Abstract
To date, heavy metals and chlorine removal from hazardous waste incineration fly ash (HWI FA) by thermal treatment was scarcely reported. High content of calcium in HWI FA might affect heavy metals chlorination volatilization. The aim of this study was to realize heavy metals and chlorine simultaneous removal from HWI FA triggered by fluidized-bed municipal solid waste incineration fly ash (FBMSWI FA) during sintering. Results showed that the dilemma of low heavy metals removal efficiency was due to the dense structure and the difficulty of transformation of the stable phases including Cu2S, CuSiO3, and Zn2SiO4. By co-sintering with FBMSWI FA at the ratio of 1:1, the removal efficiency of Cu, Zn, Pb, Cd, and Cl reached as high as 84.4%, 92.0%, 99.9%, 99.5%, and 99.7%, respectively. Compared with the control, chlorination volatilization efficiency of Cu and Zn was significantly increased by 210.5% and 89.2%. The favourable promotion could be mainly attributed to Si/Al matrix in FBMSWI FA triggered the following reaction: i) Ca-bearing compounds in HWI FA were activated to destroy the dense structure, which facilitated the transformation of Cu2S to CuO; and ii) the conversion of NaCl and KCl to gaseous chlorine was promoted, which the formation of metal chlorides was accelerated.
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