Accelerator Mass Spectrometry Research Articles

Determination of radiocarbon content in liquid fuel blends by accelerator mass spectrometry and liquid scintillation counting in the gliwice radiocarbon and mass spectrometry laboratory

Determination of radiocarbon content in liquid fuel blends by accelerator mass spectrometry and liquid scintillation counting in the gliwice radiocarbon and mass spectrometry laboratory

Transport of dust across the Solar System: Constraints on the spatial origin of individual micrometeorites from cosmic-ray exposure.

The origin of micrometeorites (MMs) from asteroids and comets is well-established, but the relative contribution from these two classes remains poorly resolved. Likewise, determining the precise origin of individual MMs is an open challenge. Here, cosmic-ray exposure ages are used to resolve the spatial origins of 12 MMs collected from urban areas and Antarctica. Their 26Al and 10Be concentration, produced during cosmic-ray irradiation in space, were measured by accelerator mass spectrometry. These data are compared to results from a model simulating the transport and irradiation of the MM precursors in space. This model, for the first time, considers a variety of orbits, precursor particle sizes, compositions and densities and incorporates non-isotropic solar and galactic cosmic-ray flux profiles, depth-dependent production rates, as well as spherical evaporation during atmospheric entry. While the origin for six MMs remains ambiguous, two MMs show a preferential tendency towards an origin in the Inner Solar System (Near Earth Objects to the Asteroid Belt) and four towards an origin in the Outer Solar System (Jupiter Family Comets to the Kuiper Belt). These findings challenge the notion that dust originating from the Outer Solar System is unlikely to survive long-term transport and delivery to the terrestrial planets. This article is part of the theme issue 'Dust in the Solar System and beyond'.

Palaeoclimatic shifts in the Central Ganga Basin during the Middle- to Late Holocene: Exploring the 4.2 ka arid event and its implications in northern India

The Central Ganga Basin is one of the most densely populated regions of India. It is agriculturally diverse and contributes much to the Indian economy. The region has housed numerous ancient and mediaeval empires. This study presents a continuous record of the paleomonsoon from the Chandrika Devi lake, Lucknow district of Uttar Pradesh, India which is linked with paleo vegetational shifts over the last ~6000 years (5871–75 cal yr BP). The chronology of the lake core is based on three accelerated mass spectrometry (AMS) radiocarbon and two Optically Stimulated Luminescence (OSL) dates. The multiproxy data (grain size, major and trace element ratio, total organic carbon (TOC wt%), carbon isotopes (δ13Corg‰) and pollen), suggest that the lake was initially a part of the Gomti river that began to transform into a lake at ~5000 cal yr BP with weakening of the Indian summer monsoon (ISM) in the Central Ganga Basin. The lake formation was completed at ~4100 cal yr BP under the influence of the 4.2 ka arid event. This phase marks the beginning of human presence as well as agricultural activities in the lake region with the appearance of Cerealia pollen and other agricultural taxa. The agricultural activity surrounding the lake catchment peaked at ~3000 cal yr BP. The lake gradually shrank and became a marshy lowland at ~75 cal yr BP. Our study is significant because it is the first comprehensive multiproxy study from the Lucknow region in the Central Ganga Basin on paleomonsoonal variability and its relationship to human activity, agricultural practices during the Late-Holocene with a focus on the 4.2 Ka arid event. Also, pollen record suggests that the changes in agriculture and human activity began just after 4.2 ka arid event in the study area.

The Metabolism and Disposition of Brepocitinib in Humans and Characterization of the Formation Mechanism of an Aminopyridine Metabolite.

<s><s></s></s> Brepocitinib is an oral once-daily Janus kinase 1 and Tyrosine kinase 2 selective inhibitor currently in development for the treatment of several autoimmune disorders. Mass balance and metabolic profiles were determined using accelerator mass spectrometry in six healthy male participants following a single oral 60 mg dose of 14C-brepocitinib (~300 nCi). The average mass balance recovery was 96.7% {plus minus} 6.3% with the majority of dose (88.0% {plus minus} 8.0%) recovered in urine and 8.7% {plus minus} 2.1% of the dose in recovered in feces. Absorption of brepocitinib was rapid, with maximal plasma concentrations of total radioactivity and brepocitinib achieved within 0.5 hours after dosing. Circulating radioactivity consisted primarily of brepocitinib (47.8%) and metabolite M1 (37.1%) derived from hydroxylation at the C5' position of the pyrazole ring. Fractional contributions to metabolism via cytochrome P450 (CYP) enzymes were determined to be 0.77 for CYP3A4/5 and 0.14 for CYP1A2 based on phenotyping studies in HLM. However, additional clinical studies are required to understand the potential contribution of CYP1A1. Approximately 83% of the dose was eliminated as N-methylpyrazolyl oxidative metabolites, with 52.1% of the dose excreted as M1 alone. Notably, M1 was not observed as a circulating metabolite in earlier metabolic profiling of human plasma from a multiple ascending study with unlabeled brepocitinib. Mechanistic studies revealed M1 was highly unstable in human plasma and phosphate buffer, undergoing chemical oxidation leading to loss of the 5-hydroxy-1-methylpyrazole moiety and formation of aminopyrimidine cleavage product M2. Time dependent inhibition and trapping studies with M1 yielded insights into the mechanism of this unusual and unexpected instability. Significance Statement This work describes the mass balance and metabolic profile of brepocitinib in human, a JAK1/TYK2 inhibitor being developed for treatment of autoimmune diseases.

Magnetic Response to the Source‐To‐Sink Environmental Changes in the Bay of Bengal Since ∼60 ka

AbstractThe terrestrial magnetic minerals of marine sediments are utilized to track the climatic changes in the source area and the dynamic characteristics of sedimentation processes. However, due to the varied source‐to‐sink environments, the magnetic response to ambient climate cannot be generalized. Here, we conducted systematic environmental magnetic analyses on core CJ04‐50 from the Ninetyeast Ridge and investigated its magnetic response to source‐to‐sink environmental changes. Core CJ04‐50 covers the last 60 Kyr based on accelerator mass spectrometry (AMS) 14C dating and the relative paleointensity (RPI) record. Rare earth element (REE) results suggest that the terrestrial materials are fed by the Ganges‐Brahmaputra (G‐B) and Irrawaddy/Indo‐Burma Ranges. High/low magnetic mineral content corresponds to strong/weak terristrial input during the cold/warm period. This pattern differs from that in the East Asian marginal seas, which have a high magnetic mineral content in warm periods. It might be attributed to the heavier Indian summer monsoon (ISM) precipitation than that of East Asian summer monsoon. Excessive moisture (&gt;1,500 mm/year) would not favor the formation and preservation of magnetic minerals in the source area during interglacials. By contrast, the enhanced physical weathering during glacials results in more magnetic contributions. A significant local magnetite dissolution occurred at the layer of Middle MIS 3, which may be caused by the non‐steady state diagenesis following deposition.

A new chronology of Cedrela fissilis (Meliaceae) for Southern Brazil: combining classical dendrochronology and radiocarbon dating

Cedrela fissilis is a tree species widely distributed in the tropical biomes of South America. This species has visible annual growth rings and can live for several centuries. The present study aims to (i) develop a chronology of C. fissilis to the Southern Brazilian Plateau using traditional dendrochronological methods, (ii) validate the dendrochronological dating using the radiocarbon (14C) bomb pulse method, and (iii) determine the influence of temperature and precipitation variations and their teleconnections with the tropical Pacific Ocean temperatures on the annual radial growth of this species. The ring width chronology was developed using 24C. fissilis trees. The Schulman years of 1957, 1962, 1963, 1966, 1969 and 1974 were independently dated using the 14C bomb pulse methodology by accelerator mass spectrometry (AMS). Tree-ring indices were compared with temperature and precipitation records from stations around the study forest. The chronology covers the period 1907-2018 (111 years) and is well replicated (> 10 trees) from 1941 onwards. Statistics commonly used in dendrochronology indicate that the chronology is highly reliable and of good quality (mean series intercorrelation r = 0.49; Rbar = 0.30; EPS = 0.86; MSI = 0.40). The 14C bomb pulse of selected calendar years showed that the trees were accurately dated using the classical cross-dating approach. Precipitation from November to December (wet period) is positively correlated with tree growth (r = 0.36, n = 49; p<0.05). In addition, variations in temperature from May to July are positively correlated with ring width (r = 0.39, n = 49; p<0.05), suggesting that C. fissilis growth is favored by abundant rainfall during the growing season and above-average winter temperatures. Interannual variation in the chronology is partially modulated by El Niño 3.4 (East Central Tropical Pacific Sea Surface Temperature) during Oct-Dec (r = 0.27, n = 68, p<0.05). The growth of C. fissilis trees is directly dependent on climate variability, suggesting that more abundant precipitation and higher winter temperatures, as projected for the future climate of southern Brazil, will have a positive effect on tree growth. However, prolonged droughts and high temperatures during the growing season will have a negative impact on tree growth, even in humid forests with high soil moisture content.

HVE ion sources for medium and high-energy accelerator systems

Since decades, High Voltage Engineering (HVE) manufactures particle accelerator systems for research and industry. HVE’s product line includes Singletron and Tandetron accelerator systems with terminal voltages of up to 6 MV. They are dedicated to a wide range of applications including ion implantation and irradiation, Ion Beam Analysis (IBA), Accelerator Mass Spectrometry (AMS), and neutron reference fields. In this paper, we give an overview of the different positive and negative ion sources that are applied in these systems. We focus especially on the recent development and the performance of a compact 2.45 GHz permanent magnet ECR bipolar ion source (HVE Model SO-160), used for negative light-ion injection into tandem accelerators. It generates high-current, low-emittance light-ion beams at 30 keV energy. The novelty in the design of this ion source is that it combines direct negative extraction for H − with positive extraction for He + that is followed by charge exchange to He − in a Na-based electron donor canal. The source produces in excess of 250 eµA of H − and more than 20 eµA of He −. It is expected the design allows for substantially higher currents, especially for H −.

Late Holocene decoupling of lake and vegetation ecosystem in response to centennial-millennial climatic changes in arid Central Asia: A case study from Aibi Lake of western Junggar Basin

Central Asian lakes are crucial for sustaining fragile oasis ecosystems in arid regions. Understanding the response of ecosystems in these lake basins to climate change is essential for predicting future variations in these ecosystems. Aibi Lake is a notable terminal lake in arid Central Asia. In this study, a 95 cm lacustrine sediment core was drilled from Aibi Lake to investigate the response of lacustrine and terrestrial ecosystems in the lake basin to climate change over the past 3200 years. Accelerator mass spectrometry (AMS) 14C dating and multi-proxy analyses of diatoms, pollen, grain size, total organic content (TOC), total nitrogen (TN), and total hydrogen (TH) are applied to the sediment core. The grain size and geochemical results show that the lake experienced elevated levels and improved productivity and nutrition during the periods of 708–181 BCE, 0–740 CE, and 1428–1900 CE. The periods align with the Roman Warm Period, Dark Age Cold Period, and Little Ice Age, respectively. For the past 3200 years, benthic diatoms have consistently been the dominant species in the lake. During the climatic transition periods of the Dark Age Cold Period, Medieval Warm Period, and Little Ice Age, there were significant changes in the abundance and survival of certain species of diatoms. Specifically, the halophilic species (Nitzschia dissipata and Nitzschia hungarica), basophilic species (Synedra acus), and the nutrition level-relevant species (Navicula menisculus) experienced notable shifts. These changes ultimately resulted in a noticeable alteration in the structure and function of the diatom community. Over the past 3200 years, the lake ecosystem has undergone three noticeable regime shifts. In contrast, the vegetation in the lake catchment has remained relatively stable, primarily consisting of desert steppe. These results suggest that aquatic ecosystems in arid central Asia are more susceptible and exhibit more rapid responses to climate change compared to terrestrial vegetation.

A microCT assessment of archaeological parenchyma from three riverine shell middens dating to the early Holocene, Yongjiang River Basin, Guangxi, southern China

Archaeobotanical investigations at three riverine shell midden sites dating to the early Holocene – Baozitou, Shichuantou and Nabeizui – in the Yongjiang River Basin, Guangxi, southern China have identified charred fragments of archaeological parenchyma. A subset of the archaeological parenchyma was assessed using X-ray micro-computed tomography (microCT), which enabled virtual histological examination of the interior of parenchyma fragments. The microCT scanning identified a fragment of lotus root (Nelumbo nucifera), a possible immature fig fruit (poss. Ficus sp.), cooked food fragments, and less diagnostic elements, some of which derive from underground storage organs (USOs), including a bud/bulb and potentially an aroid. The fragment of lotus root from Nabeizui was directly radiocarbon dated using Accelerator Mass Spectrometry to 8770–8544 cal BP. A new AMS radiocarbon chronology based on Canarium nutshells for the three sites indicates that they were all used during the early Holocene. These findings contribute to the understanding of broad spectrum plant use by hunter-gatherer-fisher communities in southern China during the early Holocene, as well as showing the potential of microCT imaging for the analysis of archaeological parenchyma from this region.

Development of pixelated silicon detector for AMS study

A pixelated silicon detector (PSD) has been developed for the position-sensitive detector on a focal plane of an accelerator mass spectrometry (AMS) system in Yamagata University (YU). The YU-AMS system measures the relative abundances of the carbon isotopes 14C, 13C, and 12C for radiocarbon dating. The beam of the rare isotope 14C is transported to the focal plane of the AMS system. When the focal plane detector is position-sensitive to the beam, it can be utilized for beam diagnostics on the AMS beamline to achieve 14C measurement with high accuracy. To investigate the characteristics of the PSD, α particles from 241Am were irradiated on the PSD. A beam test using 14C was also performed to evaluate the size and position of the 14C beam on the focal plane of the YU-AMS system.

Flood events in the lower reaches of the Yellow River: OSL and radiocarbon dating on the Anshang site

The lower reaches of the Yellow River have witnessed numerous episodes of flooding and considerable shifts in its course. Examining flood records within the Yellow River basin offers invaluable insights into ancient human settlements, agricultural practices, trade routes, and technological advancements of ancient Chinese civilizations. However, dating these fluvial sediments poses a considerable challenge due to either the scarcity of organic material for radiocarbon (14C) dating or the potential incomplete bleaching of sediments for optically stimulated luminescence (OSL) techniques. This study focused on the Anshang site located in Henan Province, we obtained OSL ages from distinct grain size fractions of quartz and cross-verified them with independent acceleration mass spectrometry (AMS) 14C ages. The findings revealed that both coarse quartz grains (CG) and medium quartz grains (MG) underwent complete bleaching in silt-dominated flood deposits and shallow lacustrine deposits. Conversely, the OSL ages of CG and MG quartz were notably overestimated by approximately 3–6 ka in silty clay-dominated flood deposits. Upon comparing the OSL ages with AMS 14C ages, it was evident that bulk organic matter AMS 14C ages aligned with CG OSL ages in shallow lacustrine deposits, but they appeared older than CG OSL ages in flood deposits. However, the AMS 14C ages from plant demonstrated good consistency. Consequently, we successfully identified flood-lacustrine sediments dating back to approximately ∼13 ka, ∼8–3 ka, ∼2.6 ka, ∼1 ka, and the last few hundred years, aligning well with historical documentation and earlier research. The regional evidence presented herein enhances our understanding of the applicability of OSL dating and AMS 14C dating in fluvial-lacustrine sediments. Armed with these new ages, we constructed a reference chronology for archaeological localities situated in the fluvial sediments of the lower reaches of the Yellow River.

MONITORING OF MODERN CARBON FRACTION IN DISPOSABLE PACKAGING

ABSTRACT Radiocarbon (14C) methodology was used to investigate the presence of biocarbon in different bio-based disposable packaging products. Packaging waste contributes to a municipal solid waste, which is increasing environmental concerns and resulting in the enhancement of EU regulations that aim to reduce packaging waste. The 14C amount in samples reflects how much of the biocarbon has been used. In this study, the concentration of 14C was determined in commonly used types of disposable packaging, such as cups, plates, straws, cutlery, and baking paper. Samples were made of materials such as paper, wheat bran, sugarcane, and wood. The mean concentration of the 14C isotope, measured by the accelerator mass spectrometry (AMS) technique, is greater than 100 pMC in all tested samples, indicating that the samples are modern. The relatively high 14C concentration values in the waterproof layer of the sample indicate that bioplastic, rather than plastic, was used in its production. The highest 14C isotope concentration values were measured for samples that used the oldest biomass (wood and paper), and the lowest for products from current crops (sugarcane and wheat bran), which is consistent with the trend of changes in 14C concentration in the biosphere. The study also addresses the problem of heterogeneity and representativeness of subsamples.

Development and carbon accumulation dynamics of a minerotrophic fen during the last millennium, northeast China

Peatlands are terrestrial ecosystems with high carbon sequestration efficiency, providing critical feedback on climate change. It is crucial to understand how peatland development and carbon accumulation respond to various factors to reveal the future direction of carbon reservoirs under changing climatic conditions. To assess the impact of climate and hydrological conditions on the development and carbon accumulation of peatlands, 15 peat core samples were analyzed to examine the processes of lateral expansion in the Dongfanghong (DFH) peatland, a minerotrophic fen located in the Changbai Mountains of northeast China. Accelerator Mass Spectrometry 14C, total organic carbon, dry bulk density, testate amoebae, δ13C of α-cellulose in Carex spp. and plant macrofossil analyses were conducted on a high-resolution peat core. The proxies were used to calculate carbon accumulation rate (CAR) and reconstruct water table depth as well as surface moisture and vegetation development of the DFH peatland. Our findings indicated that the DFH peatland was initiated at 1011 cal. CE and experienced paludification during the last millennium. The expansion of the DFH peatland was primarily determined by hydrological conditions rather than climatic factors such as total solar irradiance and regional temperature. The rapid expansion between 1500 and 1700 cal. CE was likely resulted from relatively low precipitation and a decrease in water table/surface moisture. CAR generally correlated with total solar irradiance, regional temperature, and precipitation, suggesting that climate may be crucial for CAR in DFH peatlands over multi-centennial timescales. However, the increased CAR under relatively dry conditions suggested that the CAR were regulated by hydrological conditions over a centennial timescale. This study highlighted the important roles of climate and hydrological conditions in the lateral expansion and CAR of the peatland in minerotrophic fen and that there may be a threshold for hydrology during the process of peatland development and carbon accumulation.

Effects of long-term application of inorganic fertilizers and organic amendments on the turnover rates of fractionated soil organic carbon and their determining factors in paddy fields

ABSTRACT To investigate how the long-term application of inorganic fertilizer and organic amendments affects the turnover rates of organic matter in physico-chemically fractionated components in paddy soils and how their rates are related to their amounts, we studied the effect of variable management of inorganic fertilizer and organic amendments for > 50 years on the ∆14C values of accumulated soil organic carbon (SOC) in fractionated components of 5 soil samples from three paddy fields. SOC was fractionated into four components based on their physico-chemical properties: (1) light fraction (LF) derived from plant residues, (2) heavy fraction (HF) containing stable aggregates, (3) oxidizable fraction (OxF) and (4) non-oxidizable fraction (NOxF) forming organo-mineral complexes with fine-textured minerals. The ∆14C values were determined by accelerator mass spectrometry using graphitized samples. The ∆14C values of SOC in NOxF (from −305‰ to − 90.5‰) were much lower than those of HF (from −123‰ to − 3.7‰) and OxF (from −215‰ to 21.0‰). Lowest values for NOxF suggested slowest turnover rates as expected, and higher and comparable values for OxF and HF implied much faster turnover rates of SOC in OxF compared with upland soils. This could be one of the characteristics of SOC dynamics in paddy soils, probably reflecting repeated puddling of plow layer soils. ∆14C values in all the fractions increased in response to the application of inorganic fertilizer and organic amendments, suggesting faster turnover rate. Soils with clayey and weathered characteristics had the lowest ∆14C values, or slowest turnover rates among the study fields. The relationship between the ∆14C value and the amount of accumulated C for HF, OxF and NOxF indicated that the more the SOC accumulated, the faster the turnover rate of the SOC was, regardless of the fractions, and the relationship of the HF was considerably different from those of OxF and NOxF. In conclusion, these results can be the basis for understanding the C dynamics and for improving soil fertility status and soil C sequestration in paddy soils.

Case studies of three geological archives for rare radionuclide measurements using accelerator mass spectrometry

Long-lived radionuclides in our environment provide important information on natural and anthropogenic processes. Their presence and concentration reflect the balance of production and decay. Geological archives store such information and the nuclides can be chemically extracted from the bulk sample. Accelerator mass spectrometry (AMS) represents a sensitive method to quantify those nuclides at natural levels. Three different terrestrial archives are discussed here as examples for radionuclide extraction using various chemical separation methods for subsequent AMS measurements. We focus on sample preparation for the cosmogenic radionuclides 10Be and 26Al, various anthropogenic actinide isotopes such as U, Pu, and Am as well as the astrophysically interesting nuclides 41Ca, 53Mn, and 60Fe. The processed materials cover samples with masses between a few mg and up to a few hundred kg and protocols are presented for the quantitative extraction of some 10,000 atoms of cosmogenic or interstellar origin per sample and even as low as a few hundred actinide atoms.

Radiocarbon dates from Curaçao’s oldest Archaic site extend earliest island settlement to ca. 5700 cal BP

Due to its proximity to coastal South America and settlement during the early phase of insular Caribbean occupation, Curaçao’s archaeological record offers potential evidence for early overwater exploration and regional interaction. Here, we report new accelerator mass spectrometry (AMS) dates on charcoal from C-1426 at Saliña Sint Marie, an Archaic rockshelter site that extends Curaçao’s occupation back to 5735–5600 cal BP, some 290–850 years earlier than the established settlement chronology. This finding makes the C-1426 rockshelter Curaçao’s earliest known archaeological site and among the oldest in the insular Caribbean. We describe the site and the archaeological context of dating and conclude by considering the implications of Curaçao’s revised occupation chronology for initial Caribbean settlement.

Temporal variation and pollution status of heavy metals in core sediments from Jiangsu intertidal area, China

Eight heavy metal concentrations were analyzed from a 60.35-m-long sediment core in the Jiangsu intertidal area, China. Based on the lithofacies characteristics, mean grain size, downcore distributions of elements, and accelerator mass spectrometry (AMS) 14C and optically stimulated luminescence (OSL) data, the sediments in the core were divided into three units that formed during marine isotope stages 4 (MIS 4), MIS 3, and MIS 1. Except for Cd, all the other heavy metals had the lowest average concentrations in U3, which formed during MIS 4 with the coarsest sediment, representing a fluvial deposit. Most of the heavy metals were positively correlated with Al, Fe, and the total organic carbon (TOC), indicating these metals had the same sources. Pearson's correlation coefficient, enrichment factor, geoaccumulation index, and principal component analysis suggested that there was no element enrichment or contamination in the core sediments and that all heavy metals were naturally sourced.

Understanding the pharmacokinetic journey of Fc-fusion protein, rhIL-7-hyFc using complementary approach of two analytical methods, accelerator mass spectrometry and ELISA.

Antibody-based therapeutics (ABTs), including monoclonal/polyclonal antibodies and fragment crystallizable region (Fc)-fusion proteins, are increasingly used in disease treatment, driving the global market growth. Understanding the pharmacokinetic (PK) properties of ABTs is crucial for their clinical effectiveness. This study investigated the PK profile and tissue distribution of efineptakin alfa, a long-acting recombinant human interleukin-7 (rhIL-7-hyFc), using enzyme-linked immunosorbent assay (ELISA) and accelerator mass spectrometry (AMS). Totally, four rats were injected intramuscularly with 1mg/kg of rhIL-7-hyFc containing 14C-rhIL-7-hyFc, which was prepared via reductive methylation. Serum total radioactivity (TRA) and serum rhIL-7-hyFc concentrations were quantified using AMS and ELISA, respectively. The TRA concentrations in organs were determined by AMS. Serum TRA peaked at 10hours with a terminal half-life of 40hours. The rhIL-7-hyFc exhibited a mean peak concentration at around 17hours and a rapid elimination with a half-life of 12.3hours. Peak concentration and area under the curve of TRA were higher than those of rhIL-7-hyFc. Tissue distribution analysis showed an elevated TRA concentrations in lymph nodes, kidneys, and spleen, indicating rhIL-7-hyFc's affinity for these organs. The study also simulated the positions of 14C labeling in rhIL-7-hyFc, identifying specific residues in the fragment of rhIL-7 portion, and provided the explanation of distinct analytes targeted by each method. Combining ELISA and AMS provided advantages by offering sensitivity and specificity for quantification as well as enabling the identification of analyte forms. The integrated use of ELISA and AMS offers valuable insights for the development and optimization of ABT.

RADIOCARBON AND URANIUM PROFILES IN MARINE GASTROPODS AROUND THE JAPANESE ARCHIPELAGO

ABSTRACT In this study, we investigate the distribution of radiocarbon and uranium in the calcified opercula of Turbo sp. collected from Ryukyu region and Chiba, Japan, to explore the potential of U/Th dating using mollusks collected from the Japanese archipelago. We acquired high-resolution radiocarbon and uranium concentration measurements using single-stage accelerator mass spectrometry and laser ablation−inductively coupled plasma−mass spectrometry. Our results show that uranium in the opercula of modern Turbo sp. is unevenly distributed at concentrations 1000 times less than those in coral skeletons. Radiocarbon found in the calcified opercula samples record ambient seawater radiocarbon values as well as coral skeletons. Uranium in the calcified opercula of Holocene Turbo marmoratus were also unevenly distributed and concentrated within the opercula in a different manner than observed in modern samples, suggesting uranium exchange after death. Our results suggest variable uptake of uranium isotopes into mollusk shells and highlights the need for rigorous sample selection criteria when choosing mollusks species for U/Th dating around Japan.

A novel post-1950 CE atmospheric 14C record for the tropics using absolutely dated tree rings in the equatorial Amazon

In this study, we present a comprehensive atmospheric radiocarbon (14C) record spanning from 1940 to 2016, derived from 77 single tree rings of Cedrela odorata located in the Eastern Amazon Basin (EAB). This record, comprising 175 high-precision 14C measurements obtained through accelerator mass spectrometry (AMS), offers a detailed chronology of post-1950 CE (Common Era) 14C fluctuations in the Tropical Low-Pressure Belt (TLPB). To ensure accuracy and reliability, we included 14C-AMS results from intra-annual successive cuts of the tree rings associated to the calendar years 1962 and 1963 and conducted interlaboratory comparisons. In addition, 14C concentrations in 1962 and 1963 single-year cuts also allowed to verify tissue growth seasonality. The strategic location of the tree, just above the Amazon River and estuary areas, prevented the influence of local fossil-CO2 emissions from mining and trade activities in the Central Amazon Basin on the 14C record. Our findings reveal a notable increase in 14C from land-respired CO2 starting in the 1970s, a decade earlier than previously predicted, followed by a slight decrease after 2000, signaling a transition towards the fossil fuel era. This shift is likely attributed to changes in reservoir sources or global atmospheric dynamics. The EAB 14C record, when compared with a shorter record from Muna Island, Indonesia, highlights regional differences and contributes to a more nuanced understanding of global 14C variations at low latitudes. This study not only fills critical spatial gaps in existing 14C compilations but also aids in refining the demarcation of 14C variations over South America. The extended tree-ring 14C record from the EAB is pivotal for reevaluating global patterns, particularly in the context of the current global carbon budget, and underscores the importance of tropical regions in understanding carbon-climate feedbacks.