Addition Of TiO2 Research Articles

Fabrication and microstructure refinement of calcium hexaaluminate ceramics with a relative density of over 95 %

Calcium hexaaluminate (CaAl12O19, CA6) has great potential for application in high-temperature industries. However, owing to its intrinsic hexagonal lamellar crystal structure, it is difficult to obtain calcium hexaaluminate materials with high densification. In this study, using a two-stage sintering method and TiO2 sintering aid, the densification of calcium hexaaluminate materials (relative density >95 %) was achieved. The evolution behaviors of the phase composition and microstructure and the intrinsic sintering kinetics were investigated in detail. The results showed that the addition of TiO2 promoted the formation of CA6 grains with a more homogeneous morphology and an increased-density equiaxial morphology. The elevation of the sintering temperature the sintering temperature also facilitated the densification of CA6, as the growth rate of the CA6 grains along the C-axis raised significantly with the sintering temperature. When 1 wt% of TiO2 was added and the sintering temperature was 1750 °C, a CA6 material with a bulk density of 3.61 g/cm3 (relative density over 95 %) could be fabricated.

Elimination mechanism of voids caused by density differences in high crystallinity alumina/alumina joints bonded with dysprosium aluminum silicate glass ceramic filler

In this work, the Dy2O3-Al2O3-SiO2 (DASN) and Dy2O3-Al2O3-SiO2-TiO2 (DAST) glass fillers were used for joining alumina ceramic. During the cooling process of the alumina/DASN/alumina joints, Dy2Si2O7 and Al2O3 were precipitated simultaneously and gradually grown. As a result, voids were formed due to the poor flowability of the glass ceramic filler and the large density difference between the glass filler and Dy2Si2O7 crystals. On the contrary, the addition of TiO2 altered the sequence of the crystalline phase precipitation during the cooling process. During cooling from the joining temperature (1450 °C) to 1100 °C, only Dy2Si2O7 was formed in the brazing seam. Simultaneously, the flowing glass phase was able to fill the spaces caused by the density differences. When the growth of Dy2Si2O7 phase ceased, the Al2O3 phase began to precipitate. Therefore, the voids caused by density differences can be eliminated in the alumina/DAST/alumina joints with high crystallinity. The optimal flexural strength of alumina/DAST/alumina joints tested at room temperature and 1000 °C reached 350 MPa and 158 MPa, respectively.

Investigation of The Use of Nano Powder On Roller Compressible Fibrous Concrete Roads

Despite the fact that our country's road network is inferior to that of industrialized countries, the volume of motor traffic is increasing. Thus, optimal solutions are imperative during both project and construction phases of highway investments. Concrete superstructures offer an alternative to flexible superstructures in various regions globally, including airport runways, warehouses, urban roads, streets, highways and industrial buildings. The objective of this study was to enhance the compressive and flexural strength of concrete and provide resistance against abrasion. To achieve this, a roller compressible concrete (RCC) mixture design was developed by incorporating basalt fiber, nano TiO2, and nano Fe2O3 additives. The experimental results were subjected to statistical analysis via the technique of analysis of variance (ANOVA). The findings of the study indicated that the strength performance of the optimal RCC mixture design reinforced with nano powder and fibers was superior to that of conventional concrete. Upon examination on a material basis, it was determined that the compressive strength exhibited an increase when the water/binder ratio was utilised within the range of 0.38–0.4. As the utilisation of nano-Fe2O3 and basalt fiber materials increased, their compressive strength exhibited a corresponding enhancement. The incorporation of basalt fiber into the composite material resulted in an increase in flexural strength at all ratios where it was utilised. It can be concluded that basalt fiber has the greatest potential for enhancing flexural strength. The optimal water-to-binder ratio for flexural properties is between 0.34 and 0.38. While nano powders can have a positive impact, they cannot achieve the maximum level of strength. For improving abrasion resistance, it was established that reducing the water/cement ratio, using fly ash, basalt fiber, and nano Fe2O3 in the mixture decreased abrasion. However, the usage of nano TiO2 did not have a significant positive effect. The material with the least effect on compressive, flexural and abrasion resistance was identified as nano TiO2. When materials other than nano TiO2 are utilised in accordance with the established optimal mixture calculation, the durability of the resulting RCC road will reach the requisite standard.

Flux enhancement with titanium or vanadium oxides addition for superior submerged arc welding of HSLA steel plates

A high-strength low-alloy (HSLA) steel plate of 10 mm thickness underwent submerged arc welding with enhanced fluxes containing additional titanium oxide (TiO2) or vanadium oxide (V2O5). The addition of TiO2 led to the development of a finer acicular ferrite structure but coarsening the carbide and martensite/austenite (M/A) constituents, which marginally improved the hardness, tensile strength, and ductility of weld metal. Conversely, incorporating V2O5 facilitated a substantial vanadium absorption (0.7 wt. %) in the weld metal, giving rise to a distinctive acicular microstructure less reliant on ferrite nucleation at non-metallic inclusions than conventional acicular ferrite. The distinctive microstructure, unique to vanadium steels, combined lath bainite with irregularly shaped granular bainite. The resultant dual-mode bainitic structure, coupled with a more uniform distribution of refined microphase constituents, outperformed the conventional acicular ferrite, delivering more than 20% and 13% improvements in yield and tensile strengths respectively, as evidenced by transverse tensile tests on the weld metals.

Effect of TiO₂ Addition on Elastic Moduli, Optical Bandgap, and Electrical Conductivity of xTiO₂-(0.30-x)Bi₂O₃-0.10ZnO-0.60TeO₂ Glassy Systems with Improved Thermal Stability

Glassy systems with the chemical composition xTiO2-(0.30-x)Bi2O3-0.10ZnO-0.60TeO2 (x = 0.05,0.10,0.15,0.20) have been synthesized using the melt quench approach. Numerous physical, electrical, optical, and other features of elastic moduli have been evaluated as titanium oxide concentration rises. The amorphous properties of the materials under inspection are displayed in the XRD pattern. As the concentration of arsenic rises, the glasses' density falls from 4.18 to 3.96 g/cm3, while their molar volume rises from 48.21 to 53.06 cm3mol-1. The elastic properties of the synthesized glasses, such as the shear (S) and longitudinal (L) stresses, bulk modulus (K), Young's modulus (Y), and Poisson's ratio (Pr), have all been measured using the measured values of the ultrasonic velocities. The increase in elastic moduli values showed that the materials' elastic qualities have been improved. The results are explained in terms of a significant structural alteration caused by molecular rearrangement, which controls the physical properties of the glass. The addition of titanium oxide is shown to cause a decrease in Urbach energies from 0.96 to 0.67 eV, which results in an increase in the optical band gap energies from 2.96 to 3.33 eV. DSC thermogram measurements reveal mechanically enhanced and thermally stable materials with potential for use in semiconducting devices.

Experimental analysis of cycle tire pyrolysis oil doped with 1-decanol + TiO2 additives in compression ignition engine using RSM optimization and machine learning approach

This study investigates the effect of TiO2 nano additives in conjunction with 1-decanol on the performance and emission characteristics of biodiesel. The analysis involves four different blends: 90D7TO3DO+25 ppm TiO2 (90 % Diesel+7 % Tire oil + 3 % decanol and 25 parts per minute Titanium dioxide), 80D14TO6DO+50 ppm TiO2 (80 % Diesel+14 % Tire oil + 6 % decanol and 50 parts per minute Titanium dioxide), 70D22TO8DO+75 ppm TiO2, (70 % Diesel+22 % Tire oil + 8 % decanol and 75 parts per minute Titanium dioxide), and 100TO+100 ppm TiO2.(100 % Tire oil + 100 parts per minute Titanium dioxide), (DOE), design of experiments approach is used in this analysis. BTE is high for 90D7TO3DO+25 ppm TiO2 (36.12 %), compared to Diesel (30 %), i.e. 90D7TO3DO+25 ppm TiO2 possesses 20.67 % higher than diesel. The blend 90D7TO3DO+25 ppm TiO2 exhibited the lowest fuel consumption (0.25 kg/kWh), compared to diesel (0.28 kg/kWh), i.e. it was 12 % less than diesel. Inline cylinder pressures were optimal at 70 bar for the blend 90D7TO3DO+25 ppm TiO2, indicating favorable combustion properties. In terms of emissions, diesel emits NOx (1850 ppm), and the blend 100TO+100 ppm TiO2 achieved the lowest NOX emission of 1550 ppm, representing a 16.3 % reduction compared to diesel. The RSM model's coefficient of determination (R-squared) for all the parameters considered was remarkably high (nearly 0.98), meaning that it accounts for 98.00 % of the variability in the parameters. The corrected R-squared value validates the model's robustness. The results of the coefficient of determination (R2) for Bayesian Ridge regression clearly illustrate that the method is capable of making accurate predictions across the majority of the measurements as compared to Random Forest (RF).

A stable and regenerative TiO2/Bi2MoO6 photocatalyst for highly effective degradation of Rhodamine B and Congo Red

ABSTRACT This research unravels a facile method for synthesising TiO2/Bi2MoO6 photocatalysts and their effective applications in degrading industrial dyes. Initially, Bi2MoO6 was prepared as the substrate, followed by the addition of TiO2 to form the TiO2/Bi2MoO6 composite. The photocatalyst was characterised by powder X-ray diffraction (XRD), scanning electron microscopy with energy-dispersive X-ray spectrometry (SEM-EDS), X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HR-TEM), photoluminescence (PL), and UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS). Its photocatalytic properties were evaluated by dye degradation under various conditions, including different dopant loading amounts, the reaction time, the initial concentration of the dye, and pH values. The results indicated that 50 mg of 15% TiO2/Bi2MoO6 achieved the highest photodegradation efficiency: 98.51% for 50 mL 10 mg L−1 Rhodamine B (RhB) within 100 min in a neutral buffer solution and 90.71% for 50 mL 10 mg L−1 Congo Red (CR) within 80 min in an aqueous solution. This material exerted effectiveness across a wide pH range, with removal rates of RhB exceeding 95.41% in both acidic and alkaline conditions. The degradation process conformed to the pseudo-first-order kinetic model. Radical trapping experiments revealed that the dye degradation mechanism involved ∙ O 2 − and h+. Notably, the synthesised TiO2/Bi2MoO6 photocatalyst demonstrated high stability and reusability, maintaining performance even after four degradation cycles. The TiO2/Bi2MoO6 photocatalyst, with TiO2 as the dopant and Bi2MoO6 as the substrate, demonstrated significant versatility and potential for practical dye degradation applications.

Thermal performance evaluation of the parabolic trough solar collector using nanofluids: A case study in the desert of Algeria

The use of Parabolic Trough Solar Collector (PTSC) is currently the best option for widespread application in industries operating at temperatures from 60 to 400 °C. Numerous studies have been conducted to enhance the thermal performance of the PTSC using synthetic oils as heat transfer fluids. In this study, the thermal performance of parabolic collectors was enhanced using Metallic Oxide Nanofluids (CuO, SiO2, Al2O3, TiO2) based on Therminol VP-1™ at 4 % volumetric concentration as heat-transmitting fluids. A thermal model was developed and validated through experimental and theoretical study, while the results showed good compatibility in the outlet temperature with an error rate of 0.184 % for experimental and 0.29 % for theoretical studies. Moreover, various theoretical models of the thermal properties of nanofluids were analyzed to determine the model that matches and simulates this study. The findings indicated that nanofluids enhanced the thermal efficiency of the PTSC system compared to pure Therminol VP-1™. Specifically, CuO/Therminol VP-1™ demonstrated the most significant improvement, increasing thermal efficiency by 1.03 %. Furthermore, the results also showed that the addition of CuO, TiO2, Al2O3, and SiO2 nanoparticles led to an increase in outlet temperature by 9.57 %, 6.04 %, 5.21 %, and 3.08 %, respectively.

Effect of TiO2 and CaO Addition on the Crystallization and Flexural Strength of Novel Leucite Glass-Ceramics.

The aim of this study was to investigate the effects of TiO2/CaO addition on the crystallization and flexural strength of leucite glass-ceramics (GC). Synthesis of translucent and high strength GCs is important for the development of aesthetic and durable dental restorations. To achieve this, experimental aluminosilicate glasses (1-3 mol% TiO2 and CaO (B1, B2, B3)) were melted in a furnace to produce glasses. Glasses were ball milled, screened and heat treated via crystallization heat treatments, and characterized using XRD, differential scanning calorimetry, dilatometry, SEM and biaxial flexural strength (BFS). Increasing nucleation hold time (1-3 h) led to a reduction in crystallite number for B2 and B3 GC, and significant differences in leucite crystal size at differing nucleation holds within and across test groups (p < 0.05). A high area fraction of leucite crystals (55.1-60.8%) was found in the GC, with no matrix microcracking. Changes in the crystal morphology were found with higher TiO2/CaO addition. Mean BFS of the GC were 211.2-234.8 MPa, with significantly higher Weibull modulus (m = 18.9) for B3 GC. Novel glass compositions enriched with TiO2/CaO led to crystallization of leucite GC of high aspect ratio, with high BFS and reliability. The study's findings suggest a potential high performance translucent leucite GC for use in the construction of dental restorations.

Polyethersulfone mixed matrix membrane with abundant sponge pores for high‐separation performance with high flux retention and cycling stability

AbstractIn recent years, a series of high‐performance ultrafiltration membranes have been developed, but maintaining high flux and high pollutant retention rate without sacrificing service life remains a long‐standing challenge. In this study, a porous polyethersulfone ultrafiltration membrane enriched with ZIF‐8 and TiO2 additives is prepared based on a non‐solvent induced phase separation method. During the phase transition process, the addition of organic nanocrystals ZIF‐8 and inorganic nanocrystals TiO2 delayed the phase transition rate, resulting in the transformation of the polyethersulfone modified membrane from a finger‐like pore structure to a sponge‐like pore structure. Compared to other structures, the sponge‐like modified membrane has a uniform and narrow pore size distribution, fewer surface defects, stable retention performance, and can simultaneously improve membrane permeability and mechanical strength. Therefore, the polyethersulfone modified membrane with a sponge‐like pore structure prepared in this research exhibits high flux for small molecules and good retention rate for large molecules. Long‐term cycling stability tests of the modified membrane shows high retention rate (over 98%), high flux, long service life, and good cycling stability for solute molecules. The study indicates that the prepared polyethersulfone modified membrane has high potential for application in relevant environmental separation processes.

Slow‐release fertilizer behavior of polyvinyl alcohol (PVA)/urea/TiO2 nanofiber membrane

AbstractNanofiber is a material used as a drug carrier matrix in drug release materials. Its morphology has high porosity and good flexibility, making it suitable for this purpose. The use of nanofiber as a carrier matrix in slow‐release fertilizer (SRF) material is expected to provide a solution for releasing fertilizer into the soil more measurably and efficiently In this study, PVA/Urea/TiO2 nanofibers were fabricated using the electrospinning method. PVA/Urea/TiO2 SRFs were prepared using varying urea mass percentages (10%, 15%, and 20% of PVA mass) and the concentration of titanium dioxide suspension solution (0, 0.2, and 0.4 mL). Every sample was analyzed using scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) and tested using contact angle and slow‐release tests. From SEM characterizations, all samples showed the ability to form nanofiber. It was found that the membrane diameter sizes for each sample A, B, C, D, E, and F were 341 ± 5, 309 ± 12, 109 ± 3, 313 ± 10, 109 ± 3, and 158 ± 6 nm, respectively. The FTIR characterizations showed that all the matrix samples successfully contained the nitrogen group, which was found at wave number 1605 cm−1 (NH deformation), 1574 cm−1 (CN stretching), and 3430 cm−1 (NH stretching). The SEM mapping images confirmed the presence of titanium dioxide (green dots). The contact angle test showed that all samples had hydrophilic properties (the contact angle value lower than 90°), and the greatest value of contact angle measurement was 31.08° for sample C/E (sample with the most presence of TiO2 suspension solution 0.4 mL). The sample with the greatest TiO2 suspension concentration (0.4 mL) had the longest urea release time, lasting 8 days. This result indicates the addition of TiO2, can potentially suppress the hydrophilic properties of the PVA membrane. It is found that the addition of TiO2 influenced the membrane's hydrophilicity, consequently increasing the release rate. This study used the Korsmeyer–Peppas mathematical kinetic model to show that diffusion and swelling are release mechanisms for SRF membranes.

Effect of titanium dioxide and zirconium dioxide nanoparticle incorporation on the thermal conductivity of heat-activated polymethylmethacrylate denture base resins: An in vitro experimental study.

The aim is to determine thermal conduction by heat-activated polymethylmethacrylate (PMMA) infiltrated with 1 weight% Titanium Dioxide (TiO2) and 1 weight% Zirconium Dioxide (ZrO2) nanoparticles and to compare with that of conventional PMMA. In vitro experimental study. Eighteen disc shaped specimens with a thickness of 5 mm and diameter of 50 mm, were fabricated and grouped according to the material used: Group B1 (resin infiltrated with 1 weight% TiO2), Group B2 (resin infiltrated with 1 weight% ZrO2), and Control Group B3 (heat-activated conventional PMMA resin). Disc-shaped specimens were analyzed for thermal conductivity using "modified guarded hot plate apparatus" in the thermal lab of the Indian Space Research Organisation. One-way ANOVA followed by Tukey's post hoc test was used to compare the arithmetic means of all three groups. A statistically significant difference was noted among all three groups. Group B2 had the maximum thermal conductivity, followed by Group B1. Thermal conductivity was the least for Group B3. A post hoc comparison revealed that the difference was significant between Group B2 and Group B3. Nano ZrO2 addition in PMMA increased its thermal conductivity. There is evidence that it improves its mechanical properties as well. Hence, Nano ZrO2 addition in PMMA is highly recommended. Nano TiO2 addition in PMMA did not provide any significant advantage in terms of thermal conductivity, but its addition in PMMA is justified because of its mechanical and antimicrobial properties.

Investigation of the Effect of TiO2 Nanoparticles on Engine Performance and Emission Characteristics in Diesel Engines

This study aimed to examine the changes in performance and emission values in a four-stroke and three-cylinder diesel engine by using pure diesel fuel and fuels created by adding TiO2 nanoparticles. Adding TiO2 nanoparticles to the fuel aimed to improve the combustion characteristics of the diesel engine and reduce the harmful effects of exhaust emissions. Pure diesel and TiO2 nanoparticle added fuel samples in three distinct amounts, 25 ppm, 50 ppm, and 75 ppm, were prepared in magnetic and ultrasonic mixers as D100, D100+25TiO2, D100+50TiO2, and D100+75TiO2. All fuel samples used in the research were tested at a constant speed of 1800 revolutions per minute (rpm) at 25%, 50%, 75%, and 100% full loads. When TiO2-added fuels were compared to pure diesel, there was a 15.12% rise in brake thermal efficiency at %25 load and a 13.36% drop in brake specification fuel consumption at %25 load. EGT values also increased with the increase in load and adding TİO2. The amount of CO2 in exhaust emissions increased by 5% at maximum load in the fuel with the highest TiO2 additive according to neat diesel. There was an average increase of 11.44% in NOX emissions for all loads with TiO2 addition. The results show that the fuel mixture created by adding TiO2 nanoparticles can be used in certain proportions in diesel engines and that the TiO2 addition positively improves the combustion properties, engine performance, and exhaust gas emissions.

Effect of TiO2 Addition in Ladle Slag on Evolution of Nonmetallic Inclusions in Ti-Bearing Al-Killed Steel

Effect of TiO2 Addition in Ladle Slag on Evolution of Nonmetallic Inclusions in Ti-Bearing Al-Killed Steel

Experimental evaluation of radiation shielding characteristics of borate-based-glass system reinforced with titanium oxide

In this work, the attenuation capability of new Borate-based-glass system reinforced with titanium oxide containing PbO, CaO, TiO2 and B2O3 with different percentages was determined. Four different glass samples were synthesized by experimental technique using high pure germanium detector at different gamma ray sources using narrow beam method. The experimental method was verified by XCOM software. The values of the two methods were close and the relative deviation was satisfactory (less than 5 %) for all gamma energies (0.060, 0.662, 1.173 and 1.333 MeV). The highest linear attenuation coefficient (LAC) values achieved at low radiation energy of 0.0595 MeV. The Highest LAC values were 13.64, 13.97, 14.32 and 14.67 cm−1 for samples PCBT-1, PCBT-2, PCBT-3 and PCBT-4 in the same order, respectively. Conversely, the lowest LAC values in the examined energy range were found at 1.333 MeV. The lowest LAC values were 0.259, 0.266, 0.272 and 0.279 cm−1 for the aforementioned glasses, respectively. At 0.662 MeV, the transmission factor (TF) values decreases as 64.18, 63.54, 62.88 and 62.19 % as TiO2 content increases as 5, 10, 15 and 20 mol % in the same order, respectively. The decreases in TF values was linked to an observable increase in the radiation protection efficiency (RPE). The increase in RPE with the increase of TiO2 content confirms that the addition of TiO2 leads to an improvement in the radiation shielding performance for the prepared glasses.

Photocatalytic films with high ethylene degradation efficiency for strawberry preservation

The preservation of fruits has always been a research hotspot. In this research, titanium dioxide(TiO2) exhibiting diffraction peaks characteristic of both anatase and rutile phases was synthesized. Subsequently, photocatalytic films loaded with the TiO2 were fabricated using a twin-screw extruder combined with an extrusion casting technique. The films demonstrated a highest ethylene photocatalytic degradation efficiency of 88.57 %. The addition of TiO2 significantly enhanced the hydrophilicity of the films, with a maximum increase of 8.08 %. The tensile strength and elongation at break of the films were also improved. The optical properties, barrier properties and mechanical properties revealed that the film may make contributions to slowing down light aging, reducing weight loss of strawberries and increasing the load-bearing property. Furthermore, fresh-keeping experiment proved that the photocatalytic films could markedly slow down the appearance change, reduce weight loss and TBARS accumulation while decelerating the decline of TSS and antioxidant capacity in strawberries.

Plasticised chitosan: Dextran polymer blend electrolyte for energy harvesting application: Tuning the ion transport and EDLC charge storage capacity through TiO2 dispersion

This study investigates the performance of biopolymer electrolytes based on chitosan and dextran for energy storage applications. The optimization of ion transport and performance of electric double-layer capacitors EDCL using these electrolytes, incorporating different concentrations of glycerol as a plasticizer and TiO2 as nanoparticles, is explored. Impedance measurements indicate a notable reduction in charge transfer resistance with the addition of TiO2. DC conductivity estimates from AC spectra plateau regions reach up to 5.6 × 10−4 S/cm. The electric bulk resistance Rb obtained from the Nyquist plots exhibits a substantial decrease with increasing plasticizer concentration, further enhanced by the addition of the nanoparticles. Specifically, Rb decreases from ∼20 kΩ to 287 Ω when glycerol concentration increases from 10 % to 40 % and further drops to 30 Ω with the introduction of TiO2. Specific capacitance obtained from cyclic voltammetry shows a notable increase as the scan rate decreases, indicating improved efficiency and stability of ion transport. The TiO2-enriched EDCL achieves 12.3 F/g specific capacitance at 20 mV/s scan rate, with high ion conductivity and extended electrochemical stability. These results suggest the great potential of plasticizer and TiO2 with biopolymers in improving the performance of energy storage systems.

Cross-flow photocatalytic membrane reactor (PMR) based on TiO2–AgBr–Ag–NH2-MIL-88B (Fe) /poly (ethersulfone) for enhanced removal of cefixime, anti-fouling performance and permeability

The organic-metallic framework NH2-MIL-88B (Fe) was initially synthesized using a hydrothermal process., then the TiO2–AgBr–Ag–NH2-MIL-88B (Fe) photocatalytic nanoparticles was successfully ready and used as a filler for mixed matrix membrane (MMM) poly Ether sulfone (PES) was added. A photocatalytic membrane reactor (PMR) for the degradation of cefixime aqueous solution (CFX) was fabricated using a PES-TiO2-AgBr-Ag–NH2–MIL-88B (Fe) flat sheet membrane module. FTIR, XRD, FESEM, and DRS analyses were performed to look into the produced nanoparticles' structural characteristics. Hydrophilicity and membrane surface roughness were investigated using the surface contact angle and AFM pictures test. Additionally, Cross-FESEM analysis was used to examine modifications in membrane morphology. By increasing the TiO2–AgBr–Ag–NH2-MIL-88B (Fe) nanoparticles in the polymer matrix, significant improvements were made to the membrane's hydrophilicity, porosity, pure water flux, and CFX degradation. Furthermore, the nanocomposite membranes' antifouling characteristic was assessed while the CFX solution was being filtered. The obtained results show that the flux and removal of CFX solution is improved by adding TiO2–AgBr–Ag–NH2-MIL-88B (Fe) nanoparticles to PES polymer solution up to 1 % by weight. In addition, the obtained results showed that the addition of TiO2–AgBr–Ag–NH2-MIL-88B (Fe) photocatalytic nanoparticles in the PES membrane significantly improves the antifouling properties.

Effects of TiO2 on the mechanical and physical properties of Fe2O3-Doped Yttria-Stabilized Zirconia for electrolyte of Solid Oxide Fuel Cells

Yttria-Stabilized Zirconia (YSZ) based electrolytes of Solid Oxide Fuel Cell (SOFC) are widely used due to their higher ionic conductivity, stability, and availability. The present study focuses on improving the performance of YSZ-based electrolytes particularly by doping other particles into YSZ. TiO2 was doped into Fe2O3-8YSZ composite and the effects of TiO2 on the mechanical and physical properties of the composites were observed. The concentrations of TiO2 were varied by 0 wt%, 1 wt%, 3 wt%, and 5 wt% for different compositions of the composites. The samples were fabricated by the solid-state reaction method by pressing the powders at 250 MPa for 3 min and were sintered at 1250 °C for 4 h. The sintered samples were then undergone through characterization tests in terms of percentage of volume shrinkage, density, porosity, Diametral Tensile Strength (DTS), and microhardness. The highest values of volume shrinkage (34.83%), relative density (97.83%), DTS (36.58 MPa), hardness (965 HV), and the lowest porosity (2.17%) were found for 5 wt% TiO2 addition. Besides, the lowest values of volume shrinkage (28.44%), relative density (87.94%), DTS (3.24 MPa), microhardness (340 HV), and the highest porosity (12.06%) were found for Fe2O3-8YSZ composites without (0 wt%) TiO2 addition.

Effect of MgO addition on the structural evolution, crystallization and properties of self-glazed ceramics sintered from granite sludge

Recycling of granite sludge has both economic and environmental benefits. In this paper, high glossiness self-glazed ceramics were prepared from granite sludge with the addition of TiO2, Ca(OH)2 and MgO by combining two-step sintering and low-temperature crystallization. The effect of MgO addition on the phase evolution, crystallization and properties of the glazed ceramics was studied to reveal its role in the diopside precipitation. With increasing MgO content, the reduced glass viscosity accelerates the dissolution of quartz and anorthite into the liquid glass phase, resulting in a decrease in flexural strength above 1 % MgO. Meanwhile, the addition of MgO increases the non-bridging oxygen to lower the glass transition temperature. The increase in the Al/Si ratio of the glass phase and the mixed alkaline earth effect contribute to an increase in the crystallization temperature. After thermal treatment at 950 °C, the precipitated diopside increases the crystallinity of the glazed glass-ceramic from 6.4 % to 19.3 % at 3 % MgO, resulting in a surface glossiness of 99.7 GU and a flexural strength of 64.1 MPa. High glossiness self-glazed ceramics with an aesthetic appearance could be used in decorative building tiles for scalable utilization of granite sludge.