooling effectiveness without and with radiation remains approximately the same. The numerical results indicate that although conjugate coupling plays a crucial role in determining convective and radiative heat fluxes, the coupling of radiation and convective parameters is very weak. Radiation has little influence on the film cooling effectiveness (η) and the convective heat transfer coefficient (hf). Convective parameters can be decoupled from radiation with negligible loss of accuracy. This allows the non-radiation convective parameters η and hf to be directly used for calculating the convective heat flux under radiation, with relative deviations of less than 5%.

Comprehensive Experimental Assessment Of Unsteady Pressure And Heat Flux In A Small-Core Turbine Over-Tip Shroud

Abstract For novel high-speed small core turbines, with tip clearance below 0.5mm, even small blade-to-blade tip clearance variation is significant. The assessment of these complex flows is pertinent to the design of the next generation of small-core turbines. This manuscript provides a thorough experimental analysis of the shroud?s unsteady heat flux and static pressure in a small-core squealer-tip blade turbine. Atomic Layer Thermopile sensors and fast response pressure transducers were used to perform high-frequency acquisition at 2MHz around the 51% axial blade chord on the shroud. Measurements were taken at engine-representative conditions at several operational conditions and tip clearances. The signals were phase-locked averaged over the revolution period and synchronized to identify individual blade and row signatures. The linear relationship between the rotational tip Reynolds and the static pressure ratio across the blade tip reveals the transition point to reverse over-tip flows. Total heat flux is decomposed into different steady and unsteady heat flux contributions. It is demonstrated that the adiabatic wall temperature governs the unsteady heat flux and contributes to one third of the total surface heat flux. A linear trend was observed between the unsteady heat flux and the tip clearance measured at the pressure and suction side rims. Similar trends were observed between the local heat flux and the pressure ratio across the tip. A comparison with CFD predictions highlights some limitations on resolving the detached and secondary flows, evidencing the necessity of complementary experimental data.

Residual Ferromagnetic Regions Affecting the First-Order Phase Transition in Off-Stoichiometric Fe-Rh.

Among the magnetocaloric materials featuring first-order phase transitions (FOPT), FeRh is considered as a reference system to study the FOPT because it is a "simple" binary system with a CsCl structure exhibiting a large adiabatic temperature change. Recently, ab initio theory predicted that changes in the Fe/Rh stoichiometry in the vicinity of equiatomic composition strongly influence the FOPT characteristics. However, this theoretical prediction was not clearly verified experimentally. Here, we investigated the composition dependence of the transitional hysteresis in FeRh. It is shown that a Fe excess of only 1 at. % induces a ferromagnetic state in the whole temperature range (from 5 K up to Tc) for a minor portion of the sample (≈10%), while 5 at. % is enough to completely eliminate the FOPT. Element-specific X-ray magnetic circular dichroism (XMCD) measurements suggest that this ferromagnetic contribution arises from residual FeRh ferromagnetic regions. We attribute the formation of such domains to Fe antisite defects, as Mössbauer spectroscopy demonstrates the presence of Fe atoms located at the 1b (Rh) sites in the CsCl-type structure. As a consequence, compared with the equiatomic composition, the slightly Fe-rich sample exhibits completely different FOPT properties, influencing the magnetocaloric performances. Thus, our study sheds light on the origin of the remarkable stoichiometric sensitivity of the FOPT behavior in FeRh. These insights have broader implications for understanding FOPT dynamics and the role of residual ferromagnetic domains.

Large Room-Temperature Electrocaloric Effect in Lead-Free Relaxor Ferroelectric Ceramics with Wide Operation Temperature Range

In order to obtain large room-temperature electrocaloric effect (ECE) and wide operation temperature range simultaneously in lead-free ceramics, we proposed designing a relaxor ferroelectric with a Tm (the temperature at which the maximum dielectric permittivity is achieved) near-room temperature and glass addition. Based on this strategy, we designed and fabricated lead-free 0.76NaNbO3–0.24BaTiO3 (NN-24BT) ceramics with 1wt.% BaO–B2O3–SiO2 glass addition, which showed distinct relaxor ferroelectric characteristics with strongly diffused phase transition and a Tm near-room temperature. Based on a direct measurement method, a large ΔT (adiabatic temperature change) of 1.3 K was obtained at room temperature under a high field of 11.0 kV mm−1. Additionally, large ECE can be maintained (>0.6 K@6.1 kV mm−1) over a broad temperature range from 23 °C to 69 °C. Moreover, the ECE displayed excellent cyclic stability with a variation in ΔT below ±7% within 100 test cycles. The comprehensive ECE performance is significantly better than other lead-free ceramics. Our work provides a general and effective approach to designing lead-free, high-performance ECE ceramics, and the approach possesses the potential to be utilized to improve the ECE performance of other lead-free ferroelectric ceramic systems.

Excellent Magnetocaloric Properties near 285 K of Amorphous Fe88Pr6Ce4B2 Ribbon

A novel amorphous Fe88Pr6Ce4B2 ribbon with better magnetocaloric properties near 285 K is reported in the present work. The Fe88Pr6Ce4B2 ribbon exhibits a typical second-order ferromagnetic–paramagnetic transition near its Curie temperature (Tc, ~284 K), with a maximum magnetic entropy change (−ΔSmpeak) of ~4.15 J/(kg × K) under 5 T and a maximum adiabatic temperature rise (ΔTad) of ~2.57 K under 5 T, both of which are almost the largest amongst the iron-based metallic glasses with Tc = 285 ± 10 K. The high −ΔSmpeak enables several amorphous hybrids with table-like −ΔSm–T curves to be synthesized by appropriately proportioning the Fe88Pr6Ce4B2 ribbon and other amorphous ribbons with different Tc. The larger average −ΔSm and effective refrigeration capacity, as well as the appropriate temperature range, make the two amorphous hybrids potential candidates for use as refrigerants in household magnetic air conditioners.

Study on the Thermal Safety of 3,7‐Dinitro‐1,3,5,7‐Tetraazabicyclo[3.3.1]nonane Synthesized by Nitrolysis of Hexamine

AbstractThe thermal flow curves of the nitrolysis for the synthesis of 3,7‐dinitro‐1,3,5,7‐tetraazabicyclo[3.3.1]nonane (DPT) from hexamine in the presence of different amounts of acetic anhydride were obtained using reaction calorimetry. The maximum heat release rates during the feeding process, the corresponding maximum adiabatic temperature rises, and the Maximum Temperature of the Synthesis Reaction (MTSR) were determined, respectively. The thermal stability of the reaction product DPT and the reaction mixture was analyzed, and data on their thermal decomposition characteristics were obtained. The thermal decomposition kinetic model was utilized to simulate the stability under adiabatic conditions. TD24 (The temperature corresponding to the time required to reach the maximum reaction rate under adiabatic conditions for 24 hours) of the reaction mixture was calculated as 69.65°C. According to the thermal hazard parameters of the reaction, the process's hazard level under various acetic anhydride addition conditions was determined to be level 5 using the cooling failure scenario method.

Assessing and mitigating building fire risk based on the scenario clusters in Bangladesh

The increasing occurrence of fire hazards in residential buildings in Bangladesh has led to severe property damage, physical injuries, and fatalities, underscoring a critical research gap in effective fire risk management. This study aims to address this gap by identifying key fire risks and proposing mitigation strategies using BIM technology. The research employs a comprehensive survey and scenario clustering methodology to identify these risks and assess the efficacy of various fire-resistant materials. Data collection involved questionnaires distributed to 200 respondents, including building owners, occupants, engineers, and firefighters. These clusters are based on the metrics of fatality numbers and property damage to quantify fire risk. Findings highlight the significant role of wall and ceiling lining materials (RII = 0.919) in contributing to fire risk. Further analysis was conducted using a residential building model developed in Autodesk Revit and simulated in Pyrosim software, assessing various lining materials. Quantitative results demonstrated that fire brick is the most effective material, exhibiting the lowest heat release rate (968 kW/m2), minimum adiabatic surface temperature (28°C), minimum heat transfer coefficient (1.75 W/m2/K), and lowest surface burning rate (7.5e−08 Kg/m2/s). These results suggest that fire brick is the optimal choice for enhancing fire resistance in residential buildings.

Advanced Anti-icing and Deicing Strategies for Overhead Power Transmission Lines Based on Giant Magnetocaloric Effect of La0.7Ca0.254Sr0.046MnO3.

Perovskite manganates (AMnO3) exhibit diverse structural, thermal, electrical, and magnetic properties. Their strong magnetocaloric effect (MCE) near the Curie temperature (TC) makes them ideal for magnetic-thermal anti-icing and deicing in power transmission lines. Below TC, ferromagnetic AMnO3 produces heat through multiple mechanisms, with the changing magnetic field induced by the strong AC current, causing heat through magnetic hysteresis and eddy currents, alongside the direct MCE. Above TC, no heating is generated, as MCE is unfavorable, thus preventing additional energy loss at elevated temperatures. In this work, La0.7Ca0.254Sr0.046MnO3 with TC close to 0 °C were synthesized by solid-state reaction. It is found that particle size >10 μm is beneficial for a large MCE, based on the results of particle size dependence of MCE. The resulting maximum magnetic entropy change at 277 K is 7.69 J·kg-1·K-1, and an adiabatic temperature change of 3.87 K at 277 K is achieved under 5 T. The prototype cable is fabricated using a well-established wire drawing process. A climate-simulation chamber is employed for the anti-icing and deicing experiments. The prototype cables demonstrated a strong capability for deicing and anti-icing. This simple and cost-effective prototype cable shows significant potential for mitigating the icing problem of overhead high-voltage power transmission lines.

Preparation and Characterization of Ni-Mn-Ga-Cu Shape Memory Alloy with Micron-Scale Pores

Porous Ni-Mn-Ga shape memory alloys (SMAs) were prepared by powder metallurgy using NaCl as a pore-forming agent with an average pore size of 20–30 μm. The microstructure, phase transformation, superelasticity, and elastocaloric properties of the porous alloys were investigated. The prepared porous alloy had a uniform pore distribution and interconnected microchannels were formed. Cu doping can effectively improve the toughness of a porous alloy, thus improving the superelasticity. It was found that porous Ni-Mn-Ga-Cu SMAs have a flat stress plateau, which exhibits a maximum elongation of 5% with partially recoverable strain and a critical stress for martensite transformation as low as about 160 MPa. In addition, an adiabatic temperature change of 0.6 K was obtained for the prepared porous alloy at a strain of 1.2% at about 150 MPa. This work confirms that the introduction of porous structures into polycrystalline Ni-Mn-Ga SMAs is an effective way to reduce costs and improve performance, and provides opportunities for engineering applications.

Excellent mechanical properties and giant room-temperature elastocaloric effect in spark plasma sintered Ni-Co-Mn-Ti shape memory alloy

All-d-metal Heusler-type Ni-Mn-Ti alloys have emerged as a research focus in the field of elastocaloric refrigeration due to their remarkable elastocaloric effect. However, the mechanical properties of these materials present a challenge for their engineering applications. In this work, Ni37Co13Mn33.5Ti16.5 alloys with varying particle sizes were successfully prepared under different conditions using spark plasma sintering. The influence of particle size on the microstructure, mechanical properties and the elastocaloric effect were systematically explored. The results indicate that smaller particle sizes can significantly enhance mechanical properties during the SPS process, primarily due to grain refinement and the presence of Ti-rich second phases within the grains. Notably, compressive strength and fracture strain reached as high as 2225 MPa and 33 %, respectively, marking an increase of 145.9 % and 312.5 % over the as-cast alloy. Additionally, an unprecedently adiabatic temperature variation of 31.2 K was obtained upon loading in the sintered Ni-(Co)-Mn-Ti shape memory alloys.

COMBUSTION OF HYDROGEN IN OXYGEN-STEAM MIXTURE FOR INCREASING THE STEAM TEMPERATURE OF POWER PLANTS

In the work the problems that arise at combustion of hydrogen in oxygen-steam mixture for the purpose of combustion products (steam) mixing for heating steam, which is planned to be used in steam turbines of power plants were researched. The main problem is the formation of underburning H2 and, accordingly, the presence of O2, which have a negative effect on metals, and it will also prevent steam condensation in the condenser was determined. For solve this problem, calculations of the equilibrium concentrations of chemical reaction products in the combustion zone depending on the amount of ballast steam added to the oxidizer (oxygen) for the initial conditions: T0=528 K, p=0.1 MPa; T0=​​528 K, p=3.1 MPa; T0=​​584 K, p=10 MPa were made. The corresponding adiabatic temperatures were calculated. The dilution of the oxidant (oxygen) with steam significantly decreases the adiabatic temperature (Tb) and reduces the equilibrium concentrations of other substances in the combustion zone, but at the same time the laminar flame propagation velocity (SL) also significantly decreases was established. It is important when a certain concertation of ballast steam is achieved (the final percentage is determined by the design of the burner) there will be a sharp deterioration of combustion or even the formation of a flame will be impossible. The principal design of the hydrogen-oxygen-steam combustion chamber was proposed. The necessity of heating oxygen and hydrogen and the principle of determining the pressure under which it is advisable to supply oxygen and hydrogen to ensure the maximum intensification of mixing first of oxygen and steam, and then of the formed mixture and hydrogen, were substantiated. Bibl. 20, Fig. 5, Table 3.

Large reversible magnetocaloric effect in rare-earth molybdate RE2(MoO4)3 (RE: Gd and Tb) compounds

We report on the synthesis, structural, DC magnetic susceptibility studies on Gd2(MoO4)3 and Tb2(MoO4)3 polycrystals, prepared by conventional solid-state reaction method. Temperature and magnetic field (H) dependent magnetization and heat capacity measurements have been carried out to estimate the isothermal magnetic-entropy change (−ΔSm) and adiabatic temperature change (ΔTadi) in both rare-earth molybdates. No obvious long-range magnetic ordering can be found down to 2 K in both studied compounds. The estimated maximum value of –ΔSm at 3.5 K for 70 kOe is 31.1 J kg−1 K−1 and 16.7 J kg−1 K−1 in Gd2(MoO4)3 and Tb2(MoO4)3, respectively. Further, the calculated total-adiabatic temperature change for Gd2(MoO4)3 was 12.8 K, and Tb2(MoO4)3 has shown 9.8 K. The difference in the observed magnetocaloric and adiabatic temperature responses of Tb2(MoO4)3 compared to Gd2(MoO4)3 could be attributed to the presence of orbital angular moment of Tb3+ ions and relatively low-value of magnetization. Both the systems show a large magnetocaloric effect (MCE) (−ΔSm ∼ 12 J kg−1 K−1) even in low applied H (<20 kOe) attainable by a permanent magnet. Large magnetocaloric behaviour of Gd2(MoO4)3 and Tb2(MoO4)3 systems at a moderate field change along with very low electrical conductivity and the absence of thermal and magnetic field hysteresis in magnetization make them conducive to their use as promising magnetic refrigerants in the vicinity of liquid-helium temperatures.

Analysis of the Effect of More Fuel and Air Variations Excess Air on Combustion Process Simulation at a 10 kW Biomass Power Plant Using ASPEN PLUS

Abstract The utilization of biomass as an alternative energy can support the achievement of Net Zero Emissions. Each type of biomass fuel can provide different combustion effects from one another. This is due to the different heating values of each fuel. The calorific value is one of the things that affect the combustion performance of the biomass power plant. The main purpose of this study is to examine how different amounts of excess air used during the combustion process affect the outcomes. Combustion is a chemical reaction involving decomposition and gasification that simultaneously occurs in a space where a large amount of energy is released. The modeling and simulation of the decomposition and gasification processes were carried out using Aspen Plus. In this simulator, the decomposition process takes place in the Yields Reactor, while the gasification process occurs in the Gibbs Reactor. The biomass and ash components are characterized by their ultimate, proximate, and sulfur analysis. Then the excess air is varied to analyze its impact on the flame temperature from the reaction. The simulation findings emphasize crucial considerations for achieving complete combustion and reducing harmful gas emissions. Maintaining excess air close to the stoichiometric level ensures maximum combustion temperature at 1616.15 °C while minimizing excess air reduces NOx gas concentration. Approaching stoichiometric air level decreases CO gas and increases CO2, indicating more thorough combustion. However, excess air leads to lower adiabatic flame temperature due to nitrogen formation.

Acquisition Study of Downhole Explosion Limit in Air Drilling

Summary Downhole explosions adversely affect air drilling; however, the explosion limit can facilitate the adjustment of the flow rate to prevent downhole explosions. The downhole explosion limit, comprising lower and upper limits, can be determined through diverse methodologies. In this study, the interrelation between absolute enthalpy and adiabatic flame temperature (AFT) enabled the deduction of the lower explosion limit (LEL) prediction method, and an equilibrium between heat generation and heat transfer formed the basis for the upper explosion limit (UEL) prediction method. Additionally, a variable-volume apparatus was established to measure the explosion limit and adjust the pressure precisely without changing the amount of gas. The explosion limit of methane in the air was determined using both predicted and experimental methods, mirroring the scenarios of natural gas entering the wellbore during air drilling. The theoretical model exhibited the same reliability as the experimental results, and the prediction method for the explosion limit proved more efficient. Moreover, the effects of initial temperature and pressure on the explosion limit are discussed. The LEL decreased by an average of 15.5% when the initial pressure increased from 0.1 MPa to 2 MPa, while the UEL experienced a significant increase by an average of 152%. The UEL exhibited a logarithmic dependence on the initial pressure. The effect of the initial temperature on the explosion limit was noticeably less pronounced than that of the initial pressure. This study provides the essential theoretical basis and experimental results for avoiding downhole explosions during air drilling.

Phase change materials as hydrogen explosion suppressants: An experimental and kinetic investigation

To investigate the potential application of phase change materials as H2 explosion suppressants, in the present work, the inhibition effect of Na2HPO4·12H2O, K2HPO4·3H2O, and Na2CO3·10H2O on H2 explosion were experimentally studied. The corresponding explosion suppression mechanism was calculated by using a comprehensive combustion model. Results showed that the selected phase change materials inhibited the H2 explosion, and Na2CO3·10H2O has the most significant effect for fuel-lean H2-air mixtures when 12 g was added. Of which the maximum explosion pressure (Pmax) and maximum rate of pressure rise (dp/dt)max were reduced by 26.6 % and 28.1 %, and maximum pressure increase time (tb) and peak pressure time(tc) were increased by 112.2 % and 120.3 %. The inhibition mechanism of Na2CO3·10H2O on H2 was revealed by numerical simulation. The adiabatic flame temperature (AFT) and laminar burning velocity (LBV) of H2-air mixture decrease with increasing hydrated salt addition, the free radicals H, O and OH have a decisive influence on the explosion process during which H decreases by 86.4 % at most. The chain initial reaction O + H2 ⇌ H + OH and the sodium-containing primitive reaction NaO + H + M ⇌ NaOH + M have the most significant influence on the combustion processes. The results of present work give a theoretical foundation for application the phase change materials in H2 explosion safety industry.

Investigation on the inhibition effect and mechanism of hydrogen explosion by 2-bromo-3,3,3-trifluoropropene

This study investigated the effect of 2-bromo-3,3,3-trifluoropropene (2-BTP, C3H2BrF3) on hydrogen explosion behavior through a combination of experiments and simulations. The maximum explosion pressure (pmax), maximum pressure rise rate ((dp/dt)max), and critical inhibition concentration (CIC), across different equivalence ratios (Φ) and inhibitor concentrations (V), were obtained via experiments. The changes in adiabatic flame temperature, mole fraction of active radicals and sensitivity coefficient throughout the reaction were analyzed using CHEMKIN. The fuel-like properties of 2-BTP and the carbon monoxide (CO) produced by decomposition led to a promoting effect on the lean hydrogen explosion, primarily due to the elementary reactions R31, R806 and R882. When Φ≥1.0, the capture of active radicals via elementary reactions such as R908, R1507, and R88 was enhanced, resulting in the dominance of inhibition and a corresponding inhibitory effect. Notably, 2-BTP exhibited an inhibitory effect for (dp/dt)max at any equivalence ratio. The CIC decreased from 10% to 4% when increasing equivalence ratios from 0.6 to 2.0. This work provides crucial data and a theoretical foundation for the prevention and control of hydrogen explosions.

Giant magnetocaloric effect of Ni-Co-Mn-Ti all-d Heusler alloys in high magnetic fields

Ni-Co-Mn-Ti all-d Heusler alloys are attracting considerable attention for solid-state caloric-cooling applications due to their promising combination of excellent caloric and mechanical properties. Here, we report on the maximum attainable magnetocaloric effect in Ni37Co13Mn34.5Ti15.5, which shows a first-order magnetostructural martensitic transformation around room temperature. Heat capacity measurements reveal a giant transition entropy change of 43.5J(kgK)\\protect \\relax \\special {t4ht=−}1 and are utilized to estimate the magnetocaloric effect as well as the magnetic fields required to saturate it in isothermal and adiabatic conditions. Confirming the results based on this approach, we achieve maximum isothermal entropy changes and directly measured adiabatic temperature changes of 37.8J(kgK)\\protect \\relax \\special {t4ht=−}1 and -20.2K, respectively. Thus, the herein reported maximum attainable magnetocaloric effect outperforms classical Ni-Mn-based Heusler alloys, such as Ni(-Co)-Mn-In. Especially the saturated adiabatic temperature change surpasses all previously published values of magnetic field-induced first-order phase transitions measured around room temperature in pulsed magnetic fields in recent years. Thereby, we demonstrate that Ni(-Co)-Mn-Ti Heusler alloys are particularly suitable for the application of sufficiently large external stimuli to fully induce the phase transition and exploit their intrinsically large caloric effect.

Enhancement in Magnetic and Magnetocaloric Properties of CoFe2O4 Nanofibers at Lower Temperatures

AbstractThis research paper investigates new and first insights into the magnetic and magnetocaloric properties of one-dimensional (1D) cobalt ferrite CoFe2O4 (CFO) nanofibers (NFs) fabricated using a sol–gel-based electrospinning technique, focusing in particular on their behavior at low temperatures for specific applications. The microstructural, structural, magnetic, and magnetocaloric properties of the calcined CFO NFs were explored. The microstructure of the NFs, with an average diameter of 210 nm, was examined by scanning and transmission electron microscopy (SEM, TEM). The x-ray diffraction (XRD) of the CFO NFs showed a pure cubic close-packed (ccp) spinel crystalline structure with the Fd$$\overline{3}$$ 3 ¯ m space group. The Raman spectroscopic studies further confirm the cubic inverse spinel phase. The magnetic properties were explored as a function of temperature, ranging from 10 K to 300 K, and ferromagnetic behavior was observed with the highest saturation magnetization of 75.87 emu/g and coercivity of 723 Oe at room temperature. The variation of the magnetic entropy was measured indirectly using the Maxwell approach with an increasing magnetic field. A maximum of $$\left| {\Delta S} \right|$$ Δ S = 1.71 J/K was reached around 32 K. At 180 K, the associated adiabatic temperature change, ΔTmax, was 0.93 K, with a large RCP value of 7.58 J/kg, which is reasonably high for the corresponding nanoparticles (NPs). This work suggests that 1D CFO NFs offer a promising route for the production of nanostructured magnetic materials, potentially impacting various electronic and electromagnetic device applications at low temperatures.