Abstract

We report here measurements of two-body associative-ionization collisions between sodium atoms confined in a magneto-optic trap. These collisions represent a kind of ``open'' or dissipative collision for which the energy of the atom plus applied light field subsystem need not be conserved due to spontaneous-emission coupling to the vacuum modes of the radiation field. The experiment measures the photoassociative-ionization-rate constant as a function of the optical field intensity from about 40 to 260 mW ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}2}$. These results are in reasonable agreement with the predictions of an optical-Bloch-equation theory [Y. B. Band and P. S. Julienne, Phys. Rev. A 46, 330 (1992)], but differ strongly from the predictions of a local-equilibrium theory [A. Gallagher, Phys. Rev. A 44, 4249 (1991)].

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