Excitation functions for lithium were obtained by measuring the intensity of ejected electrons at 75 degrees to an incident electron beam. The maximum incident electron energy was 550 eV. Excitation functions were obtained for the 1s(2s2p 3P)2P, (1s2s2)2S, (1s2s2p)4P and 1s(2s2p 1P)2P states. The excitation function for 1s(2s2p 1P)2P suggests that an optically forbidden level lies close to the optical level and an electron configuration is suggested for this additional level. The very recent experimental data for caesium presented by Pejcev et al. (1977) are reconsidered in the light of the present work.