Flexible, free-standing supercapacitors play a significant role in the development of future wearable energy storage devices. Herein, we successfully fabricated the highly flexible and free-standing graphene/cerium oxide/polypyrrole hybrid films by thermal reduction of graphene oxide (GO) followed by the sol–gel synthesis of CeO2 and then the addition of PPy. By regulating oxygen functional groups in GO, the electronic conductivity and electroactive sites of the hybrid films are significantly controlled, leading to enhanced energy storage capability. Finally, a symmetric flexible supercapacitor (FSC) device was developed using the prepared films as electrodes. Resulting, the integrated symmetric GO-400/CeO2/PPy FSC manifests excellent areal capacitance of 49.0 mF cm−2 at 1 mA cm−2, with a durability of 83.1 % over 10,000 cycles. Specifically, the FSC exhibited capacitance retention of 77.2 % after 10,000 cycles under bending state with exceptional rate ability. Meanwhile, an impressive energy density of 19.69 µW h cm−2 was attained at a power density of 0.85 mW cm−2. Evidently, the synergistic interactions between GO and PPy nanosheets, along with CeO2 favour the rapid electron movement of electrode material for next-generation wearable, portable electronics.