Addition Of Titanium Research Articles

Effect of Vanadium Addition on the Wear Resistance of Al0.7CoCrFeNi High-Entropy Alloy.

High-entropy alloys are of interest to many researchers due to the possibility of shaping their functional properties by, among other things, the use of alloying additives. One approach to improving the wear resistance of the AlCoCrFeNi alloy is modification through the addition of titanium. However, in this study, an alternative solution was explored by adding vanadium, which has a completely different effect on the material's structure compared to titanium. The effect of vanadium additives on changes in the microstructure, hardness, and wear resistance of the Al0.7CoCrFeNi alloy. The base alloys Al0.7CoCrFeNi and Al0.7CoCrFeNiV0.5 were obtained by induction melting. The results showed that the presence of vanadium changes the microstructure of the material. In the case of the base alloy, the structure is biphasic with a visible segregation of alloying elements between phases. In contrast, the Al0.7CoCrFeNiV0.5 alloy has a homogeneous solid solution bcc structure. The presence of vanadium increased hardness by 33%, while it significantly reduced friction wear by 73%. Microscopic observations of friction marks indicate differences in the wear mechanisms of the two materials.

Research on the influence of titanium addition on the structure and frictional performance of laser clad tin bronze coating

Cu has a high infrared light reflectivity, which leads to the easy formation of defects such as pores in copper alloys during the laser cladding process. The purpose of this research is to reduce the porosity of tin bronze coatings during laser cladding by adding titanium elements with high infrared absorption. The porosity of the coating was characterized using scanning electron microscopy, metallographic microscopy, energy-dispersive spectroscopy, and x-ray diffraction. The research results indicate that as the content of titanium element increases, the porosity within the coating first decreases and then increases. When the titanium addition was 2%, the minimum porosity of the coating was 0.034%. The microhardness of the samples was tested using a semiautomatic Vickers hardness tester, and the reciprocating dry friction performance at room temperature was tested using a UMT-3 friction tester. The incorporation of titanium significantly enhances the microhardness and frictional properties of the laser-clad tin bronze coating. Therefore, this study provides experimental data support for controlling the porosity and frictional properties of laser-clad tin bronze coatings through elemental composition.

Preparation and mechanical properties of 316L-Ti composites by Laser Powder Bed Fusion

Abstract To investigate the feasibility of additive manufacturing of energetic structural materials, this study fabricated 316L-Ti composites using Laser Powder Bed Fusion. The research examined the forming process parameters of 316L-Ti and analyzed the changes in relative density, defects, phases, and mechanical properties of the composites with varying laser energy densities. The results indicate that the primary defects in 316L-Ti composite samples are delamination and lack of fusion (LoF) pores. At high laser energy densities, delamination cracks are likely to occur, leading to significant delamination, warping, and even failure to form the samples. Conversely, at low laser energy densities, samples show minimal delamination but an increase LoF pores, leading to worsened mechanical properties. The addition of titanium results in the presence of both austenite and ferrite phases. Optimal results are achieved at a laser energy density of 120 W and a scanning rate of 1200 mm/s, yielding samples with minimal defects, achieving a density of 91.69% of the theoretical value, and demonstrating a compressive strength of 1191 MPa.

Development of in-Situ Method for Synthesis of TiCl2 Electrolyte

The Kroll process was developed in the 1960s and remains the main commercial process for titanium production. While the production of titanium sponge in large amounts has been established, its drawbacks include high energy consumption, toxicity, high GHG emissions, and the generation of iron-contaminated titanium scrap, which remain unsolved. Therefore, many researchers have attempted to develop alternative methods for titanium production in the past decades, and electrorefining is one of these methods. The titanium electrorefining process is based on the transfer of titanium from an impure electrode (anode) to another electrode (cathode) in the electrolyte environment. The electrolyte plays a huge role in the transport of titanium, as well as in the oxidation and reduction mechanisms on the electrodes. According to past research, it is important to maintain titanium species in the form of divalent titanium (TiCl2). An increase in trivalent titanium in the electrolyte requires more electric energy and results in lowered current efficiency and lower quality of deposits. The preparation of TiCl2 is complicated by its high hygroscopic ability and the high exothermicity of the reaction, which may cause the formation of higher titanium chlorides in gaseous form. Therefore, this study is focused on the development of an in-situ synthesis method for TiCl2 electrolyte. This method is based on the preparation of a CaCl2-NaCl-CuCl solution and the addition of titanium metal powder into the solution at elevated temperatures in an argon atmosphere. As a result of the synthesis, a CaCl2-NaCl-TiCl2 solution is obtained, along with a byproduct of synthesis, copper metal, which sediments in the shape of sponge or flakes at the bottom of the crucible. Thermodynamic equilibrium evaluation revealed that the optimal temperature for TiCl2 synthesis is within the range of 600-700 °C, and the ratio of titanium addition is within the range of 1.0-1.1Ti. Additionally, the influence of temperature and the ratio of titanium addition on synthesis was studied experimentally under the same conditions. TiCl2 electrolytes were prepared and analyzed using hydrogen volumetric analysis to quantify TiCl2 concentration, titration analysis to quantify TiCl3 concentration, and ICP analysis to quantify total Ti concentration in the solution. The sedimented copper byproduct was leached from the electrolyte and analyzed by SEM/EDS to quantify the reaction yield of titanium. Experimental results showed that TiCl2 can be successfully synthesized in molten CaCl2-NaCl and that the temperature of the synthesis process and the ratio of Ti added have a strong impact on the composition of the electrolyte, Ti concentration, copper residual content in the electrolyte, and reaction yield. The optimal temperature was in good agreement with theoretical evaluation and was found to be 650 °C. A stoichiometric ratio or slight excess of Ti (1.0-1.1Ti) is recommended for the highest reaction yield of TiCl2 synthesis at 650 °C.

Effect of Initial Intergranular Ferrite Size on Induction Hardening Microstructure of Microalloyed Steel 38MnVS6

In this study, we investigated the effect of grain size of an initial microstructure (pearlite + ferrite) on a resulting microstructure of induction-hardened microalloyed steel 38MnVS6, which is one topical medium carbon vanadium microalloyed non-quenched and tempered steel used in manufacturing crankshafts for high-power engines. The results show that a coarse initial microstructure could contribute to the incomplete transformation of pearlite + ferrite into austenite in reaustenitization transformation by rapid heating, and the undissolved ferrite remains and locates between the neighboring prior austenite grains after the induction-hardening process. As the coarseness level of the initial microstructure increases from 102 μm to 156 μm, the morphology of undissolved ferrite varies as granule, film, semi-network, and network, in sequence. The undissolved ferrite structures have a thickness of 250–500 nm and appear dark under an optical metallographic view field. To achieve better engineering applications, it is not recommended to eliminate the undissolved ferrite by increasing much heating time for samples with coarser initial microstructures. It is better to achieve a fine original microstructure before the induction-hardening process. For example, microalloying addition of vanadium and titanium plays a role of metallurgical grain refinement via intragranular ferrite nucleation on more sites, and the heating temperature and time of the forging process should be strictly controlled to ensure the existence of fine prior austenite grains before subsequent isothermal phase transformation to pearlite + ferrite.

Crack suppression in directed energy deposition of molybdenum

Additive manufacturing (AM) is a valuable tool for the fabrication and repair of refractory parts such as molybdenum alloys. Cracking is a common defect encountered during AM processing of refractory parts, that is generally associated with the segregation of light elements to grain boundaries which affect grain boundary cohesion and, ultimately, affect the final performance of the part. Similarly, because of the high melting points of refractory metals, lack-of-fusion defects are also common. The effect of build substrate and small alloying additions on suppression of defects during multilayer builds was investigated using directed energy deposition (DED) printing. Identical sample matrices were printed on three different build substrates: molybdenum (Mo), commercially pure titanium (Cp-Ti), and 316 stainless steel (316). Twenty-six usable samples were produced. Samples were cross sectioned, polished, and were characterized for total cross-section defect area. Additionally, samples from each substrate material were analyzed for grain boundary oxygen content. The strongest defect suppression, producing crack free material, was observed in samples printed on a Cp-Ti build substrate with a ten atomic percent addition of titanium in the molybdenum powder feed. The part quality was enhanced due to three factors: 1) the moderation of thermal diffusivity through a change in build plate material, 2) the suppression of light element segregation via increased solubility through titanium addition, and 3) a lack of brittle phase formation due to metallurgical compatibility of the build material with the build substrate. Analysis of defect area versus dimensionless number, π1, shows that increasing π1 reduced defects throughout the part.

AUBERT & DUVAL PER72

Abstract Aubert and Duval PER72 (NiCr18Co15TiMoAI alloy) is a precipitation hardening, nickel-base superalloy. The alloy is solid solution strengthened by additions of chromium, cobalt, molybdenum, and tungsten, while additions of titanium and aluminum provide precipitation strengthening. Aubert & Duval PER72 combines high strength with metallurgical stability as demonstrated by excellent impact strength retention after long exposures at elevated temperatures. It also exhibits good oxidation resistance, as well as excellent resistance to sulfide corrosion. This datasheet provides information on composition, physical properties, elasticity, and tensile properties. It also includes information on low temperature performance, high temperature performance, and corrosion resistance as well as forming and heat treating. Filing Code: Ni-787. Producer or source: Aubert & Duval S.A. (a member of the Eramet Group).

Impact of titanium modification on the performance improvement and phase change mechanism of ZnSb thin film

Phase change memory has emerged as a promising option for neuro-inspired and data-intensive AI applications, attracting significant attention from the semiconductor field recently. The performance of the device relies on the phase change material, aiming for enhanced thermal stability along with low power consumption. Nanocomposite ZnSb thin films with titanium dopant were prepared and their crystallization properties and mechanisms were investigated. Compared to pure ZnSb material, the addition of titanium can significantly enhance the temperature of crystallization and the 10-year data retention ability, both of which surpassing 16 °C. The obvious enhancement in thermal stability may be ascribed to the ionic bond formation between titanium and antimony elements, as indicated by differential charge calculations. Also, phase change memory cells with a diameter of 190 nm were fabricated using standard CMOS technology. The Ti-doped ZnSb thin film demonstrates rapid crystallization and amorphization within 50 ns while consuming low power at approximately 1.5 × 10−10 J. The decrease in power consumption may stem from the increase in band gap energy and a decrease in electrical conductivity, as confirmed by first-principles calculations. Both experimental and theoretical results prove that titanium doping can remarkably improve the physical properties of ZnSb thin film, facilitating the exploration and design of novel phase change materials with high thermal stability, low power consumption, as well as fast switching speed.

Can foliar application of Titanium and Zeolite Soil Addition Enhance Crisphead Lettuce Production, and Reduce N-Leaching or/and Volatilization?

Can foliar application of Titanium and Zeolite Soil Addition Enhance Crisphead Lettuce Production, and Reduce N-Leaching or/and Volatilization?

Manufacturing of Ni-Co-Fe-Cr-Al-Ti High-Entropy Alloy Using Directed Energy Deposition and Evaluation of Its Microstructure, Tensile Strength, and Microhardness.

High-entropy alloys (HEAs) have drawn significant attention due to their unique design and superior mechanical properties. Comprising 5-35 at% of five or more elements with similar atomic radii, HEAs exhibit high configurational entropy, resulting in single-phase solid solutions rather than intermetallic compounds. Additive manufacturing (AM), particularly direct energy deposition (DED), is effective for producing HEAs due to its rapid cooling rates, which ensure uniform microstructures and minimize defects. These alloys typically form face-centered cubic (FCC) or body-centered cubic (BCC) structures, contributing to their exceptional strength, hardness, and mechanical performance across various temperatures. However, FCC-structured HEAs often have low yield strengths, posing a challenge for structural applications. In this study, a Ni-Co-Fe-Cr-Al-Ti HEA was manufactured using the DED method. This study proposes that the addition of aluminum and titanium creates a γ + γ' phase structure within a multicomponent FCC-HEA matrix, enhancing the thermal stability and coarsening the resistance and strength. The γ' phase with an ordered FCC structure significantly improves the mechanical properties. Analysis confirmed the presence of the γ + γ' structure and demonstrated the alloy's high tensile strength and microhardness. This approach underscores the potential of AM techniques in advancing HEA production for high-performance applications.

Impact of Aluminium and Titanium Additives on Ignition and Combustion in Boron-Loaded Gelled Jet A-1 Fuel

ABSTRACT A high-energy metal has been identified as a possible supplementary energy source for liquid fuel, which can be used to fuel volume-limited propulsive devices. However, the stability of metal particles in liquid fuel is a significant disadvantage, which can be overcome by suspending the particles in the gel fuel network. Boron’s (B) high energy density makes it a potential choice as fuel or energetic fuel additive for propulsion systems. However, the combustion of boron particles is challenging due to a native oxide layer on the boron particle surface that acts as an inhibitor. The influences of aluminum and titanium addition into the gel fuel containing boron particles have been investigated in the present study to understand whether Al or Ti positively enhances the ignition and combustion of boron particles. A droplet combustion study was conducted for gel fuel samples containing boron, boron-aluminum, and boron-titanium combinations. The key analyses include the feature of droplet diameter regression, the effect of Al/Ti additive on the ignition delay of boron particles through spectroscopic analysis, combustion of boron particles through chemiluminescence measurement of intermediate species of boron combustion (BO2) and flame imaging, and analysis of combustion residues. The obtained results and corresponding analyses suggest that the addition of Al particles improves the ignition of boron. In contrast, Ti particles significantly enhance the combustion of boron particles loaded in gel fuel.

Flux enhancement with titanium or vanadium oxides addition for superior submerged arc welding of HSLA steel plates

A high-strength low-alloy (HSLA) steel plate of 10 mm thickness underwent submerged arc welding with enhanced fluxes containing additional titanium oxide (TiO2) or vanadium oxide (V2O5). The addition of TiO2 led to the development of a finer acicular ferrite structure but coarsening the carbide and martensite/austenite (M/A) constituents, which marginally improved the hardness, tensile strength, and ductility of weld metal. Conversely, incorporating V2O5 facilitated a substantial vanadium absorption (0.7 wt. %) in the weld metal, giving rise to a distinctive acicular microstructure less reliant on ferrite nucleation at non-metallic inclusions than conventional acicular ferrite. The distinctive microstructure, unique to vanadium steels, combined lath bainite with irregularly shaped granular bainite. The resultant dual-mode bainitic structure, coupled with a more uniform distribution of refined microphase constituents, outperformed the conventional acicular ferrite, delivering more than 20% and 13% improvements in yield and tensile strengths respectively, as evidenced by transverse tensile tests on the weld metals.

Microstructural, mechanical and neutron-attenuation properties of apatite-wollastonite doped by SiO2, Fe2O3, and TiO2

In this study, the preparation, physical characteristics, microstructural attributes, and fast neutron (FN) removal parameters of apatite-wollastonite (AW)-containing GCs doped with 10 % SiO2, Fe2O3, and TiO2 were reported. Glass-ceramics containing the AW crystal structure within the SiO2–CaO–Al2O3–MgO–P2O5–CaF2 glass system were prepared and doped with 10 % SiO2, Fe2O3, and TiO2 by weight. The microstructural and chemical evolution of the glass-ceramics were studied using SEM/EDS. The density and Vicker hardness of the samples were experimentally evaluated, while the fast neutron removal cross-sections (ΣR) were computed using standard equations. The SEM micrograph showed densely crystallised and crack-free surface surfaces. Silicon and titanium additions did not cause a significant increase in density. However, Fe doping had a higher effect on density. The values of ΣR for pristine, SiO2, TiO2, and Fe2O3-doped AW were found to be 0.0796 cm−1, 0.0832 cm−1, 0.0869 cm−1, and 0.0904 cm−1, respectively. Compared to some other materials, such as polymers, AW-10Fe showed better attenuation for fast neutrons. The investigated ceramics could be used in tissue engineering and fast neutron moderation functions.

Effect of different titanium addition methods on the properties of diamond/Cu composites

Due to the low bonding strength between diamond and copper, the thermal conductivity and mechanical strength of diamond/copper composites are affected. In order to improve the interface bonding strength, this paper prepared diamond/Cu composites with titanium element in two forms: adding titanium to the copper matrix and using titanium coated diamond particles, respectively. The microstructure and composition analysis of the materials were carried out through SEM, EDS, AFM, etc. The bending strength and thermal conductivity of titanium coated diamond/copper composites reached 230 MPa and 480 W/(m·K), respectively, which were higher than the bending strength and thermal conductivity of diamond/Cu composites with added titanium in the matrix (208 MPa and 127 W/(m·K) and significantly higher than the corresponding properties of pure diamond/Cu composites (69 MPa and 108 W/(m·K)). Pre coating a layer of titanium carbide on the surface of diamond can serve as a connecting bridge, effectively reducing interfacial thermal resistance and improving mechanical properties, which is more effective than adding titanium powder to the matrix to improve the bending strength and thermal conductivity of diamond/Cu composites.

PENGARUH TITANIUM DALAM LAPISAN LAS TERHADAP STRUKTUR MAKRO-MIKRO, KEKERASAN, DAN LAJU KOROSI

Low carbon steel cannot be hardened because of its low carbon content. Therefore, a hardfacing process is carried out to increase hardness. Apart from increasing hardness, the benefits of hardfacing can increase wear and corrosion resistance. The hardfacing process using the shielded metal arc welding (SMAW) process generally uses commercial electrodes. Therefore, it is necessary to add other elements such as titanium (Ti) to the weld layer to further increase its hardness. This research aims to study the influences of Titanium (Ti) addition in welding layers that were welded using HV 600 to micro and macrostructure, hardness, and corrosion rate. The hardfacing was conducted using the SMAW process with the various addition of Ti (0.115, 0.223, and 0.334 g) and cooled at room temperature. Macrostructure and microstructure were investigated using digital cameras and an optical microscope. Hardness and corrosion rate were investigated using the Vickers hardness test and weigh loss method. Based on macrostructure investigation, there is a perfect fusion between base metal and weld metal. The microstructure formed is a austenite, martensite and carbide phase. The lowest corrosion rate of 17.54 mpy was seen in the Ti1 sample. The lowest Ti addition would resulting higher hardness at 761.06 VHN.

Porous alumina‐based ceramics with very low thermal conductivity prepared by the starch consolidation route

AbstractAlumina‐based porous ceramics were fabricated via the starch consolidation casting route, using titanium oxide as a sintering additive. Alumina‐titania‐starch slurries with starch contents of 2.5, 5, 7.5, and 10 wt% relative to the alumina‐titania system were prepared. Titania was added to the slurries in proportions of 0, 1, 3, and 5 wt%, relative to alumina. The effects of starch and titania contents in the green bodies on the linear and volumetric shrinkage, as well as the total and open porosities of the sintered alumina product, were investigated. The effect of titania addition on mechanical, electrical, and thermal properties of the obtained porous alumina ceramics was studied. Microstructure and pores morphology were characterized by SEM. The alumina‐based ceramics obtained had external porosities that varied between 54 and 76 vol%. Thermal conductivities as low as 0.06–0.1 W/m.K were achieved and the volume electrical resistivity ranged from 3.6 to 600 GΩ·m, while compressive strengths up to 2.8 MPa for a titania ratio of 1 wt% were attained.

Improvements in Wear and Corrosion Resistance of Ti-W-Alloyed Gray Cast Iron by Tailoring Its Microstructural Properties.

The improved wear and corrosion resistance of gray cast iron (GCI) with enhanced mechanical properties is a proven stepping stone towards the longevity of its versatile industrial applications. In this article, we have tailored the microstructural properties of GCI by alloying it with titanium (Ti) and tungsten (W) additives, which resulted in improved mechanical, wear, and corrosion resistance. The results also show the nucleation of the B-, D-, and E-type graphite flakes with the A-type graphite flake in the alloyed GCI microstructure. Additionally, the alloyed microstructure demonstrated that the ratio of the pearlite volume percentage to the ferrite volume percentage was improved from 67/33 to 87/13, whereas a reduction in the maximum graphite length and average grain size from 356 ± 31 µm to 297 ± 16 µm and 378 ± 18 µm to 349 ± 19 µm was detected. Consequently, it improved the mechanical properties and wear and corrosion resistance of alloyed GCI. A significant improvement in Brinell hardness, yield strength, and tensile strength of the modified microstructure from 213 ± 7 BHN to 272 ± 8 BHN, 260 ± 3 MPa to 310 ± 2 MPa, and 346 ± 12 MPa to 375 ± 7 MPa was achieved, respectively. The substantial reduction in the wear rate of alloyed GCI from 8.49 × 10-3 mm3/N.m to 1.59 × 10-3 mm3/N.m resulted in the upgradation of the surface roughness quality from 297.625 nm to 192.553 nm. Due to the increase in the corrosion potential from -0.5832 V to -0.4813 V, the impedance of the alloyed GCI was increased from 1545 Ohm·cm2 to 2290 Ohm·cm2. On the basis of the achieved experimental results, it is suggested that the reliability of alloyed GCI based on experimentally validated microstructural compositions can be ensured during the operation of plants and components in a severe wear and corrosive environment. It can be predicted that the proposed alloyed GCI components are capable of preventing the premature failure of high-tech components susceptible to a wear and corrosion environment.

Effect of carbide refinement on high temperature erosive wear behavior of high chromium white cast iron with different titanium and carbon additions

It is known that better erosion wear resistance of high chromium (27 wt% Cr) white cast iron (HWCI) with titanium (Ti) addition can be achieved by controlling the size of M7C3 carbides. Nevertheless, it might not be directly applicable to high temperature conditions due to the more complex factors involved, especially the hot oxidation behavior. Therefore, the effect of 0–2 wt% Ti and 3–4 wt% carbon (C) addition on the high temperature erosion wear behavior of HWCI has been investigated in this research. The results show that there are TiC and M7C3 carbides precipitated in the material matrix. The size of M7C3 carbides decreases drastically as the amount of Ti increases. On the contrary, it is effectively enlarged with the addition of higher C. In addition, there is no significant difference in hardness among all specimens due to the relatively similar carbide volume fraction (CVF). The wear resistance of HWCI is improved by increasing the amount of Ti although it has a lower value as the C content increases. It means that hardness is not an important factor in evaluating the wear characteristics of HWCI at high temperatures. The worn surfaces and cross-sections show that the smaller M7C3 carbides are more likely to undergo plastic deformation rather than being directly peeled out. In addition, the effect of hot oxidation behavior was negligible because there is only a very thin oxidation layer on the worn surface. Therefore, it can be concluded that the erosive wear behavior of the material is greatly influenced by the size of M7C3, which the material with better erosive wear resistance contains finer carbides.

Effect of titanium and deposition parameters on microstructure and mechanical properties of W-Ti-B thin films deposited by High Power Impulse Magnetron Sputtering

Tungsten diboride alloyed with transition metals provides an opportunity to obtain exceptional mechanical, physical, and chemical properties. We report a strategy for designing and synthesizing of superhard and low-compressible ceramic thin films with increased toughness and lowered residual stresses (σ < −0.9 GPa) deposited with high-power impulse magnetron sputtering (HiPIMS) from one target. The addition of 7–12 % titanium promotes additional strengthening mechanisms of the layers in one material, leading to the improvement of wear resistance compared to an alloyed WB2-z yet at even higher hardness 43.8 ± 2.1 GPa and nanoindentation toughness 4.9 ± 0.2 MPa√m. The compression of the micropillar shows that titanium addition changed the type of nanoindentation from cracking along the slip plane to bulging on the top of the pillar and next the crack initiation along column boundaries. The highest adhesion of the layers is obtained for addition of 7 % titanium and in all cases the wear has abrasive character. The controlled use of 200 μs pulses during synthesis with HiPIMS allows for an increase in the deposition rate and maintaining exceptional mechanical properties of the layers even at a substrate temperature of 300 °C.

Investigation of interfacial microstructure and connection mechanism of magnetic field-assisted magnesium/aluminum laser welding joint

Variable process experiments to prepare hybrid joints of AZ31 magnesium (Mg) and 6061 aluminum (Al) alloys by magnetic field-assisted laser welding were performed in an overlap Mg-on-Al configuration with the addition of titanium (Ti) foil. Temperature field and flow field of molten pool including chemical potential of each element were also calculated. It is shown that at the optimal welding parameters, the shear force of joint reaches 887.79 N, which is 83.4 % higher than that of no-added joint. In the case of external magnetic field, the improved mechanical properties of joints largely depend on the diffusional barrier effect of Ti foil, which benefits from the enhanced energy absorption and flow of molten pool leading to the enlargement of interface connection area and the formation of Ti-Al compounds such as TiAl3 at Mg/Al interface. Meanwhile, the grains refines due to the magnetic field, which reduces the strain at the joint and enhances the uniformity of the interface microstructure. However, under the condition of excessive magnetic field strength, the enhanced stirring effect of molten pool will cause Ti foil break and the direct interaction between Mg and Al, which deteriorates the joint properties.