Based on ionospheric total electron content (TEC) data for Zhongshan station (ZHS) and Scott Base station (SBA) in Antarctica, acquired during 2010–2020, high-latitude ionospheric TEC diurnal variations of two near cusp latitude stations were studied. The magnetic latitude and longitude differences between the two stations were approximately 5° and 135°, respectively. It was found that during the 11-year solar activity cycle, the maximum diurnal variation of the ionospheric TEC at ZHS occurred mainly between local noon and magnetic noon. Statistically, the TEC peaks occurred closer to local (magnetic) noon under low (high) solar activity conditions. The maximum diurnal variation of ionospheric TEC at SBA occurred mainly around local noon under low solar activity conditions but before magnetic midnight under high solar activity conditions. The effects of solar radiation, particle precipitation, and polar ionospheric convection pattern on the diurnal variation of TEC were investigated. At both stations, photoionization caused by solar radiation was the main reason for the maximum diurnal variation of ionospheric TEC around local noon. During high solar activity with high concentration plasma in the dayside polar ionosphere, the convection pattern was the dominant influence on the maximum diurnal variation of TEC before magnetic midnight (noon) at SBA (ZHS).