Active Metasurface Research Articles

Microfluidic Metasurfaces: A New Frontier in Electromagnetic Wave Engineering

AbstractMetasurfaces, as 2D artificial electromagnetic materials, play a pivotal role in manipulating electromagnetic waves by controlling their amplitude, phase, and polarization. Achieving this control involves designing subwavelength meta‐molecules with specific geometries and periodicities. In the context of microfluidic metasurfaces, optical properties can be dynamically modulated by altering either the geometric structure of liquid meta‐molecules or the refractive index of the liquid medium. Leveraging the fluidity of liquid materials, microfluidic metasurfaces exhibit remarkable performance in terms of reconfigurability and flexibility. These properties not only establish a cutting‐edge research area but also broaden the scope of applications for active metasurface devices. Additionally, the integration of metasurfaces within microfluidic systems has led to novel functionalities, including enhanced particle manipulation and sensor technologies. Compared to conventional solid‐material‐based metasurfaces, microfluidic metasurfaces offer greater design freedom, making them advantageous for diverse fields such as electromagnetic absorption, optical sensing, holographic displays, and tunable optical meta‐devices like flat lenses and polarizers. This review provides insights into the characteristics, modulation techniques, and potential applications of microfluidic metasurfaces, illuminating both the current research landscape and promising avenues for further explorations.

Phase change material metasurface loading enables an ultrafast all-optically switchable, compact, narrowband freespace optical filter

Active metasurfaces leveraging phase change materials (PCMs) remain a subject of intense investigation, owing to their inherent tunable properties and successful integration into integrated photonics. By harnessing the ultra-compact form factor of optical metasurfaces, further advancements in switching speeds and reduction in switching energies have the potential to revolutionize applications in free space optical communication, optical signal processing, neuromorphic photonics, quantum photonics, and compact LiDAR. In this context, an ultrafast all-optically switchable narrowband spectral filter employing a distributed Bragg reflector cavity loaded with a PCM-metasurface is proposed. The work involves a comprehensive numerical exploration of its optical properties, encompassing design optimization and anticipating limits in switching speeds and energy requirements. Specifically, focusing on a GST225 metasurface operating in the shortwave-infrared spectrum, the numerical investigations reveal the potential to achieve transmission contrast levels as high as 24 dB, accompanied by Q-factors up to a thousand and less than 1 dB insertion loss. This performance notably outperforms recently reported free-standing PCM metasurfaces and cavities loaded with unstructured PCM thin films. Furthermore, the study predicts full-cycle reconfigurability (transitioning from amorphous to crystalline states and vice versa) with anticipated switching speeds of 91 & 200 MHz and switching fluence of 0.655 & 0.616 mJ/cm2 per cycle for the RESET and SET processes respectively. This investigation holds promise for advancing the state-of-the-art performance of PCM-based metasurfaces.

Nonreciprocal field transformation with active acoustic metasurfaces.

Field transformation, as an extension of the transformation optics, provides a unique means for nonreciprocal wave manipulation, while the experimental realization remains a substantial challenge as it requires stringent material parameters of the metamaterials, e.g., purely nonreciprocal bianisotropic parameters. Here, we develop and demonstrate a nonreciprocal field transformation in a two-dimensional acoustic system, using an active metasurface that can independently control all constitutive parameters and achieve purely nonreciprocal Willis coupling. The field-transforming metasurface enables tailor-made field distribution manipulation, achieving localized field amplification by a predetermined ratio. The metasurface demonstrates the self-adaptive capability to various excitation conditions and can be extended to other geometric shapes. The metasurface also achieves nonreciprocal wave propagation for internal and external excitations, demonstrating a one-way acoustic device. The nonreciprocal field transformation not only extends the framework of the transformation theory for nonreciprocal wave manipulation but also holds great potential in applications such as ultrasensitive sensors and nonreciprocal communication.

Solution to the cocktail party problem: A time-reversal active metasurface for multipoint focusing

The cocktail party effect is the capability to focus one’s auditory attention on particular audio sources while ignoring other audio sources. We propose an experimental strategy to reproduce this ability by designing a time-dependent metasurface composed of independent active mirrors. Each active mirror is a programmable acoustic unit cell capable of hearing, computing, and re-emitting acoustic signals: each of them acts as a convolution filter. The proper configuration of the metasurface temporal filters allows one to establish an acoustic communication link between groups of individuals immersed in the noisy environment: a multiple-user multiple-input, multiple-output acoustic system is built. Published by the American Physical Society 2024

Multitask Learning Deep Neural Networks Enable Embedded Design of Active Metamaterials.

In this study, we propose and implement a deep neural network framework based on multitask learning aimed at simplifying the forward modeling and inverse design process of photonic devices integrating active metasurfaces. We demonstrate and validate our approach by constructing a continuously tunable bandpass filter that is effective in the midwave infrared region. The key to this filter is the combination of a metasurface and Fabry-Perot (F-P) cavity structure of the tunable phase-change material Ge2Sb2Se4Te (GSST) and the precise control of the crystallinity of the GSST by a silicon-based heater. With the help of a deep learning framework, we are able to independently model the crystallinity and geometric parameters of the filter to maximize the use of GSST tuning for bandpass filtering. Our model discusses the self-attention mechanism and the effect of noise and compares several existing popular algorithms, and the results show that a multitask deep learning strategy can better assist the on-demand reverse design of photonic structures with phase change materials. This opens up new possibilities for personalization and functional extension of optical devices.

Controlled Second Harmonic Generation with Optically Trapped Lithium Niobate Nanoparticles.

We report the second harmonic generation (SHG) response from a single 34 nm diameter lithium niobate nanoparticle. The experimental setup involves a first beam devoted to the optical trapping of single nanoparticles, whereas a second arm involves a femtosecond laser source leading to the SHG emission from the trapped nanoparticles. SHG operation where one to three nanoparticles are present in the optical trap is first demonstrated, highlighting the transition between coherent and incoherent SHG, the latter known as hyper-Rayleigh scattering (HRS). With a spatial light modulator moving the optical trap in and out of the focus of the femtosecond beam, the SHG intensity is switched back and forth between a low and a high level. This controlled operation opens new avenues for nanoparticle characterization and applications in sensing or communication and information technologies and constitutes the first step in the design of active substrateless metasurfaces.

Nanoimprinting Solution-Derived Barium Titanate for Electro-Optic Metasurfaces.

Electro-optic metasurfaces have demonstrated significant potential in enhancing the modulation speed and efficiency for fast and large-scale free-space optical devices. Barium titanate has a strong electro-optic Pockels coefficient, but its availability in thin-film form is restricted due to costly growth processes or low thickness. Here, we fabricated active metasurfaces using an etch-free bottom-up process with sol-gel-based polycrystalline barium titanate with a large electro-optic coefficient similar to bulk lithium niobate. We achieve strong hybrid Mie/surface lattice resonances with a quality-factor of 200 at 633 nm wavelength, enhancing the light-matter interaction and therefore the Pockels effect. The metasurface transmission is electro-optically modulated with up to 5 MHz driving frequency at low voltages of less than 1 V thanks to resonant enhancement of the modulation amplitude by 2 orders of magnitude. This successful demonstration of electro-optic modulation in nanoimprinted barium titanate structures paves the way for low-cost and large-scale free-space modulators or tunable metalenses.

Electrostatic steering of thermal emission with active metasurface control of delocalized modes

We theoretically describe and experimentally demonstrate a graphene-integrated metasurface structure that enables electrically-tunable directional control of thermal emission. This device consists of a dielectric spacer that acts as a Fabry-Perot resonator supporting long-range delocalized modes bounded on one side by an electrostatically tunable metal-graphene metasurface. By varying the Fermi level of the graphene, the accumulated phase of the Fabry-Perot mode is shifted, which changes the direction of absorption and emission at a fixed frequency. We directly measure the frequency- and angle-dependent emissivity of the thermal emission from a fabricated device heated to 250 °C. Our results show that electrostatic control allows the thermal emission at 6.61 μm to be continuously steered over 16°, with a peak emissivity maintained above 0.9. We analyze the dynamic behavior of the thermal emission steerer theoretically using a Fano interference model, and use the model to design optimized thermal steerer structures.

Nonvolatile Phase-Only Transmissive Spatial Light Modulator with Electrical Addressability of Individual Pixels.

Active metasurfaces with tunable subwavelength-scale nanoscatterers are promising platforms for high-performance spatial light modulators (SLMs). Among the tuning methods, phase-change materials (PCMs) are attractive because of their nonvolatile, threshold-driven, and drastic optical modulation, rendering zero-static power, crosstalk immunity, and compact pixels. However, current electrically controlled PCM-based metasurfaces are limited to global amplitude modulation, which is insufficient for SLMs. Here, an individual-pixel addressable, transmissive metasurface is experimentally demonstrated using the low-loss PCM Sb2Se3 and doped silicon nanowire heaters. The nanowires simultaneously form a diatomic metasurface, supporting a high-quality-factor (∼406) quasi-bound-state-in-the-continuum mode. A global phase-only modulation of ∼0.25π (∼0.2π) in simulation (experiment) is achieved, showing ten times enhancement. A 2π phase shift is further obtained using a guided-mode resonance with enhanced light-Sb2Se3 interaction. Finally, individual-pixel addressability and SLM functionality are demonstrated through deterministic multilevel switching (ten levels) and tunable far-field beam shaping. Our work presents zero-static power transmissive phase-only SLMs, enabled by electrically controlled low-loss PCMs and individual meta-molecule addressable metasurfaces.

Evolutionary Games‐Assisted Synchronization Metasurface for Simultaneous Multisource Invisibility Cloaking

AbstractThe realization of a metasurface cloak for the simultaneous invisibility of multiple sources presents a long‐standing scientific challenge. Ideally, for the establishment of a simultaneous multisource invisibility cloak, the metasurface must provide a wide phase coverage and angular stability in a single architecture, especially for broadband, wide‐angle, and even omnidirectional scenarios. However, achieving this goal has proven to be elusive thus far. Current approaches for implementing metasurface‐based invisibility cloak involve both active and passive metasurface. These approaches often rely on phase‐compensation mechanisms, which inevitably encounter issues related to limited incidence angles or narrow working bands. Here, a novel paradigm of synchronization metasurface optimized through an evolution‐optimization strategy, enabling the realization of simultaneous multisource invisibility cloaking, is proposed. The underlying physics of the synchronization metasurface relies on an evolution‐optimization strategy (an evolutionary game algorithm), which is used to get rid of the entanglement between incident directions, frequencies, and metasurface phase gradients. Consequently, the synchronization metasurface is capable of manipulating simultaneous incoming waves at any angle over a wide range (cloak). In experimental validation, the synchronization metasurface demonstrates an impressive capability to cloak both single and simultaneous double sources in any direction, highly resembling background fields.

Multi-band tunable electromagnetically induced transparencies based on active metasurface with polarization-independent property

The analogue of an electromagnetically induced transparency (EIT) spectrum is achieved using a metasurface that consists of an array of cross and L-shaped resonators. The mechanism of the EIT-like phenomenon are analyzed, and the influence of geometrical parameters on the effect is discussed. We achieve a multi-band EIT-like through structure configuration. In particular, polarization-independent EIT is realized. A potential application in sensing is suggested and the sensitivity of 65 GHz RIU−1 is obtained. We also investigate the impact of analyte and substrate on the transmission spectrum. We find that when the analyte thickness is higher than 40 μm, the EIT spectral shift is less affected by the analyte thickness. The thickness insensitive characteristics are beneficial for reducing errors caused by analyte dose, thereby improving the accuracy of sensing. By introducing a phase change material, vanadium dioxide, we obtain active control of the EIT effect. Our results provide valuable insights into the development of multi-band tunable compact devices based on metasurfaces.

Active Tunable Elastic Metasurface for Abnormal Flexural Wave Transmission

An active elastic metasurface has more flexibility than a passively modulated elastic metasurface, owing to the manipulation of the phase gradient that can be realized without changing the geometrical configuration. In this study, a negative proportional feedback control system was employed to provide positive active control stiffness for adaptive unit cells, with the aim of achieving the active modulation of the phase gradient. The relationship between the control gain and the phase velocity of the flexural wave was derived, and the transfer coefficients and phase shifts of the flexural wave through the adaptive unit cells were resolved using the transfer matrix method. Finite element simulations for wave propagations in the adaptive unit cells were conducted, and they verified the analytic solutions. Based on this theoretical and numerical work, we designed active elastic metasurfaces with adaptive unit cells with sub-wavelength thicknesses according to the generalized Snell’s law. These metasurfaces show flexibility in achieving abnormal functions for transmitted waves, including negative refraction and wave focusing, and transforming guided waves at different operating frequencies by manipulating the control gain. Therefore, the proposed active metasurface has great potential in the fields of the tunable manipulation of elastic waves and the design of smart devices.

Tunable Mid‐Infrared Multi‐Resonant Graphene‐Metal Hybrid Metasurfaces

AbstractElectrically tunable graphene‐metal metasurfaces with controllable optical properties have attracted interest for straightforward manipulation of free space light. Their resonance tuning range depends on graphene's electrical transport characteristics, which are affected by its quality, operating conditions, and the device design. An important example of the latter is the direct contact of metallic antennas with the graphene layer that limits the extent to which a bias voltage can tune the metasurface's permittivity. In this work, this issue is resolved in a straightforward and fabrication‐efficient way for graphene‐metal hybrid metasurfaces with multiple plasmonic resonances. It is demonstrated that the incorporation of a 10 nm Al2O3 barrier layer enhances the tuning range of mid‐infrared resonances compared to metasurfaces without barrier layer, i.e., from 300 to 700 nm for a 7.3 µm resonance and from 110 to 140 nm for a 4.7 µm resonance. The improved tunability of the metal/dielectric/graphene metasurface can be attributed to the reduced electrical coupling between metal and graphene, as confirmed by an equivalent circuit model. These results bring closer the use of active metasurfaces based on two‐dimensional materials under ambient conditions, with possible applications as optical filters, modulators, and information processing devices that require dynamic control of light.

Magnetoplasmonic Metasurface-Modulated Electrochemiluminescence Strategy for Extracellular Vesicle Detection.

Due to the ideal optical manipulation ability, the metasurface has broad prospects in the development of novel optical research. In particular, an active metasurface can control optical response through external stimulus, which has attracted great research interest. However, achieving effective modulation of the optical response is a significant challenge. In this work, we have developed a novel electrochemiluminescence (ECL) signal modulation strategy by an active magnetoplasmonic metasurface under an external magnetic field. The magnetoplasmonic metasurface was assembled based on yolk-shell Fe3O4@Au nanoparticles (Fe3O4@Au YS-NPs). On the one hand, the yolk-shell structure of Fe3O4@Au YS-NPs possessed the surface plasmon coupling effect and cavity-based Purcell effect, which provided high-intensity electromagnetic hot spots in the magnetoplasmonic metasurface. On the other hand, due to the strong magnetic response of the Fe3O4 core, the local magnetic field was induced by the external magnetic field, which further generated Lorentz force acting on the free electrons of Au nanoshells with strong optical anisotropy. The plasmon frequency of the metasurface can be effectively modulated by the Lorentz force effect. As a result, the ECL signal of nitrogen dots (N dots) was dynamically modulated and significantly enhanced at a specific polarization angle by the magnetoplasmonic metasurface under the variable external magnetic field. Based on the luminescence modulation ability and structure feature, the magnetoplasmonic metasurface was further established successfully as a sensing interface for gastric cancer (GC) extracellular vesicle (EV) detection. This study illustrated that the electromagnetic response of the active metasurface can effectively improve the optical modulation ability and luminescence sensing performance.

Time-Dependent Ultrafast Quadratic Nonlinearity in an Epsilon-Near-Zero Platform.

Ultrafast nonlinearity, which results in modulation of the linear optical response, is a basis for the development of time-varying media, in particular those operating in the epsilon-near-zero (ENZ) regime. Here, we demonstrate that the intraband excitation of hot electrons in the ENZ film results in a second-harmonic resonance shift of ∼10 THz (40 nm) and second-harmonic generation (SHG) intensity changes of >100% with only minor (<1%) changes in linear transmission. The modulation is 10-fold enhanced by a plasmonic metasurface coupled to a film, allowing for ultrafast modulation of circularly polarized SHG. The effect is described by the plasma frequency renormalization in the ENZ material and the modification of the electron damping, with a possible influence of the hot-electron dynamics on the quadratic susceptibility. The results elucidate the nature of the second-order nonlinearity in ENZ materials and pave the way to the rational engineering of active nonlinear metamaterials and metasurfaces for time-varying applications.

Low-Scattering and Dual-Polarized Reconfigurable Reflectarray Antenna Based on Absorptive and Active Coding Metasurfaces

Low-Scattering and Dual-Polarized Reconfigurable Reflectarray Antenna Based on Absorptive and Active Coding Metasurfaces

Multifunctional metasurface for ultrafast all-optical efficient modulation of terahertz wave

Metasurfaces have been widely used to terahertz (THz) modulators due to their unique electromagnetic (EM) modulation properties. However, to realize ultrafast and efficient control of the active metasurfaces remains a critical challenge. Herein, we first demonstrate a multifunctional metasurface modulator based on metal square rings, which have central rotational symmetry with local asymmetry. The former captures more EM energy to achieve strong enhancement of the local EM responses, and the latter generates high quality factor (Q-factor) Fano resonance. By scaling the unit structure, the resonant frequency shifts in an ultra-wideband range of ∼0.29-10 THz, which shows a linear relation between the Q-factor and the scaling factor, and an exponential variation between the full width at half maximum (FWHM) and the scaling factor. The results provide an effective approach to predict the frequency selection characteristics of the modulators in the THz regime. More importantly, by embedding the silicon into the specific position of the metasurface, external optical control results in the unit structure is constructed from meta-atom to molecularization model, the shifting of resonant frequency and the multi-level modulation of amplitude are realized, and the maximum modulation depth (MD) reaches ∼100 %. By systematically studying the dynamics of frequency and amplitude regulation, benefiting from the ultra-short relaxation time of the photo-carriers in silicon bridge, an ultrafast full recovery time of 2000 ps is achieved. Combined with the local field characteristics, the scaled unit structure achieves efficient modulation of the resonant frequency and amplitude under optical pumping, which provides a promising approach for the development of active metasurface modulator suitable for the whole THz band. This work demonstrates the viability of optical control molecularization of specific meta-atoms is applicable to the entire THz band, which has great potential use for future state-of-the-art THz modulators.

Multiscale Supercrystal Meta-atoms.

Meta-atoms are the building blocks of metamaterials, which are employed to control both generation and propagation of light as well as provide novel functionalities of localization and directivity of electromagnetic radiation. In many cases, simple dielectric or metallic resonators are employed as meta-atoms to create different types of electromagnetic metamaterials. Here, we fabricate and study supercrystal meta-atoms composed of coupled perovskite quantum dots. We reveal that these multiscale structures exhibit specific emission properties, such as spectrum splitting and polaritonic effects. We believe that such multiscale supercrystal meta-atoms will provide novel functionalities in the design of many novel types of active metamaterials and metasurfaces.

Single-substrate active metasurface for polarization reconfigurable omnidirectional antenna application

In this paper, a wideband polarization reconfigurable omnidirectional antenna (PROA) based on a single-substrate active metasurface is proposed. By controlling the states of the PIN diodes, the antenna can selectively radiate an omnidirectional linearly polarized wave and an omnidirectional circularly polarized wave. The reflection coefficient, axial ratio (AR), radiation pattern, and gain of the proposed antenna have been analyzed from the perspective of simulation and measurement. The measured results show that the PROA has a wide overlapped bandwidth from 2.87 to 3.67 GHz (relative bandwidth 24.46%). To the authors' best knowledge, this is the first reported wideband PROA based on a single-substrate reconfigurable polarization converter. This study not only offers a novel approach to design PROAs, but also greatly reduces the design complexity of the feed source compared with the traditional design method of PROAs.

Dynamic light manipulation via silicon-organic slot metasurfaces

Active metasurfaces provide the opportunity for fast spatio-temporal control of light. Among various tuning methods, organic electro-optic materials provide some unique advantages due to their fast speed and large nonlinearity, along with the possibility of using fabrication techniques based on infiltration. In this letter, we report a silicon-organic platform where organic electro-optic material is infiltrated into the narrow gaps of slot-mode metasurfaces with high quality factors. The mode confinement into the slot enables the placement of metallic electrodes in close proximity, thus enabling tunability at lower voltages. We demonstrate the maximum tuning sensitivity of 0.16nm/V, the maximum extinction ratio of 38% within ± 17V voltage at telecommunication wavelength. The device has 3dB bandwidth of 3MHz. These results provide a path towards tunable silicon-organic hybrid metasurfaces at CMOS-level voltages.