Abstract

Up to now, the synthetic development of metal-organic frameworks (MOFs) continues to attract much attention because of their intriguing structural topologies and potential applications. Herein, two anionic low-connectivity microporous indium-organic framework materials (named complex 1 and complex 2) have been solvothermally synthesized, which were further characterized by single-crystal X-ray diffraction, powder X-ray diffraction (PXRD), elemental analysis, thermogravimetric analysis (TGA), and gas sorption in detail. In addition, complex 1 exhibits high selectivity adsorption of CO2 over CH4 at ambient conditions.

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