Abstract
Voltammetric studies at a channel electrode irradiated with monochromatic visible light have been carried out to demonstrate that the photolysis of fac-Mo(CO)3{η3-[(Ph2PCH2CH2)2PPh]} in acetonitrile or dimethylformamide solution leads to the formation of the corresponding mer-isomer. No photofragmentation resulting in the loss of carbon monoxide or phosphine is observed on the voltammetric timescale. Kinetic parameters for the photo-isomerisation are reported.
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Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
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