Adequate Wastewater Treatment Research Articles

Analysis of Pollutant Sources from Community Health Center Activities in Mataram City

Health centers are health service facilities that produce waste containing microorganisms, toxic chemicals and radioactive materials that are dangerous and can pose risks to health and the environment. The purpose of this study was to determine the sources of health center waste and the types of waste from health center activities. This research method is a type of cross-sectional study, and data collection is done by filling out a questionnaire. The results of the study are the sources of health center waste, namely from the activities of the dental clinic, laboratory, Maternal and Child Health room, and the Emergency Unit room. The types of health center waste are liquid, domestic, solid medical, and toxic and hazardous. For the processing of liquid waste, all health centers in Mataram City have adequate wastewater treatment plants, either with a biofilter wastewater treatment plant system or other types of wastewater treatment plants, from 11 health centers, which have carried out sorting and have temporary storage places, namely 8 health centers. The process of managing medical waste involves sorting, transportation, storage and final processing with a third party. The weak point of B3 waste management is in the recording and sorting system of B3 solid waste and routine reporting of environmental management efforts and environmental monitoring efforts to related agencies that have not been able to be carried out by all existing health center agencies.

Ultrasonically Assisted Electrocoagulation Combined with Zeolite in Compost Wastewater Treatment

In this paper, the possibility of combining electrocoagulation (EC), ultrasound, and the addition of zeolite for wastewater treatment was investigated for the first time. The following combinations of hybrid processes were tested: electrocoagulation with zeolite (ECZ), simultaneous electrocoagulation with zeolite and ultrasound (ECZ+US), and two-stage electrocoagulation with zeolite and ultrasound (US+Z - EC), carried out with three different electrode materials. The results show that the simultaneous assistance of ultrasound in the ECZ leads to a lower increase in pH, while the temperature increase is higher. Regarding the COD, the assistance of ultrasound is only useful for Zn electrodes in the two-stage US+Z - EC, while the reduction in voltage consumption occurs for Fe and Al electrodes. Ultrasonic assistance caused more damage to the anodes, but anode consumption was reduced for Al and Zn electrodes. The total amount of zeolite that can be recovered is between 55–97%, and recovery is higher in systems with higher turbidity reduction. Good settling ability is only achieved with Al and Fe electrodes in simultaneous performance. Taguchi’s orthogonal L9 array design was applied to analyze the effects of electrode material, process type, mixing speed, and time duration on COD decrease, settling velocity, electrode, and voltage consumption. The results show that the use of ultrasound does not contribute to the desired result and generally only has a favorable effect on voltage and electrode consumption, while it has no positive effect on settling ability or COD decrease. Furthermore, although longer times and higher mixing speeds negatively impact cost due to voltage and electrode consumption, it is advisable not to choose the shortest duration and lowest speed to obtain adequate wastewater treatment quality.

Characterization of biofilm formation and multi-drug resistance among Pseudomonas aeruginosa isolated from hospital wastewater in Dhaka, Bangladesh.

Hospital wastewater has been identified as a hotspot for the emergence and transmission of multidrug-resistant (MDR) pathogens that present a serious threat to public health. Therefore, we investigated the current status of antibiotic resistance as well as the phenotypic and genotypic basis of biofilm formation in Pseudomonas aeruginosa from hospital wastewater in Dhaka, Bangladesh. The disc diffusion method and the crystal violet assay were performed to characterize antimicrobial resistance and biofilm formation, respectively. Biofilm and integron-associated genes were amplified by the polymerase chain reaction. Isolates exhibited varying degrees of resistance to different antibiotics, in which >80% of isolates showed sensitivity to meropenem, amikacin, and gentamicin. The results indicated that 93.82% of isolates were MDR and 71 out of 76 MDR isolates showed biofilm formation activities. We observed the high prevalence of biofilm-related genes, in which algD+pelF+pslD+ (82.7%) was found to be the prevalent biofilm genotypic pattern. Sixteen isolates (19.75%) possessed class 1 integron (int1) genes. However, statistical analysis revealed no significant association between biofilm formation and multidrug resistance (χ2 = 0.35, P = 0.55). Taken together, hospital wastewater in Dhaka city may act as a reservoir for MDR and biofilm-forming P. aeruginosa, and therefore, the adequate treatment of wastewater is recommended to reduce the occurrence of outbreaks.

Microfiber Fragment Pollution: Sources, Toxicity, Strategies, and Technologies for Remediation

With the pervasive consumption (currently >65% of total market shares and steadily increasing) of petroleum-derived synthetic textiles, the escalating concern of microfiber fragment (MF) pollution has emerged as a formidable menace to our ecological equilibrium. Over the lifetime (pre- and post-consumption) of these textiles, they shed tiny fibers recognized as MFs. These MFs are carriers of persistent organic pollutants and have been linked to cytotoxicity, oxidative stress, and genotoxicity, even at minimal exposures via air and water sources. Grounded in the state-of-the-art literature, this review discusses the primary and secondary sources of MF release, their fate, transport, environmental impacts, and novel technologies for MF pollutant remediation. Our results infer that MF pollution is a multifactorial issue with serious environmental and public health implications, as studies reported their presence in human blood, feces, and urine samples. We recommend a multifaceted approach to increase sanitation coverage, ensuring adequate wastewater treatment prior to environmental discharge for MF pollution mitigation. Additionally, transformation is warranted for consumers’ use, care, and purchase behavior of textile products. Government regulation of fast fashion (a major user of synthetic textiles), exemplified by recent French legislation, is essential to preventing microfiber pollution. We urge similar policy-making efforts globally to safeguard public health.

Treatment of Slaughterhouse Wastewater through a Series System: Upflow Anaerobic Reactor and Artificial Wetland

Slaughterhouse wastewater is characterized by high concentrations of organic matter. This creates a need to explore methods for its treatment before discharge. This study evaluated the efficiency of an integrated treatment process consisting of a laboratory-scale upflow anaerobic sludge blanket reactor and a pilot-scale horizontal subsurface flow wetland. This treatment was used for (i) the removal of organic matter through anaerobic–aerobic microbiological processes, (ii) the conversion of organic matter from hydraulic processes, and (iii) for bioremediation and phytoremediation. The treatment system was evaluated at hydraulic retention times (HRTs) of 7.5, 5.0, and 2.5 d; during the investigation, the influence of the HRTs on the removal efficiency of the system was evaluated. High efficiencies of 85% and 75% were obtained for CODT and BOD, respectively, at an HRT of 7.5 d. The highest overall efficiency for the removal of total solids was observed at an HRT of 2.5 d. The results obtained confirm the feasibility of implementing the suggested system as an alternative for the adequate and sustainable treatment of slaughterhouse wastewater, and the system can be applied to slaughterhouses with similar conditions to those in this study.

Design, implementation, and evaluation of a short rotation coppice system for wastewater treatment and resource recovery in India

Despite growing health concerns and increasing water scarcity, adequate wastewater treatment and reuse remains limited in India. Low-cost, decentralised, and nature-based on-site sanitation systems could play a key role in a circular water approach. This paper evaluates the performance of a Wastewater Fertigated Short Rotation Coppice (wfSRC) system based on willow, poplar, and bamboo species as a potential solution, offering low-cost, efficient water treatment, and high biomass production. Through a full-scale wfSRC pilot plant (250 m3·day−1 municipal wastewater on 6864 m2) established at Aligarh Muslim University, Uttar Pradesh, India, treatment capacities, biomass production rates, and contamination tolerance of different willow, poplar, and bamboo species were investigated. The chemical compositions of incoming wastewater, percolation water, soil, and biomass were monitored regularly. Despite the high load, all plant sections of the wfSRC system showed efficient removal of wastewater-originated pollutants. BOD5 and COD removal efficiencies were up to 99% and 95% respectively. Removal efficiencies for PO4-P reached 93% and for TN 91%. In general, total nitrogen and phosphate loads appear to be the limiting design parameters under the conditions at Aligarh to meet all discharge limits in India. Biomass production was projected to be >225 tDM·ha−1·yr−1 for bamboo, 65 tDM·ha−1·yr−1 for willow, and 206 tDM·ha−1·yr−1 for poplar. The pilot, conducted from March 2022 to June 2023, showcased how these densely planted agroforestry systems can effectively treat wastewater through natural processes such as oxidation, microbial degradation, and plant uptake. The findings demonstrate wfSRC's potential to serve as a nature-based, sustainable approach to wastewater treatment, particularly beneficial for suburban and rural areas in India and similar regions worldwide. This paper also provides recommendations for future implementation of wfSRC systems, emphasizing the need for careful planning regarding plant selection, system design, and operational strategies to maximize treatment efficiency and biomass production.

USE OF MICROWAVE RADIATION FOR EFFECTIVE PURIFICATION OF WASTEWATER FROM ORGANIC COMPOUNDS

This article is devoted to the problem of using microwave radiation as a potentially effective method of cleaning wastewater from organic compounds. The problem of cleaning wastewater from organic contaminants in the food industry requires highly effective methods since protein compounds in wastewater can cause environmental hazards and complicate the cleaning process. The purpose of the work was to investigate the effectiveness of using microwave radiation to purify wastewater from organic compounds, particularly protein impurities, and to establish the possibilities of this method for improving the process of water purification in the food industry. The article mainly examines the use of microwave radiation for this purpose and analyses its effect on proteins usually present in wastewater from the food industry. Experimental studies have shown the possibility of adequate wastewater treatment using microwave radiation. The advantages of using microwave heating, as well as its speed and regulation accuracy, are analysed, making this method attractive for use in wastewater treatment and other industrial production processes. The study includes an analysis of microwave radiation's effect on proteins commonly present in wastewater from the food industry. The research methodology involves modelling the composition of wastewater and using a microwave oven to process protein solutions. The results of the experiments demonstrate the possibility of adequate wastewater treatment using microwave radiation, which opens up prospects for further use of this method in industry and environmental protection. The results indicate the success of using microwave radiation to purify wastewater from organic compounds, notably protein pollution.

The ability of biochars from cookstoves to remove pharmaceuticals and personal care products from hospital wastewater

Adequate treatment of wastewater to remove micropollutants constitutes a major concern globally. Despite this, large volumes of untreated wastewater are released into the environment, mainly due to the cost involved. Biochars have been suggested to have the potential to remove pharmaceuticals and personal care products (PPCP) from wastewater, but, adsorption potential needs to be investigated further. Production of biochars should also preferably be sustainable and based on low-cost materials. This study investigated the ability of nine biochars produced in three cookstoves and from three feedstocks. All biochars were characterized and then applied in adsorption experiments, based on authentic hospital effluent. Our analytical method included 32 pharmaceuticals and personal care products, and 28 of these were detected and quantified in hospital wastewater effluent samples. Some PPCP were present in relatively high concentrations (more than 24 µg/L). Adsorption experiments showed that the biochars used in the investigation had average removal rates (RR) ranging from 14.2% to 65.5%. Removal rates also varied between and within cookstoves and feedstock. Although cookstove biochars with a low surface area in this study generally showed lower removal rates, results from surface characterization were not detailed enough to correlate the physicochemical properties of the pollutants with the adsorption. Further characterizations are therefore needed to point out the most important parameters involved in PPCP adsorption on cookstove biochars.

Pretreatment with fine bubbles for effective zinc ion precipitation and removal from zinc electroplating wastewater

AbstractHeavy metals such as zinc are widely used in plating plants for the processing of material surfaces; therefore, an adequate wastewater treatment is required afterwards to comply with wastewater regulations. However, the presence of chemicals such as degreasing agents in the wastewater generated from the plating process inhibits the formation of hydroxides, thereby making treatment of wastewater and compliance with the stipulated regulations difficult. Herein, the effects of fine bubbles on oil cleaning and wastewater treatment were investigated for developing an alternative cleaning technology to degreasing agents. The concentration of fine bubbles significantly affected the oil cleaning. The fine bubbles demonstrated remarkable cleaning of highly viscous oil, which was difficult to remove using pure water. The high cleaning effect of fine bubbles on oil was achieved because of the hydrophobic interaction of the bubbles. Furthermore, a decrease in cleaning effect was observed for samples with uneven shapes, which was attributed to the difficulty in penetration of fine bubbles in materials with irregularities. Furthermore, fine bubble cleaning exhibited better efficiency for wastewater treatment than degreaser cleaning. Therefore, fine bubble cleaning is speculated to be an excellent cleaning technology with high oil cleaning effectiveness and improved wastewater treatability.

Elevated levels of anthropogenic antibiotic resistance gene marker, sul1, linked with extreme fecal contamination and poor water quality in wastewater-receiving ponds.

In several low- and middle-income countries, such as India, the rapid construction of toilets to combat open defecation has not been matched with adequate wastewater treatment, resulting in extreme fecal contamination of the receiving environments. The sewage-receiving surface water bodies, typically close to the residences, are a potential hotspot for disease transmission and antibiotic resistance. Water, soil, and sediment samples from seven wastewater-receiving ponds (WRPs) were analyzed for water quality, chlorophyll-a, fecal contamination (yccT for Escherichia coli), 16S rRNA gene copies, and anthropogenic antibiotic resistance gene markers-sul1 and intI1. These WRPs were contrasted with two ponds that did not directly receive sewage. The water quality in the WRPs was comparable to raw sewage (BOD: 210-380mg/L; COD: 350-630mg/L; total-N: 100-190mg/L; and total-P: 6-21mg/L), and the relative levels of the DNA marker of E. coli were very high (yccT: 0.1% to ∼100% of total bacterial count) indicating extreme fecal contamination. The relative levels of sul1 and intI1 were 1-3 orders of magnitude higher in WRPs (sul1: 0.32%-10% of total bacterial count; and intI1: 0.2%-5% of total bacterial count) compared to the ponds that did not receive sewage directly. The relative levels of sul1 correlated with the DNA marker for the fecal indicator, E. coli (p-value<0.05; r=0.50; Spearman's rank correlation), and poor water quality.

Synthesis and characterization of titanium-substituted nanocrystalline Co2-Y hexaferrite: magnetically retrievable photocatalyst for treatment of methyl orange contaminated wastewater.

Rapid industrial growth causes considerable environmental havoc, adversely affecting human and aqueous life. It becomes a significant concern to deal with adequate wastewater treatment strategies by converging on water scarcity. This research work explored the synthesis of titanium-substituted Y-type barium hexaferrite (Co2-Y), having a general formula of Ba2Co2Fe12-xTixO22 (x = 0.0, 0.1, 0.2, 0.3, 0.4, and 0.5), using a facile nitrate-based sol-gel auto-combustion route and its suitability was investigated as a heterogeneous catalyst within the photo-Fenton-based degradation of methyl orange (MO), one of the significant pollutants generated from textile industries. Developing a thermochemically stable and magnetically separable heterogeneous catalyst for photocatalytic decomposition of nonbiodegradable organic dye from wastewater was also emphasized. The as-prepared nanocrystalline Co2-Y powders were analyzed using XRD, FTIR, DLS, UV-visible spectroscopy, SEM, VSM, and XPS. Furthermore, the photocatalytic degradation performance of pristine and titanium substituted Ba2Co2Fe11.6Ti0.4O22 ferrite, having the lowest bandgap value among all samples, was quantified and compared in terms of apparent rate constant (karc) value and turnover frequency values. The enriched photocatalytic performance was correlated with the existence of multi-valance states of transition metal cations and the availability of oxygen vacancy, confirmed by the surface chemistry using the XPS analysis. The modified (enhanced thermal and chemical stability) hexaferrite catalyst was magnetically separable and reusable without significant losses to its catalytic performance. This promising catalyst may be considered as a replacement for soft ferrite materials to catalyze the degradation of several other nonbiodegradable organic pollutants from wastewater in large-scale industries.

EFFECT OF FIXED FILAMENTOUS MEDIA ON BIOLOGICAL WASTEWATER TREATMENT

Adequate treatment of wastewater is important for the protection of the environment. In many countries, the existing conventional biological wastewater treatment systems are unable to meet the required standards. Therefore, the present research focused on the improvement of aerobic wastewater treatment plants by adding readily available cheap media. Plastic filamentous media was used due to its non-biodegradable property. The media length was 5 meters, but it was rolled into a spiral shape. The average removal of TDS and COD, without the media, was about 35% and 70%. After the media has been added, the removal efficiency improved to 55% and 95%. The experimental results demonstrated that the use of media is capable of improving the quality of effluents in wastewater treatment towards a better quality of effluent to be discharged to nature.

Electrochemical Reduction of Hexavalent Chromium in the Tannery Effluents in the Quindío Department, Colombia

Considering the essential participation of Colombia in leather production, it is necessary to consider new alternatives for wastewater degradation as a factor for its development. This industry is recognized worldwide as one of the most polluting water due to the chemical processes. The effluents of the leather industry constitute one of the most complex residues for their treatment due to the characteristics of their contaminant load. Thus, an adequate treatment of such wastewater is essential from an environmental and health viewpoint. This study aims to reduce hexavalent chromium in the tannery effluents of the Quindío Department. This study applied different electrochemical methods to simulated wastewater with hexavalent chromium concentrations similar to those of tannery effluents in the Quindío Department, such as cyclic voltammetry, linear sweep voltammetry, and chronoamperometry, using graphite rod and carbon cloth as working electrodes. Obtaining a chromium reduction of around 99.45% is a very satisfactory result considering that the tanning industries in Colombia do not comply with the legislation for eliminating chromium in their effluents. Finally, the electrochemical techniques employed proved to be very efficient and reliable for remediating industrial wastewater, specifically with the effluents treated in this study, since they have economically sustainable characteristics in terms of operating costs, in addition to being environmentally friendly.

Microfibers in laundry wastewater: Problem and solution

Data corroborated in this study highlights laundry wastewater as a primary source of microfibers (MFs) in the aquatic environment. MFs can negatively impact the aquatic ecosystem via five possible pathways, namely, acting as carriers of other contaminats, physical damage to digestive systems of aquatic organisms, blocking the digestive tract, releasing toxic chemicals, and harbouring invasive and noxious plankton and bacteria. This review shows that small devices to capture MFs during household laundry activities are simple to use and affordable at household level in developed countries. However, these low cost and small devices are unrealiable and can only achieve up to 40 % MF removal efficiency. In line filtration devices can achieve higher removal efficiency under well maintained condition but their performance is still limited compared to over 98 % MF removal by large scale centralized wastewater treatment. These results infer that effort to increase sanitation coverage to ensure adequate wastewater treatment prior to environmental discharge is likely to be more cost effective than those small devices for capturing MFs. This review also shows that natural fabrics would entail significantly less environmental consequences than synthetic materials. Contribution from the fashion industry to increase the share of natural frabics in the current textile market can also reduce the loading of plastic MFs in the environment.

Macro- and Microplastics in the Antarctic Environment: Ongoing Assessment and Perspectives

The number of scientists and tourists visiting Antarctica is on the rise and, despite the management framework for environmental protection, some coastal areas, particularly in the Antarctic Peninsula region, are affected by plastic contamination. The few data available on the occurrence of microplastics (&lt;5 mm) are difficult to compare, due to the different methodologies used in monitoring studies. However, indications are emerging to guide future research and to implement environmental protocols. In the surface and subsurface waters of the Southern Ocean, plastic debris &gt;300 µm appears to be scarce and far less abundant than paint chips released from research vessels. Yet, near some coastal scientific stations, the fragmentation and degradation of larger plastic items, as well as microbeads and microfibers released into wastewater from personal care products and laundry, could potentially affect marine organisms. Some studies indicate that, through long-range atmospheric transport, plastic fibers produced on other continents can be deposited in Antarctica. Drifting plastic debris can also cross the Polar Front, with the potential to carry alien fouling organisms into the Southern Ocean. Sea ice dynamics appear to favor the uptake of microplastics by ice algae and Antarctic krill, the key species in the Antarctic marine food web. Euphausia superba apparently has the ability to fragment and expel ingested plastic particles at the nanoscale. However, most Antarctic organisms are endemic species, with unique ecophysiological adaptations to extreme environmental conditions and are likely highly sensitive to cumulative stresses caused by climate change, microplastics and other anthropogenic disturbances. Although there is limited evidence to date that micro- and nanoplastics have direct biological effects, our review aims at raising awareness of the problem and, in order to assess the real potential impact of microplastics in Antarctica, underlines the urgency to fill the methodological gaps for their detection in all environmental matrices, and to equip scientific stations and ships with adequate wastewater treatment plants to reduce the release of microfibers.

Microbial contamination in surface water and potential health risks for peri-urban farmers of the Bengal delta.

Ensuring safe irrigation practices is vital to sustaining food production in water-scarce delta areas. Bangladesh and many other developing countries discharge untreated wastewater into their surrounding surface water bodies, serving as the primary irrigation source. This indirect irrigation of wastewater is believed to pose threats to the farmers, consumers and market vendors and may also affect crop and soil quality. To assess the risk, peri-urban farmers who use surrounding water bodies of Khulna city, Bangladesh, for crop irrigation were selected for the study. The microbial and heavy metal concentrations were measured in water samples collected from various locations over different seasons. For heavy metals As, Co, Ni, Cd, Cr, Cu and Pb, concentrations were below the detection limit, whereas Al, Fe, Mn, Ti and Zn were present but below the FAO recommendation limit for safe irrigation. The mean concentrations of microbial parameters were above the thresholds of WHO guidelines for crop irrigation intended for human consumption. Significant temporal variations in Faecal Coliform, E. coli and Enterococcus concentrations in the water samples were observed. The annual risk of infection for farmers was determined using the screening-level Quantitative Microbial Risk Assessment (QMRA). The results indicated that the annual probability of infection with pathogenic E. coli in different seasons ranges between 5×10-3 to 5×10-2, above the WHO's acceptable threshold for annual risk of infection for safe water reuse in agriculture. During the farmers' survey, around 45% reported health-related issues and more than 26% reported suffering from water-borne diseases after getting in contact with polluted surface water. This illustrates the actuality of the risks in practice. To ensure safe irrigation, the health risks need to be reduced below the acceptable limits. Suggested technical measures include adequate treatment of wastewater before disposal into rivers and access to protective equipment for farmers. This should be complemented by raising awareness through education programs among farmers to reduce accidental ingestion.

Treatment of Hydrothermal-Liquefaction Wastewater with Crossflow UF for Oil and Particle Removal.

This study aims to evaluate the application of ceramic ultrafiltration membranes in the crossflow mode for the separation of particles and oil in water emulsions (free oil droplets and micelles) from hydrothermal-liquefaction wastewater (HTL-WW) from the hydrothermal liquefaction of municipal sewage sludge. The experiments were carried out using one-channel TiO2 membranes with pore sizes of 30, 10 and 5 nm. The results showed that the highest stable permeability could be achieved with a membrane-pore size of 10 nm, which experienced less fouling, especially through pore blockage, in comparison to the two other pore sizes. Instead of observing an increase in the permeability, the application of a higher feed temperature as well as backwash cycles led to a clear increase in irreversible fouling due to the presence of surfactants in the HTL-WW. Among several physical and chemical cleaning methods, alkaline cleaning at pH 12 proved to be the most efficient in removing fouling and maintaining stable performance on a long-term basis. Ceramic-membrane ultrafiltration can be considered as an adequate first-stage treatment of real HTL wastewater.

Interaction between bioaccumulation and the efficiency of intermittent sand filters in wastewater treatment

Decentralized onsite wastewater treatment systems (OWTS) play an important role in alleviating the global carbon emissions pressure and meeting the United Nations Sustainable Development Goal for 2030. As a type of OWTS, intermittent sand filters (ISF) have a wide application in rural areas, but bioaccumulation caused bioclogging threatens its viability as a rural wastewater treatment technology. Proper understanding of the relationship between bioclogging and wastewater treatment is fundamental to the environmental sustainability of ISF. In this study, the interplay of ISF bioclogging and wastewater treatment efficiency is described by a mechanistic deterministic model to explore the role of bioclogging in ISF performance. The model incorporates variably saturated flows, reactive pollutant transport, bacterial growth, bioclogging caused soil permeability change, and reactive gas-phase oxygen transport and provides several insights regarding ISF operations. It is demonstrated that bioclogging as a result of wastewater treatment is necessary in maintaining adequate wastewater treatment efficiency. Bioclogging zone is the most active wastewater treatment region and the coupling between stimulated oxygen utilization rate and triggered oxygen replenishment rate is decisive in bioclogging development speed and effluent N profile. Overall, this study challenges the traditional negative viewpoint toward bioclogging, and the positive and negative aspects of bioclogging in ISF can be managed to promote the environmental sustainability of ISF.

A review of the adsorption-biological hybrid processes for the abatement of emerging pollutants: Removal efficiencies, physicochemical analysis, and economic evaluation

The limited efficiency of conventional wastewater treatment plants (WWTPs) in emerging pollutants (EPs) removal encourages the development of alternative technologies for the adequate treatment of wastewater, due to its adverse effects on human health and ecosystems. The biological, physical or chemical hybrid technologies to treat EPs results interesting since they can enhance the performance of WWTPs. Among them, hybrid adsorption/biological technology could offer different possibilities that are explored in this work (PAC-MBR, PACT/GAC-CAS, BAC configurations). In this way, different variations in the adsorption process have been considered: the form of the adsorbent, the feed to the system, and the type of biological process, either conventional activated sludge (CAS), membrane bioreactor (MBR) or biofilm systems. For each combination, the removal efficiency of micropollutants, classified according to their use into pharmaceuticals, personal care products (PCPs) and other micropollutants (mainly benzotriazoles) was analysed. From reported data, it was observed a beneficial synergistic effect of dipole moment and octanol-water partition coefficient on the removal efficiency of micropollutants by adsorption/biological hybrid technology. Finally, a preliminary economic evaluation of the powdered activated carbon in a conventional activated sludge reactor (PACT), powdered activated carbon-membrane bioreactor (PAC-MBR) and biological activated carbon (BAC) hybrid systems was carried out by analysing the capital expenditure (CAPEX) of plants for capacities up to 75,000 m3d-1. Likewise, estimations of adsorbent concentration for a hypothetical plant with a capacity of 10,000 m3d-1 is presented. Among these hybrid configurations, PAC-MBR achieved the highest micropollutant elimination percentages; however, it presents the highest CAPEX and activated carbon requirements.

Performance and biofilm-associated bacterial community dynamics of an upflow fixed-film microaerophilic-aerobic bioreactor system treating raw textile effluent

Textile wastewater contains numerous xenobiotic compounds which have several detrimental effects on aquatic and terrestrial ecosystems. Therefore, the adequate treatment of textile wastewater is essential. This study elucidated the biodegradation of raw textile effluent (RTE) in an upflow fixed-film microaerophilic bioreactor (UFMB) along with the characterization of its bacterial community dynamics at different hydraulic retention times (HRTs) and organic loading rates (OLRs). Among the various packing materials tested in the UFMB operation, wood charcoal was found to be the most suitable packing material for the establishment of biofilm and biodegradation of RTE. The steady-state performance of UFMB having wood charcoal as packing material achieved 81.97% of American dye manufacturers institute (ADMI) colour index removal, 73.08% of biochemical oxygen demand (BOD) removal and 80.47% of chemical oxygen demand (COD) removal at 2d HRT. Whereas, upon integration of the UFMB with the sequential aerobic bioreactor (UFMB-AB system), achieved better performances with 98.6% COD, 98% ADMI and 92% BOD removal from the RTE. Additionally, the combined UFMB-AB system effectively removed other contaminants such as sulphate, phenolics and nitrogenous compounds in the RTE. The biofilm was synergistically established by the bacterial community DR4 and the native community of RTE. In response to different HRTs and OLRs, the UFMB bacterial biofilm community experienced various shifts in its composition. However, a core microbiome persisted throughout the bioreactor operation. The imputed metagenome analysis of the established UFMB biofilm using phylogenetic investigation of communities by unobserved state reconstruction (PICRUSt), revealed the presence of several xenobiotic degradation and metabolism pathways with an abundance of various different oxidoreductase genes responsible for the biodegradation of dyes and other organic pollutants present in the RTE.