In this article, the remote estimation problem is addressed for a class of discrete-time complex networks under the influence of probabilistic quantization and amplify-and-forward (AF) relays. The underlying complex network model, which is inherently nonlinear and stochastic, is affected by additive process and measurement noises. Owing to the limited bandwidth of the transmission channel, the measurement outputs are quantized by a probabilistic quantizer prior to transmission. To enhance the signal quality over long-distance transmissions, the quantized measurements are sent to AF relays and subsequently forwarded to the estimator. Utilizing the unscented Kalman filter approach, a novel state estimator is designed to minimize an upper bound on the estimation error covariance. Moreover, sufficient conditions are derived to ensure that the estimation error is exponentially bounded in the mean-square sense. Lastly, the efficacy of the proposed scheme is illustrated through numerical simulations.