Multiple-input multiple-output (MIMO) radar has acquired considerable attention as it offers an additional degree of freedom which results in performance gains when contrasted with the regular single antenna element radar system. Waveform optimization in MIMO radar is essential as it can offer tremendous improvements in target detection which are quantified in terms of reductions in the symbol error rate and improvements in target detection probability. In this work, we foster a strategy for the optimization of transmitter and receiver waveform in a collocated MIMO radar by only considering the second order statistics, thus relaxing the information of the instantaneous target states. Our contributions are primarily two-fold. First, we find a closed-form expression of the outage probability of an unknown target under clutter environment. For this prospect, we model the signal-to-interference-plus-noise ratio in a canonical quadratic structure, and then utilize the modern residue theory approach to characterize the distribution function. Secondly, we propose constrained and unconstrained optimization problems for the reduction in outage probability using algorithmic techniques such as interior-point, sequential-quadratic programming, and the active-set method for the optimization of the transmitter and receiver waveform. We also provide simulated re-enactments to validate our hypothetical deductions.