Abstract

Apparent mol. wts have been determined for a number of lithium and sodium salts in acetone and in tetrahydrofuran solutions in the 0·01–0·15 M concentration range. The degrees of association have been estimated from the data and are found to be strongly solvent and anion dependent. In acetone solutions, tetraphenylborates show nearly complete dissociation while thiocyanates, bromides and especially chlorides are strongly associated. In tetrahydrofuran solution all salts are strongly associated into ion pairs and for the chloride and the thiocyanate, to higher ionic aggregates.'

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