Abstract
Infrared spectra of gaseous MoF6 and TcF6 from 6–43 μ, the Raman spectrum of MoF6 gas, and an incomplete Raman spectrum of liquid TcF6 are reported. These are interpreted in terms of the octahedral point group 0h. The fundamental frequencies for MoF6 are 741(ν1), 643(ν2), 741(ν3), 264(ν4), 306(ν5), and 190(ν6). For TcF6 they are 705(ν1), 551(ν2), 748(ν3), 265(ν4), 255(ν5) and ν6 has not been determined. Differences between the spectra of MoF6 and TcF6 are explained as a consequence of orbital degeneracy in the ground state of the latter, in analogy with similar differences in the 5d series.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.