Abstract
Two new complexes {Ag2(TPBT)(NO3)2}n (1) and Ag2(TPBT)4 (ClO4)2 (2) were constructed by the reaction of tripodal connector 1,3,5-[(2-pyridyl)-1H-benzoimidazol- 1-methyl)-2,4,6-trimethylbenzene (TPBT) and corresponding silver salts under solvothermal conditions. The synergistic effect of the flexible tripodal ligand and anions has led to different complexes 1 and 2. Complex 1 is a 2D layer with the binuclear units with the Ag···Ag distance of 2.9054 Å, whereas 2 is a binuclear motif with Ag···Ag separation of 10.526 Å. Both 1 and 2 are further extended into 3D supramolecular architectures by hydrogen bonds and π···π interactions, which exhibit weak luminescence emission in the solid state at room temperature. Supplementary material is available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
