Abstract
AbstractThe stereoselective total synthesis of oxylipin macrolide (+)‐sacrolide A was achieved in a 13 longest linear step sequence with 12.1 % overall yield. The key reactions are Jacobsen′s hydrolytic kinetic resolution, Sharpless asymmetric epoxidation, Yamaguchi esterification and intramolecular Nozaki–Hiyama–Kishi (NHK) macrocyclization to construct the required 14‐membered lactone.
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