18O Values Research Articles

Analyses of water dependency of Haloxylon ammodendron in arid regions of Iran using stable isotope technique.

The complex relationships within desert ecosystems and their environmental conditions are reflected in patterns of plant water use. Thus, understanding the sources of water used by plants in these areas is crucial for effective resource management. In this study, we investigated the water use pattern of Haloxylon ammodendron in Semnan province, in the central plateau of Iran, using the stable isotope analysis. We employed a simple, homemade cryogenic vacuum distillation (CVD) system to directly extract water from soil samples and different plant components for subsequent analysis by mass spectrometer. The contribution of each possible water source to the plant xylem water was estimated using the IsoSource mixing model. The pattern of 18O values in the xylem water of H. ammodendron indicated its reliance on groundwater as a primary water resource during the wet season. Additionally, the correlation of sand particles with both δ2H and δ18O was found to be 0.32. Moreover, the 18O values of H. ammodendron xylem water were mainly similar to those of groundwater, suggesting the species' dominant use of groundwater. The findings of this study provide valuable insights for strategically planting H. ammodendron to mitigate impacts on groundwater resources and ensure long-term sustainability in arid and semi-arid regions.

ISOSCAPES AND PALEOISOTHERMS OF THE HOLOCENE MEAN JANUARY AIR TEMPERATURE IN THE NORTHWESTERN SIBERIA (BASED ON STABLE OXYGEN ISOTOPE COMPOSITION OF ICE WEDGES)

Holocene ice wedges at 16 sites in the Northwestern Siberia were studied, the age of ice wedges was determined, and stable isotope data ( 18O and 2Н values) for all studied ice wedges have been summarized. The δ2H-δ18O ratio and the dexc values for ice wedge ice indicate good preservation of the isotope signal of winter precipitation in ice, which allows to use the obtained δ18O values for paleotemperature reconstructions. The isoscapes (lines of equal 18O values) created for the Holocene ice wedges and modern ice veinlets are generally submeridional; the 18O values decrease from west to east of the study area. Taking into account a new Holocene tripartite division scheme it was shown that the mean January air temperature (TmJ) in the Northwestern Siberia ranged approximately from -21 to -30°С during Greenlandian and the first half of the Northgrippian stage of the Holocene (11,4 to 6 cal ka BP) and approximately from -24 to -27°С from the end of the Northgrippian - to the Meghalayan stage of the Holocene (5,2 to 0,9 cal ka BP). The Holocene isotherms are close to the modern sub-meridional position and show an eastward decrease in TmJ values. Winter climatic conditions in the Northwestern Siberia were generally stable during the Holocene, meanwhile TmJ was on average 1-2°C lower than modern ones.

Comparison of carbon, nitrogen, and oxygen stable isotope ratios and mercury concentrations in muscle tissues of five beaked whale species and sperm whales stranded in Hokkaido, Japan

ABSTRACT We studied δ 13C, δ 15N and δ 18O values, and total mercury (THg) concentrations in muscle samples from deep-sea predators – five beaked whale species and sperm whales – stranded along the coast of Hokkaido, in the north of Japan in 2010 and 2019. The δ 13C, δ 15N and δ 18O values, THg concentrations, and body length (BL) of Stejneger’s beaked whales were similar to those of Hubbs’ beaked whales, which belong to the same genus. In contrast, δ 13C values, THg concentrations, and BL of Sato’s beaked whales were markedly different from those of Baird’s beaked whales, which belong to the same genus. Stejneger’s and Hubbs’ beaked whales living around Hokkaido may compete in their ecological niches, whereas Sato’s and Baird’s beaked whales may segregate their ecological niches. Although Cuvier’s beaked whales and sperm whales belong to different genera and their BLs were significantly different, their δ 13C and δ 15N values were similar, probably because they can dive and stay in deeper waters than other beaked whale species. The δ 13C values in combined samples from all whales increased with increasing BL, probably owing to the larger whale species’ dietary preference for squid. The δ 13C values in combined samples from all whales were positively correlated with THg concentrations, whereas the δ 15N values in the combined samples were negatively correlated. The δ 18O values in combined samples from most whales tended to be positively correlated with THg concentrations. These correlations may be explained by a higher THg load from deep-sea feeding than from pelagic feeding and by a feeding shift towards lower trophic levels.

Weathering as a control on the triple oxygen isotopes of groundwater-associated ferromanganese deposits: lessons from the Grimlock Ni–Co–Mn prospect, Northern Territory, Australia

At the Grimlock laterite deposit (Northern Territory, Australia), Co and Ni mineralization occurs mainly in the Mn-oxide rich layers of the ferromanganese (Fe-Mn) crust overlying ultramafic bedrock. Groundwater-associated Fe-Mn crusts consist of mineral (e.g. Mn-oxide, Fe-oxyhydroxide and silicate) groups suitable for studying triple oxygen isotopes and present unique interpretative challenges (e.g. small Mn-oxide fractions relative to Fe-Mn precipitates from other formation environments and extensive weathering). We evaluate triple oxygen isotopes within the context of changes to properties (i.e. mineralogy, major and trace element geochemistry, and degree of weathering) of a lateritic profile. We use pre-existing mineral-water fractionation factors, meteoric water δ 18 O and temperature data to calculate δ 18 O values of fully altered mineralogical endmembers, then, using mass balance, discuss scenarios to elucidate measured whole-rock δ 18 O values. The δ ′ 18 O (′ denotes linearized notation) and Δ ′ 17 O of near-surface samples (0–8 m) are generally lower (mean of 8.892‰) and higher (mean of −0.141‰), respectively, than the δ ′ 18 O (mean of 12.767‰) and Δ ′ 17 O (mean of −0.176‰) of samples from greater depths (19–22 m). At 16–17 m depth, δ ′ 18 O and Δ ′ 17 O are relatively high (means of 17.509 and −0.118‰, respectively). The measured whole-rock δ 18 O values are explainable by substituting lower δ ′ 18 O values for the Mn-oxide and Fe-oxyhydroxide fractions, and higher δ ′ 18 O values for the aluminosilicate fraction, changes coinciding with greater alteration. These results suggest that mineral weathering is primarily responsible for observed variations in the triple oxygen isotopes of groundwater-associated Fe-Mn crusts, rather than variation in the initial source of oxygen incorporated into Mn-oxide. Supplementary material: Grimlock sample photographs, XRD patterns and supplementary figures and tables are available at https://doi.org/10.6084/m9.figshare.c.7071907

Morphology of the Buluus, Ulakhan-Taryn aufeis, conditions of its occurrence and stable oxygen and hydrogen isotope variations in the lower part

Aufeis is one of the most dangerous natural phenomena. The negative impact of aufeis is determined by the unexpected flooding of the territory and subsequent freezing of water, the formation of ice barriers, the icing of underground structures and communications (mines, tunnels, culverts, and sewer wells), as well as the icing of roads and railways, coastal hydraulic structures, etc. There are cases when explosions of aufeis mounds produce catastrophic disturbances within a few seconds. The aufeis that forms annually in the valley of the Buluus Creek is one of the most famous and studied aufeis of Central Yakutia. The aufeis was sampled from a vertical section. The aufeis is layered, and the thickness of the layers is 3-10 cm. In the upper part of the aufeis, the ice layers are thicker than in the lower. Sampling from the aufeis ice was carried out using a 5.1-cm-diameter steel crown driven by a Bosch electric drill. Measurements of the isotopic composition of oxygen and hydrogen in ice were performed using a Picarro L 2130-i laser isotope analyzer. The isotopic composition of the Buluus ice varies in a narrow range: δ18O values vary from −20.2 to −21.9‰, δ2H values vary from −159.5 to −173.7‰. Generally, the ice is isotopically slightly enriched compared to the surface water of the Ulakhan-Taryn creek, where the δ18O value is −22.18‰ and the δ2H value is −175.1%. Groundwater is isotopically close to the creek water; its isotope composition is also isotopically enriched compared to the ice of the aufeis, with δ18O values varying from −22.17 to −22.25‰ and δ2H values varying from −173.7 to −175.1‰.

Middle Eocene Climatic Optimum (MECO): The first record based on planktonic foraminifera and stable isotopes from SW Anatolia/Turkiye

The Kayikoy Formation (Isparta, SW Turkiye) consisting of sandstone, claystone, and marl units contains abundant, low-moderate preserved, and diverse planktonic foraminifera assemblages. Eight planktonic foraminiferal biozones (E9-E16) were determined encompassing the Lutetian-Priabonian stages (middle-upper Eocene) by using the biostratigraphic distributions of 17 genera and 62 species of planktonic foraminifera. Stable delta 18O and delta 13C isotope values were measured for 53 individuals belonging to Morozovelloides crassatus, Acarinina bullbrooki, A. topilensis, A. echinata, Globigerinatheka curryi, G. index, G. subconglobata, G. mexicana, G. barri, G. euganea, Orbulinoides beckmanni, Turborotalia frontosa, T. pomeroli, Hantkeninamexicana, H. liebusi, H. dumblei, H. alabamensis, and Dentoglobigerina eotripartita. By integrating planktonic foraminiferal biostratigraphy, stable delta 18O and delta 13C isotopes, and paleotemperature analyses, the first detailed study of the Middle Eocene Climatic Optimum (MECO) record was performed in SW Anatolia/Turkiye. The overall signature of the MECO is similar to global observations but also involves some regional differences. The MECO paleotemperatures, determined to vary between approximately 2 degrees C and 5 degrees C, were similar to the global records, but the slight differences in values in the three sections are most likely due to the paleogeographic position of the studied section in Turkiye.

Evaluation of geological structures and geothermal resources in the North Tanzania Volcanic area using remote sensing and gravity data analysis

Problems Statement and Purpose. Northern Tanzania Volcanic terrain has been a subject of evaluation for geothermal potential in the last four decades. The region is characterized by Neogene to Recent volcanic and tectonic activities. This preliminary study based on remote sensing, water chemistry, gravity data, geological structures and volcanic centers distribution reports the geothermal manifestations identified and discusses the implications on geothermal fluid pathways. Oxygen-hydrogen isotope data from water samples indicate that there were involved in the hydrothermal system. Tectono-Volcanic Structures. The Northern Tanzania Divergence (NTD) area characterized by Neogene to Recent volcanic and tectonic activities. Recent volcanic and tectonic activities are ash cone and lava dome eruption at the floor of Meru crater a century ago, dyke intrusion and volcanic eruption south of Gelai volcano, and Oldoinyo-Lengai volcano, respectively. Fumarolic activities and hot springs are dominant in a relatively young volcanic area to the north-eastern and northern part of the NTD. Data and Methods. Shuttle Radar Topography Mission (SRTM), Landsat 8 Operational Land Imager (OLI) image, water isotope analysis and gravity data were used to extract and analyze the surface and subsurface geological lineaments and map the hydrothermal alteration zones in the study area. The hydrothermal alteration is used to evaluate and identify the permeable structures. Analysis and interpretation of the length and trends of extracted lineaments were used to investigate the tectonic evolution. Geological map of a study area was digitized from the existing geological maps and the age of rocks to delineate volcanic activity and associated lineaments based on the age of the lithological domain. Digital image processing was applied to enhance the visual interpretation. Gravity data were used to give insight into the subsurface structure in the study area. Results and Discussion. The higher δ 18O values and large deviation from meteoric water lines suggest that is due to the interaction of fluids with host rocks at elevated temperatures. These are consistent with open structures that act as conduits for fluid flow. The potential field gravity data reveal a basin-like structure trending in the NNW direction. The gravity data show that the basement units gradually deepen towards the central part and that it is controlled by two main fault systems that trend N-S and NW-SE respectively. The gravity data presented here provides new constraints on the tectonic evolution and geothermal resources of the study area.

Snow sampling strategy can bias estimation of meltwater fractions in isotope hydrograph separation

The Isotope based Hydrograph Separation (IHS) has been instrumental in understanding the partitioning of streamflow sources and processes. However, uncertainties persist in the accuracy of IHS estimations and the appropriate definition and sampling of endmembers. To address these uncertainties, we used field data of snowpack, snowfall, and snow meltwater isotopes (δ18O) from Pallas, Northern Finland to estimate the total meltwater contribution during the snowmelt period. We investigated the biases resulting from the application of different sampling strategies for event water endmember. The total meltwater contribution to streamflow was 59.6 % (±2% uncertainty) using the time-variant rolling runoff-corrected melt flux-weighted meltwater 18O isotope value. However, replacing it with either snowfall or winter snowpack 18O isotope weighted average values underestimated the meltwater contribution by 17.8 % or 22.6 %, respectively. Conversely, using time-variant instantaneous meltwater 18O isotope values overestimated the meltwater contribution by only 1.5 %. These discrepancies highlight the importance of choosing the appropriate endmember isotopes in IHS. The large differences in meltwater contribution for a 2-week peak discharge period based on different endmembers can lead to different interpretations of hydrological, ecohydrological, and biogeochemical processes. Thus, to better understand streamflow generation processes, we suggest using rolling runoff-corrected meltwater 18O or 2H isotope values in the IHS. In the absence of meltwater samples, the 18O or 2H isotope values of snowpack samples during the peak melt season may provide reasonable estimates of the meltwater contribution, with some minor underestimations. Our study highlights the importance of appropriate event meltwater endmember selection and sampling methodology for the IHS.

Stable isotope hydrology of surface and ground waters in King George Island, Antarctica

ABSTRACT The region around the tip of the Antarctic Peninsula is warming fast, a situation that will lead to widespread changes in local hydrological cycles. King George Island (KGI) hosts a complex network of lakes and rivers, fed by glaciers, snow and rain, and underlain by thick permafrost. We present here the first study of the stable isotope composition of the surface waters in the ice-free southern peninsulas of KGI. Permafrost samples had the highest δ 18O and δ 2H values (–6.7 and –50 ‰, respectively), and river waters the lowest (–9.1 and –70 ‰, respectively), with groundwater (–8.2 and –62.7 ‰, respectively), lakes (–8.6 and –66.8 ‰, respectively) and (summer) meltwater (–9 and –69.5 ‰, respectively) having intermediary values. Our results suggest that a clear separation of the various water bodies (permafrost, snow, meltwater, lakes) based on the δ 18Owater and δ 2Hwater is possible. Further, water in lakes on a W–E transect (i.e. with increased distance from the Bellingshausen Sea) have a general tendency towards lower δ 18O (and δ 2H) values. The results allow for the establishment of a baseline against which ongoing and future changes of the hydrological cycle could be analysed, and past climate changes be reconstructed.

Disequilibrium in historic volcanic rocks from Fogo, Cape Verde traces carbonatite metasomatism of recycled ocean crust

Fogo, Cape Verde, located upon thick oceanic lithosphere, provides a window into processes occurring in the mantle where recycled ocean crust in an upwelling mantle plume interacts with ambient mantle. Our objective is to investigate the nature of the lithologies of the mantle sources involved in the petrogenesis of historic volcanic rocks from Fogo. We observe enclaves and mingling textures in the lavas combined with oxygen isotope disequilibrium between olivine and clinopyroxene phenocrysts. Olivine δ18O values display positive correlations with Zr/Hf and Zr/Y and a negative correlation with U/Th, whereas clinopyroxene δ 18O values correlate positively with Ba/Nb. Heterogeneity between crystal populations and within the groundmass indicates that multiple magma batches are mixed beneath Fogo. In terms of mantle endmembers and source lithologies, a HIMU endmember was generated by melting of carbonated eclogite as indicated by low δ 18O values, Zr/Hf, Ba/Nb and high U/Th ratios. In contrast, we show the EM1 endmember has high δ 18O, Zr/Hf, Ba/Nb and low U/Th ratios, derived from melting of variably carbonated peridotite. Additionally, Ba/Th ratio are high, indicating that carbonatite melts have contributed to alkaline magma compositions at Fogo.

The suitability of isotopic methods in identifying water sources of a shallow-rooted herbaceous plant in a desert steppe

Isotopic methodologies have gained prominence in investigating the composition of plant water sources; however, concerns regarding their suitability and reliability in diverse environments have emerged in recent years. This study presents a comparative analysis of root, soil, and liquid water (precipitation, dew, and groundwater) samples obtained from a desert steppe using isotope ratio infrared spectrometry (IRIS) and isotope ratio mass spectrometry (IRMS). The objective was to evaluate the applicability of these techniques in discerning the water sources of Stipa breviflora, a shallow-rooted herbaceous plant species. Additionally, we explored the root water uptake characteristics and water use strategy of S. breviflora. Our findings indicate that the IRIS method had more enriched values of D compared to the IRMS method across all samples, while no discernible pattern was observed for 18O. Notably, the differences observed among all samples exceeded the instruments' accuracies. Moreover, an unexpected occurrence was noted, whereby both D and 18O values in the root water were more enriched than in any of the considered water sources, rendering identification of the plant water sources unattainable. By conducting a re-analysis of more refined soil layer samples, we discovered that S. breviflora exhibits the ability to absorb and utilize water sources in close proximity to the soil surface. It further suggested that the shallow-rooted herbaceous plants in desert steppes can exploit small rainfalls, frequently overlooked in their ecological importance. Considering the distinctive soil and plant characteristics of desert steppes, we recommend adopting IRMS methods in conjunction with refined surface soil sampling for isotopic analysis aiming to identify water sources of shallow-rooted herbaceous plants. This study provides novel insights into assessing the suitability of isotopic techniques for analyzing plant water sources, while enhancing our understanding of water use strategies and environmental adaptation mechanisms employed by shallow-rooted herbaceous plants within xerophytic grassland ecosystems.

Association of Siderite with Iron Sulfides and Silicates in Rocks of Mikheevskoe Cu(Mo,Au) Porphyry Deposit (Southern Urals)

The mineral association of siderite with Cu–Fe sulfides, cronstedtite, and goethite were first recognized when studying the Mikheevskoe Cu(Mo,Au)–porphyry deposit. This association is confined to fault zones, where it fills a network of mineralized fractures developed on porphyry- and argillizite-type ores. Minerals of this association were also identified in some argillizite samples of this deposit. The formation conditions of this mineral association and its relation to the evolution of the Late Paleozoic porphyry system or other endogenic–exogenic processes manifested during the subsequent geological history of the study area were studied. The integrated research included microprobe analysis and the measurement of O and C stable isotopes in minerals of the studied association in the “Geoanalitik” (Yekaterinburg) and “Geonauka” (Syktyvkar) Centers for Collective Use. The study of mineral compositions and their relationships indicates that the studied mineral association deposited at temperature of about 70° C from neutral or low-acid solutions HS–,13C with varying HS–, and aSiO2 (aq) contents. The measurements of .13C (from –5.5 to –18.2‰) and 18O (from 20.4 to 33.4‰) values in siderite made it possible to calculate the composition of a mineral-forming fluid. It was established that such a fluid has the following parameters: .18O H2O from –3 to +10‰ and 13C CO2 from 15 to –28‰. It could correspond to magmatogenic water fluids mixed with Corg-bearing surface water. Based on the obtained results, it is suggested that this mineral association is related to argillizites, the development of which occurred at the last stage of endogenic mineral formation at the Mikheevskoe deposit. Nevertheless, it is not excluded that it may be related with other low-T hydrothermal processes at the stage of Meso-Cenozoic tectonomagmatic activation of the Urals. There is no evidence of the relation of the studied mineral association with weathering crusts

Occurrence, source identification and ecological risk assessment of heavy metals in water and sediments of Uchalli lake – Ramsar site, Pakistan

Uchalli Lake is an internationally significant Ramsar site that needs protection for supporting migratory birds. The current study aimed to assess wetland health by examining water and sediments utilizing total and labile heavy metals concentration, pollution indices, ecological risk assessment, water recharge and pollution induction sources through isotope tracer techniques. Al concentration in water was of serious concern as it was 440 times higher than the maximum acceptable concentration of Environmental Quality Standard of the UK for aquatic life in saline waters. Labile concentration predicted very severe enrichment of Cd, Pb, and moderate enrichment of Cu. Modified ecological risk index predicted very high ecological risk in sediments. The δ 18O, δ2H and D-excess values indicate that the lake was mainly recharged by local meteoric water. Enriched values of δ 18O and δ2H suggest a high evaporation of lake water, making lake sediments more enriched with metals. Isotopic and D-excess values of groundwater suggest a quick rainwater recharge to groundwater around the Uchalli Lake. Nitrates isotopes indicate that the rainwater runoff is main source of induction of fertilizers, pesticides and soil bonded metals in the lake system. The lake is recharged by rainwater runoff, from catchment areas, that erode the soil particles and agricultural residual waste dumped in the lake.

Quantifying irrigation uptake in olive trees: a proof-of-concept approach combining isotope tracing and Hydrus-1D

ABSTRACT An isotope-enabled module of Hydrus-1D was applied to a potted olive tree to trace water parcels originating from 26 irrigation events in a glasshouse experiment. The soil hydraulic parameters were optimized via inverse modelling by minimizing the discrepancies between observed and simulated soil water content and soil water isotope (18O) values at three soil depths. The model’s performance was validated with observed sap flow z-scores and xylem water 18O. We quantified the source and transit time of irrigation water by analysing the mass breakthrough curves derived from a virtual tracer injection experiment. On average, 26% of irrigation water was removed by plant transpiration with a mean transit time of 94 hours. Our proof of concept work suggests that transit time may represent a functional indicator for the uptake of irrigation water in agricultural ecosystems.

The Ediacaran metamorphosed banded iron formation (BIF) at Gohar Zamin mine (Gol-e-Gohar #3 anomaly), Sirjan (southeastern Iran): Perspective from ore structures, bulk ore-rock geochemistry and O-S-Pb isotopic signatures

Little is known about the occurrence of the Neoproterozoic banded iron formations (BIFs), except few cases of the glaciogenic Cryogenian BIFs. In this investigation, we describe an Ediacaran metamorphosed BIF interbedded with metamorphosed rocks. The Gohar Zamin iron deposit (643 Mt @ 54.3 % Fe, 2.04 % S, 0.12 % P) is hosted by mica schist, quartz schist and meta-basite that formed by metamorphism of the Fe-oxy-hydroxides, terrigenous (pelitic)-chemical (carbonate) sediments, silica gel and repeated phases of MORB-type submarine basic eruptions in shallow marine syn-rift basins. The sediments, basaltic eruptions and iron oxides were lithified to BIFs and then metamorphosed to greenschist facies during Cimmerian orogeny. The presence of macro-meso-microbandings in BIFs, coarse-grained quartz dropstones and magnetite clasts in the ores-host rocks, chemical index of alteration (CIA) (41.83 to 95.42 %) and positive correlation of Al2O3 against TiO2 and SiO2 values suggests a possible syn-glaciogenic BIF deposition. Fe/Ti-Al (Al + Fe + Mn), Fe-P, Co-Ni, V-Ti, V-Ni and Ni/ (Cr + Mn)-Ti + V diagrams suggest similarity to BIFs rather than the I-type granitoid magmatic-hydrothermal-skarn iron ores. REE + Y patterns display LREE depletion to slight enrichment, low-moderate Y/Ho ratios, HREE flat patterns, a nearly-zero to a seawater-like negative Ce anomaly and negative Eu anomaly. Such signatures may reflect low-T (300–200 °C) hydrothermal fluids for the origin of Fe-oxy-hydroxides formed by seawater-basaltic interaction and syn-glaciogenic meltwater influxes. Delta 18O values in magnetite-hematite (+3.3 to + 9.5 ‰) are in equilibrium with seawater and global BIFs. Delta 34S values in pyrite (+21.51 to + 26.59 ‰) reflect similarity to the Ediacaran pyrite composition formed by both thermal sulfate reduction (TSR) and bacterial sulfate reduction (BSR) processes. The radiogenic ratios of 206Pb/204Pb (19.228–25.105), 207Pb/204Pb (15.50–16.158) and 208Pb/204Pb (38.526–39.895) plot on the right side of 0.0 Ga geochron and were probably originated from the highly radiogenic zircon or galena clasts deposited by glaciogenic deposits. Geochemostratigraphy records zigzag elemental halos with the highest values of Fe (59.08 wt%) and Au (49.9 ppb). Exploration guides may be oriented to surficial sampling of the gossanized outcrops and heavy mineral surveys in drainage crosscutting the schistose rocks.

In Situ Trace Element and Fe-O Isotope Studies on Magnetite of the Iron-Oxide Ores from the Takab Region, North Western Iran: Implications for Ore Genesis

The early Cambrian Takab iron ore deposit is situated in the northern part of the Sanandaj-Sirjan zone, western Iran. It consists of banded, nodular and disseminated magnetite hosted in folded micaschists. Trace element and Fe and O isotopic experiments reveal various hydrothermal precipitation environments under reduced to slightly oxidizing conditions. Disseminated magnetite has high Ti (945–1940 ppm) positively correlated with Mg + Al + Si, and heavy Fe (+0.76 to +1.86‰) and O (+1.0 to +4.07‰) isotopic compositions that support a magmatic/high-T hydrothermal origin. Banded magnetite has low Ti (15−200 ppm), V (≤100 ppm), Si and Mg (mostly ≤300 ppm) and variable Al. The ∂56Fe values vary from −0.2‰ to +1.12‰ but most values also support a magmatic/high-T hydrothermal origin. However, variable ∂18O (−2.52 to +1.22‰) values provide evidence of re-equilibration with lower-T fluid at ~200–300 °C. Nodular magnetite shows high Mn (≤1%), and mostly negative ∂56Fe values (average, −0.3‰) indicative of precipitation from an isotopically light hydrothermal fluid. Re-equilibration with carbonated rocks/fluids likely results in a negative Ce anomaly and higher ∂18O (average, +6.30‰). The Takab iron ore deposit has, thus, experienced a complex hydrothermal history.

In‐Situ and Triple Oxygen Isotope Characterization of Seafloor Drilled Cherts: Marine Diagenesis and Its Bearing on Seawater Reconstructions

AbstractCherts are used to reconstruct the evolution of seawater δ18O and temperature over geological time. However, given the influence of marine diagenesis, reconstructing seawater from the isotope composition of cherts is not straightforward, resulting in ambiguity of interpretation. Here, we present a detailed isotope and petrographic investigation of deep‐sea drilled 135–40 Ma cherts with focus on the effects of marine diagenesis. We combined triple O‐isotope data with in‐situ δ′18O‐16OH/16O measurements using secondary ion mass spectrometry (SIMS). We also provide electron microprobe maps, traditional δ′18O measurements from petrographically diverse domains, and δD and H2O wt.% values. The bulk δ′18O values range between 29‰ and 38‰ in our collection, while SIMS δ′18O data reveal significant intra‐sample heterogeneities up to 6‰ related to distinct petrographic features (e.g., filled radiolarian tests) and to micrometer‐scale variations in silica forms. Further, the δ′18O—Δ′17O values of these seafloor‐drilled cherts plot near and under equilibrium curve. Both triple‐O and SIMS δ′18O results reflect diagenesis in presence of marine pore waters at temperatures higher than ambient seawater, which is especially appreciable in cherts deposited on young oceanic crust. Despite the relatively constant δ18O seawater values over last 135 Ma, the marine silica spanning between 0 and 135 Ma occupies a wide compositional space in the δ′18O—Δ′17O rather than an equilibrium curve. The δ′18O values of cherts from modern‐seafloor positively correlate with the oceanic crustal age at the time of deposition, hinting at the importance of the heat flux in the diagenetic recrystallization of marine silica.

The Stable Isotopes Approach as Tracers to Investigate the Origin of Groundwater In The Unconfined Aquifer of Denpasar, Bali

Groundwater plays an elemental role in the supply of water for numerous purposes, so the use of groundwater must also pay attention to the balance and preservation of the resource itself. Knowing the origin of the groundwater and the recharge area on an aquifer is essential to determine the conservation model. The purpose of this research is to determine the Denpasar Meteoric Water Line (DMWL), the recharge area, and the origin of groundwater in the unconfined aquifer of Denpasar. The determination of the number and location of samples, both rainwater samples, and groundwater samples, using a purposive sampling approach. A total of 5 samples of rainwater and 18 samples of groundwater were taken at several locations in the Denpasar area. The stable isotopes of δ18O and δ2H were carried out using laser spectrometry Picarro L2130-i. This research shows the Denpasar LMWL is δD = 8.5839 x δ18O + 19.876; from the distribution of oxygen-18 isotope, the low 18O value is dominated in the North and Northeast areas, so here this area can be delineated as the potential recharge area; and based on the isotope ratio, groundwater in the unconfined aquifer of Denpasar can be divided into three geneses groups: (a) Groundwater Genesis-A and B groups represent groundwater systems that come from direct rainfall as well as local recharge with low (depleted) to moderate δ18O and δ2H isotope ratios and groundwater groups Genesis-C, which has high (enriched) δ18O and δ2H isotope ratios, is located below the slope of the DMWL.

Variance of Carotid-Rete-Mediated Selective Brain Cooling Across Aridity Indices

Species-environment interactions are integral to survivorship, especially when those environments test the extremes of organismal physiology. Large-bodied (>50kg) mammals, specifically artiodactyls and feliform carnivores, possess a specialized physiology known as carotid-rete-mediated selective brain cooling (CR-SBC), which has been established to be selectively advantageous in environments where water availability is limited and risk for dehydration is high. In this study, we investigate whether CR-SBC provides a release from physiological constraint imposed by the environment, specifically aridity. Using 18O values from tooth enamel as a proxy for water metabolism, we model the range in variance across 1265 individuals from species that possess a carotid rete against those without from three different environmental categories – arid, dry subhumid, and humid – using a non-parametric ANOVA. The results of the analysis indicate there is a comparatively higher, and statistically significant, amount of variance of 18O in mammals possessing CR-SBC than those without, especially within arid climates, that begins to equalize as environmental water availability increases. As environments become increasingly arid, understanding which species are more vulnerable to shifts in climate becomes more pertinent. The presence of CR-SBC provides a clear, binary feature by which to measure the relationship between the environment and species survivorship under varying levels of water availability, and is useful in informing and improving conservation tools, such as physiological distribution models.

Hydrochemistry and stable isotopes revealed focused and diffuse recharge processes in the Sonora River basin, Mexico

ABSTRACT A hydro-geochemical characterization was conducted in the northern part of the Sonora River basin, covering an area of 9400 km2. Equipotential lines indicated that groundwater circulation coincided with the surface water flow direction. Based on the groundwater temperature measured (on average ∼21 °C), only one spring exhibited thermalism (51 °C). Electrical conductivity (160–1750 μS/cm), chloride and nitrate concentrations (>10 and >45 mg/L) imply highly ionized water and anthropogenic pollution. In the river network, δ 18O values revealed a clear modern meteoric origin. Focused recharge occurred mainly from the riverbeds during the rainy season. During the dry season, diffuse recharge was characterized by complex return flows from irrigation, urban, agricultural, mining, and livestock. Drilled wells (>50 m) exhibited a strong meteoric origin from higher elevations during the rainy season with minimal hydrochemical anomalies. Our results contribute to the knowledge of mountain-front and mountain-block recharge processes in a semi-arid and human-altered landscape in northern Mexico, historically characterized by limited hydrogeological data.