Abstract
The u.v. spectra of a series of alkyl benzyl sulphides are consistent with the presence of a band which arises from mixed charge-transfer and locally excited states of very weakly π-conjugated sulphide and aryl groups. The u.v. spectra of alkyl aryl sulphides (including thioanisole) are consistent with the presence of one preferred conformation in which the alkylthio group is partially twisted out of plane of the aryl ring. p–π Overlap is sufficiently reduced to allow d-orbital participation to be detected.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
