Ultrasonically Assisted Electrocoagulation Combined with Zeolite in Compost Wastewater Treatment

Abstract

In this paper, the possibility of combining electrocoagulation (EC), ultrasound, and the addition of zeolite for wastewater treatment was investigated for the first time. The following combinations of hybrid processes were tested: electrocoagulation with zeolite (ECZ), simultaneous electrocoagulation with zeolite and ultrasound (ECZ+US), and two-stage electrocoagulation with zeolite and ultrasound (US+Z - EC), carried out with three different electrode materials. The results show that the simultaneous assistance of ultrasound in the ECZ leads to a lower increase in pH, while the temperature increase is higher. Regarding the COD, the assistance of ultrasound is only useful for Zn electrodes in the two-stage US+Z - EC, while the reduction in voltage consumption occurs for Fe and Al electrodes. Ultrasonic assistance caused more damage to the anodes, but anode consumption was reduced for Al and Zn electrodes. The total amount of zeolite that can be recovered is between 55–97%, and recovery is higher in systems with higher turbidity reduction. Good settling ability is only achieved with Al and Fe electrodes in simultaneous performance. Taguchi’s orthogonal L9 array design was applied to analyze the effects of electrode material, process type, mixing speed, and time duration on COD decrease, settling velocity, electrode, and voltage consumption. The results show that the use of ultrasound does not contribute to the desired result and generally only has a favorable effect on voltage and electrode consumption, while it has no positive effect on settling ability or COD decrease. Furthermore, although longer times and higher mixing speeds negatively impact cost due to voltage and electrode consumption, it is advisable not to choose the shortest duration and lowest speed to obtain adequate wastewater treatment quality.