Well-to-wheels energy use and greenhouse gas emissions of ethanol from corn, sugarcane and cellulosic biomass for US use

Land management practices such as cover crop adoption or manure application that can increase soil organic carbon (SOC) may provide a way to counter SOC loss upon removal of stover from corn fields for use as a biofuel feedstock. This report documents the data, methodology, and assumptions behind the incorporation of land management practices into corn-soybean systems that dominate U.S. grain production using varying levels of stover removal in the GREETTM (Greenhouse gases, Regulated Emissions, and Energy use in Transportation) model and its CCLUB (Carbon Calculator for Land Use change from Biofuels production) module. Tillage (i.e., conventional, reduced and no tillage), corn stover removal (i.e., at 0, 30% and 60% removal rate), and organic matter input techniques (i.e., cover crop and manure application) are included in the analysis as major land management practices. Soil carbon changes associated with land management changes were modeled with a surrogate CENTURY model. The resulting SOC changes were incorporated into CCLUB while GREET was expanded to include energy and material consumption associated with cover crop adoption and manure application. Life-cycle greenhouse gas (GHG) emissions of stover ethanol were estimated using a marginal approach (all burdens and benefits assigned to corn stover ethanol) and an energy allocation approach (burdens and benefits divided between grain and stover ethanol). In the latter case, we considered corn grain and corn stover ethanol to be produced at an integrated facility. Life-cycle GHG emissions of corn stover ethanol are dependent upon the analysis approach selected (marginal versus allocation) and the land management techniques applied. The expansion of CCLUB and GREET to accommodate land management techniques can produce a wide range of results because users can select from multiple scenario options such as choosing tillage levels, stover removal rates, and whether crop yields increase annually or remain constant. In a scenario with conventional tillage and a 30% stover removal rate, life-cycle GHG emissions for a combined gallon of corn grain and stover ethanol without cover crop adoption or manure application are 49 g CO2eq MJ-1, in comparison with 91 g CO2eq MJ-1 for petroleum gasoline. Adopting a cover crop or applying manure reduces the former ethanol life-cycle GHG emissions by 8% and 10%, respectively. We considered two different life cycle analysis approaches to develop estimates of life-cycle GHG emissions for corn stover ethanol, marginal analysis and energy allocation. In the same scenario, this fuel has GHG emissions of 12 – 20 g CO2eq MJ-1 (for manure and cover crop application, respectively) and 45 – 48 g CO2eq MJ-1 with the marginal approach and the energy allocation approach, respectively.

Aluminum production is a major energy consumer and important source of greenhouse gas (GHG) emissions globally. Estimation of the energy consumption and GHG emissions caused by aluminum production in China has attracted widespread attention because China produces more than half of the global aluminum. This paper conducted life cycle (LC) energy consumption and GHG emissions analysis of primary and recycled aluminum in China for the year 2020, considering the provincial differences on both the scale of self-generated electricity consumed in primary aluminum production and the generation source of grid electricity. Potentials for energy saving and GHG emissions reductions were also investigated. The results indicate that there are 157,207 MJ of primary fossil energy (PE) consumption and 15,947 kg CO2-eq of GHG emissions per ton of primary aluminum ingot production in China, with the LC GHG emissions as high as 1.5–3.5 times that of developed economies. The LC PE consumption and GHG emissions of recycled aluminum are very low, only 7.5% and 5.3% that of primary aluminum, respectively. Provincial-level results indicate that the LC PE and GHG emissions intensities of primary aluminum in the main production areas are generally higher while those of recycled aluminum are lower in the main production areas. LC PE consumption and GHG emissions can be significantly reduced by decreasing electricity consumption, self-generated electricity management, low-carbon grid electricity development, and industrial relocation. Based on this study, policy suggestions for China’s aluminum industry are proposed. Recycled aluminum industry development, restriction of self-generated electricity, low-carbon electricity utilization, and industrial relocation should be promoted as they are highly helpful for reducing the LC PE consumption and GHG emissions of the aluminum industry. In addition, it is recommended that the central government considers the differences among provinces when designing and implementing policies.

Impacts of pre-treatment technologies and co-products on greenhouse gas emissions and energy use of lignocellulosic ethanol production

Reducing life cycle greenhouse gas emissions of corn ethanol by integrating biomass to produce heat and power at ethanol plants

BackgroundThe availability of feedstock options is a key to meeting the volumetric requirement of 136.3 billion liters of renewable fuels per year beginning in 2022, as required in the US 2007 Energy Independence and Security Act. Life-cycle greenhouse gas (GHG) emissions of sorghum-based ethanol need to be assessed for sorghum to play a role in meeting that requirement.ResultsMultiple sorghum-based ethanol production pathways show diverse well-to-wheels (WTW) energy use and GHG emissions due to differences in energy use and fertilizer use intensity associated with sorghum growth and differences in the ethanol conversion processes. All sorghum-based ethanol pathways can achieve significant fossil energy savings. Relative to GHG emissions from conventional gasoline, grain sorghum-based ethanol can reduce WTW GHG emissions by 35% or 23%, respectively, when wet or dried distillers grains with solubles (DGS) is the co-product and fossil natural gas (FNG) is consumed as the process fuel. The reduction increased to 56% or 55%, respectively, for wet or dried DGS co-production when renewable natural gas (RNG) from anaerobic digestion of animal waste is used as the process fuel. These results do not include land-use change (LUC) GHG emissions, which we take as negligible. If LUC GHG emissions for grain sorghum ethanol as estimated by the US Environmental Protection Agency (EPA) are included (26 g CO2e/MJ), these reductions when wet DGS is co-produced decrease to 7% or 29% when FNG or RNG is used as the process fuel. Sweet sorghum-based ethanol can reduce GHG emissions by 71% or 72% without or with use of co-produced vinasse as farm fertilizer, respectively, in ethanol plants using only sugar juice to produce ethanol. If both sugar and cellulosic bagasse were used in the future for ethanol production, an ethanol plant with a combined heat and power (CHP) system that supplies all process energy can achieve a GHG emission reduction of 70% or 72%, respectively, without or with vinasse fertigation. Forage sorghum-based ethanol can achieve a 49% WTW GHG emission reduction when ethanol plants meet process energy demands with CHP. In the case of forage sorghum and an integrated sweet sorghum pathway, the use of a portion of feedstock to fuel CHP systems significantly reduces fossil fuel consumption and GHG emissions.ConclusionsThis study provides new insight into life-cycle energy use and GHG emissions of multiple sorghum-based ethanol production pathways in the US. Our results show that adding sorghum feedstocks to the existing options for ethanol production could help in meeting the requirements for volumes of renewable, advanced and cellulosic bioethanol production in the US required by the EPA’s Renewable Fuel Standard program.

The decarbonization of regional electricity systems is a critical enabler of broader economy-wide decarbonization strategies and has motivated robust research on how to decarbonize electricity systems at minimum monetary cost. Since these efforts often focus on the operation of electricity systems, however, they do not account for emissions of the full life cycle associated with different resources. Different resource mixes can achieve a similar level of apparent decarbonization through operational emissions, while achieving very different levels of life cycle greenhouse gas (GHG) emissions reductions. To explore these differences, we model the expansion of the California electricity system from 2030 to 2045 using a simplified electricity dispatch model to investigate how the planning of future electricity systems may differ between prioritizing minimum cost versus minimum life cycle GHG emissions under a common target for operational GHG reductions. We find that explicitly planning for minimum life cycle GHG emissions yields an additional 1.6%–2.0% reduction in annual life cycle GHG emissions at a cost penalty of 5.1%–6.9% and that electricity resource mixes that minimize life cycle GHG emissions tend to favor high capacity factor zero-carbon resources and long-duration storage compared to a minimum cost approach. Comparatively, we find that aggressive supply chain decarbonization of generation and storage technologies reduces life cycle GHG emissions of electricity supplies by 3.0% to 14% and combining both increases these reductions to 5.0% to 16%. Further, we find that applying a carbon tax to minimum cost-based capacity expansion can incentivize planning to account for life cycle GHG emissions. Our results indicate that a planning approach focused on minimizing life cycle GHG emissions may not be palatable, but significant reductions in life cycle emissions can be realized through conventional mechanisms like carbon taxes, import standards, and targeted supply chain decarbonization.

The decarbonization of regional electricity systems is a critical enabler of broader economy-wide decarbonization strategies and has motivated robust research on how to decarbonize electricity systems at minimum monetary cost. Since these efforts often focus on the operation of electricity systems, however, they do not account for emissions of the full life cycle associated with different resources. Different resource mixes can achieve a similar level of decarbonization apparent decarbonization through operational emissions, while achieving very different levels of life cycle greenhouse gas (GHG) emissions reductions. To explore these differences, we model the expansion of the California electricity system from 2030 to 2045 using a simplified electricity dispatch model to investigate how the planning of future electricity systems may differ between prioritizing minimum cost versus minimum life cycle GHG emissions under a common target for operational GHG reductions. We find that explicitly planning for minimum life cycle GHG emissions yields an additional 1.6-2.0% reduction in annual life cycle GHG emissions at a cost penalty of 3.2–9.6% and that electricity resource mixes that minimize life cycle GHG emissions tend to favor high capacity factor zero-carbon resources and long-duration storage compared to a minimum cost approach. Comparatively, we find that aggressive supply chain decarbonization of generation and storage technologies reduces life cycle GHG emissions of electricity supplies by 3.0% to 14% and combining both increases these reductions to 5.0% to 16%. Further, we find that applying a carbon tax to minimum cost-based capacity expansion can incentivize planning to account for life cycle GHG emissions. Our results indicate that a planning approach focused on minimizing life cycle GHG emissions may not be palatable, but significant reductions in life cycle emissions can be realized through conventional mechanisms like carbon taxes, import standards, and targeted supply chain decarbonization.

Introducing demand to supply ratio as a new metric for understanding life cycle greenhouse gas (GHG) emissions from rainwater harvesting systems

Impacts of alternative fuel combustion in cement manufacturing: Life cycle greenhouse gas, biogenic carbon, and criteria air contaminant emissions

The climate impact assessment of vehicle/fuel systems may be incomplete without considering short-lived climate forcers of black carbon (BC) and primary organic carbon (POC). We quantified life-cycle BC and POC emissions of a large variety of vehicle/fuel systems with an expanded Greenhouse gases, Regulated Emissions, and Energy use in Transportation model developed at Argonne National Laboratory. Life-cycle BC and POC emissions have small impacts on life-cycle greenhouse gas (GHG) emissions of gasoline, diesel, and other fuel vehicles, but would add 34, 16, and 16 g CO2 equivalent (CO2e)/mile, or 125, 56, and 56 g CO2e/mile with the 100 or 20 year Global Warming Potentials of BC and POC emissions, respectively, for vehicles fueled with corn stover-, willow tree-, and Brazilian sugarcane-derived ethanol, mostly due to BC- and POC-intensive biomass-fired boilers in cellulosic and sugarcane ethanol plants for steam and electricity production, biomass open burning in sugarcane fields, and diesel-powered agricultural equipment for biomass feedstock production/harvest. As a result, life-cycle GHG emission reduction potentials of these ethanol types, though still significant, are reduced from those without considering BC and POC emissions. These findings, together with a newly expanded GREET version, help quantify the previously unknown impacts of BC and POC emissions on life-cycle GHG emissions of U.S. vehicle/fuel systems.

Plug-in hybrid electric vehicle (PHEV) technology has the potential to reduce operating cost, greenhouse gas (GHG) emissions, and petroleum consumption in the transportation sector. However, the net effects of PHEVs depend critically on vehicle design, battery technology, and charging frequency. To examine these implications, we develop an optimization model integrating vehicle physics simulation, battery degradation data, and U.S. driving data. The model identifies optimal vehicle designs and allocation of vehicles to drivers for minimum net life cycle cost, GHG emissions, and petroleum consumption under a range of scenarios. We compare conventional and hybrid electric vehicles (HEVs) to PHEVs with equivalent size and performance (similar to a Toyota Prius) under urban driving conditions. We find that while PHEVs with large battery packs minimize petroleum consumption, a mix of PHEVs with packs sized for ∼25–50 miles of electric travel under the average U.S. grid mix (or ∼35–60 miles under decarbonized grid scenarios) produces the greatest reduction in life cycle GHG emissions. Life cycle cost and GHG emissions are minimized using high battery swing and replacing batteries as needed, rather than designing underutilized capacity into the vehicle with corresponding production, weight, and cost implications. At 2008 average U.S. energy prices, Li-ion battery pack costs must fall below $590/kW h at a 5% discount rate or below $410/kW h at a 10% rate for PHEVs to be cost competitive with HEVs. Carbon allowance prices offer little leverage for improving cost competitiveness of PHEVs. PHEV life cycle costs must fall to within a few percent of HEVs in order to offer a cost-effective approach to GHG reduction.

Improving energy and GHG performance of the rice-wheat rotation system: A life-cycle analysis based on a large-scale behavior investigation

A life-cycle assessment (LCA) of corn ethanol was conducted to determine the reduction in the life-cycle greenhouse gas (GHG) emissions of corn ethanol compared to gasoline by integrating biomass fuels in a 190 million liter (50 million gallon) per year dry-grind corn ethanol plant to replace fossil fuels (natural gas and grid electricity). The biomass fuels studied are corn stover and ethanol co-products [dried distillers grains with solubles (DDGS), and syrup (solubles portion of DDGS)]. The biomass conversion technologies/systems considered are process heat (PH) only systems, combined heat and power (CHP) systems, and biomass integrated gasification combined cycle (BIGCC) systems. The key inventory components of the LCA are corn production, stover production, ethanol production, fertilizer inputs, truck transport, co-product credits, ethanol transport to blending, biomass fuel conversion systems, and combustion of anhydrous ethanol (E100). The life-cycle GHG emission reduction for corn ethanol compared to gasoline (97.7 g CO2e/MJ gasoline) is 42.5% for PH with natural gas, 61.3% for PH with corn stover, 82.2% for CHP with corn stover, 81.6% for IGCC with natural gas, 127.7% for BIGCC with corn stover, and 119.1% for BIGCC with syrup and stover. These GHG emission estimates do not include indirect land use change effects. GHG emission reductions for CHP, IGCC, and BIGCC include power sent to the grid which replaces electricity from coal. BIGCC results in greater reductions in GHG emissions than IGCC with natural gas because biomass is substituted for fossil fuels. In addition, underground sequestration of CO2 gas from the ethanol plant’s fermentation tank could further reduce the life-cycle GHG emission of corn ethanol by 31.5% compared to gasoline.

A probabilistic fleet analysis for energy consumption, life cycle cost and greenhouse gas emissions modelling of bus technologies

Exploring impacts of process technology development and regional factors on life cycle greenhouse gas emissions of corn stover ethanol