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Natural aging mechanism of buried polyethylene pipelines during long-term service

Currently, accelerated aging tests are widely used to study the aging process of polyethylene pipelines. However, this approach can only simulate one or several main influencing factors in the natural environment, which are often quite different from the actual environment of the buried pipelines. In this study, five types of PE80 buried pipelines in service for 9–18 years were taken as the research object, while new PE80 pipelines were taken as the reference group. The aging process and mechanism of polyethylene buried pipelines were studied through mechanical and chemical property tests and microstructural analysis. The results showed that the pipeline exhibited cross-linking as the main aging mechanism after being in service for 0–18 years. The aging degree and law of the inner and outer surface of the pipeline were compared, and the observed mechanism of both surfaces was explained. After 18 years in service, the elongation at the break of the pipe decreased by 16.2%, and the toughness of the matrix in the main collapse area of the tensile sample was the fundamental reason responsible for changes in the mechanical properties. Finally, after 18 years in service, the oxidation induction time of the pipeline was 25.7 min, which was 28.5% higher than the national standard value. There were no potential safety hazards during continuous long-term service. The results of this paper provide reference data and theoretical guidance for the aging process study of buried polyethylene pipelines.

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Open Access
Parameter Optimization and Experiment of a Seed Furrow Cleaning Device for No-Till Maize Seeding

To avoid the issues of seeds lying atop straw, where the seeds cannot germinate, during no-till maize seeding, a seed furrow cleaning device is proposed. The device uses rotating spring teeth and a curved sliding shovel to clear the straw from the seed furrow to the outside. The critical components of the side throwing mechanism, rotary disc and spring teeth design are analyzed, and the value range of the installation inclination angle, rotating speed and bending angle of spring teeth are determined. The force on the straw at the moment of starting to touch and throw it is analyzed theoretically in the three installation directions of forward inclination, radial and backward inclination on the rotary disc, and the backward inclination of the spring teeth is determined. A simulation model of the seed furrow cleaning device is established by using the discrete element method simulation software; the forwarding speed, rotating speed, installation inclination angle, and bending angle of spring teeth are used as influencing factors to carry out single-factor experiments. The influence characteristics of different parameters on seed ditch cleaning effect are analyzed from the aspects of straw cleaning quantity and soil disturbance. A field validation experiment is carried out, and the results show that when rotating speed is 180 r/min, installation inclination angle of spring teeth is 40°, and bending angle is 30°, the straw cleaning rate is 82.26%. The research could provide references to develop the no-till seeder for maize seeding.

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Bio-compatible n-HAPs/polymer monolithic composites templated from CO2-in-water high internal phase emulsions

According to the applications of materials in food and biology etc. fields, the open-cell macroporous polymer composite must contain a non-toxic component, and be bio-compatible, and the preparation processes should be green and facile. Herein, bio-compatible macro-porous nano-hydroxyapatite particles (n-HAPs)/polymer monolithic composites were templated from green and facile CO2-in-Water high internal phase emulsion (C/W HIPE). The bio-active n-HAPs that acted as emulsifiers were incorporated, which enable the well-dispersion of functional fillers in these monolithic composites. Green and facile C/W HIPE templating combined with radical polymerization of bio-compatible monomers involves nontoxic chemicals, and produced polymer monolith with macro-porous open-cell structure (80–120 μm in pore size, 20–40 μm in pore-throat size), and enable the n-HAPs/polymer improved flexibility and mechanical performance (above 80% compression strain, > 400 kPa of compression strength). Results of bio-compatibility tests show that these n-HAPs/polymer monoliths have non-cytotoxicity on HepG2 cells; Furthermore, the immobilization of pectinase by the composite indicates that composites have physical adsorption of pectinase, and the introduction of n-HAPs is more conducive to the immobilization of pectinase and the improvement and maintenance of enzyme activity; after reusing the immobilized pectinase 10 times, the relative catalytic activity can still be above 85%. Therefore, this kind of porous composite has promising potential in applications of bio-tissue engineering, food, and pharmaceutical.

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