This study demonstrates an investigation of coalescence mechanism of oil droplets in water-filled and air-filled membrane pores in a crossflow filtration. Methanol, ethanol and propanol additives are used to create polyvinylidene fluoride (PVDF) membrane pores through phase inversion process. The air-filled pores are obtained by drying the membrane at temperature 50 °C. Results show that membrane structure transition occurred from short fingerlike (PVDF-M) to long fingerlike (PVDF-E) and drop-shaped macrovoid (PVDF-P) when the diffusivity of additives into water coagulant decreases. The emulsion permeation flux acquired by water-filled pores is higher than that attained by air-filled pores membranes and the flux increases in the manner: PVDF-P > PVDF-E > PVDF-M. The membrane with water-filled pores is more hydrophilic which is able to reduce the fouling. Stearic repulsion plus the crossflow and pressurized effects promote cleavage of oil droplets when small pores membrane is used. The low crossflow and high pressurized effects are preferable to coalescence in larger pores. Capillary effect controls the coalescence in the air-filled pores. In the smallest pores, the coalescence switched to cleavage when crossflow increases and feed pressurized effect reduces with the presence of repulsion effect. The PVDF-E with the relatively small pores appeared a better coalescence than the PVDF-P which possesses the largest pores, due to the capillary motion occurred more desirable in the smaller pores and low pressurized condition.
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