More and more modern buildings are using glass curtain walls as their building envelope. The large area of window leads to a significant increase in solar heat gain, resulting in an increase in the cooling load and energy consumption of the building envelope. In the calculation of building cooling load, the thermal performance parameter of windows, the solar heat gain coefficient, is used to calculate the solar radiation heat gain of the windows. The window-to-wall ratio of buildings with glazing facades is large, and the phenomenon of escape of incident solar radiation cannot be ignored. In order to calculate the solar radiation escape rate, a dynamic model of solar radiation escape rate incorporating the solar path tracking model is developed in this research, which can achieve big data simulation analysis based on actual meteorological conditions. The model is programmed and simulated using MATLAB R2024a software. Five representative cities from different climate regions in China are selected and the variation rule of solar radiation escape rate are analyzed on three different time scales: day, month, and year. The influence of building orientation was also calculated and analyzed. The numerical calculation results indicate that the escape solar radiation rate varies with the incident angle of solar radiation at different times. It was found that the smaller the solar azimuth angle and solar altitude angle, the smaller the escape rate of solar radiation. The latitude of a city has a significant impact on the solar radiation escape rate. The weighted average of the solar radiation escape rates for each city were calculated for both summer and winter. Regardless of the season, the city’s location, and the orientation of the room, the value of solar radiation escape rate varies from 8.64% to 10.33%, which indicates that the solar radiation escape phenomenon cannot be ignored in glass curtain wall buildings. The results can be used as a reference value of solar radiation escape rate for the correction of actual solar heat gain of buildings in different climate regions.