Topological insulator VxBi1.08-Sn0.02Sb0.9Te2S as a promising n-type thermoelectric material

Abstract

As one of the most important n -type thermoelectric (TE) materials, Bi 2 Te 3 has been studied for decades, with efforts to enhance the thermoelectric performance based on element doping, band engineering, etc. In this study, we report a novel bulk-insulating topological material system as a replacement for n -type Bi 2 Te 3 materials: V doped Bi 1.08 Sn 0.02 Sb 0.9 Te 2 S (V:BSSTS). The V:BSSTS is a bulk insulator with robust metallic topological surface states. Furthermore, the bulk band gap can be tuned by the doping level of V, which is verified by magnetotransport measurements. Large linear magnetoresistance is observed in all samples. Excellent thermoelectric performance is obtained in the V:BSSTS samples, e.g., the highest figure of merit ZT of ~ 0.8 is achieved in the 2% V doped sample (denoted as V 0.02 ) at 530 K. The high thermoelectric performance of V:BSSTS can be attributed to two synergistic effects: (1) the low conductive secondary phases Sb 2 S 3 , and V 2 S 3 are believed to be important scattering centers for phonons, leading to lower lattice thermal conductivity; and (2) the electrical conductivity is increased due to the high-mobility topological surface states at the boundaries. In addition, by replacing one third of costly tellurium with abundant, low-cost, and less-toxic sulfur element, the newly produced BSSTS material is inexpensive but still has comparable TE performance to the traditional Bi 2 Te 3 -based materials, which offers a cheaper plan for the electronics and thermoelectric industries. Our results demonstrate that topological materials with unique band structures can provide a new platform in the search for new high performance TE materials. • The high conductive topological surface state of the V:BSSTS samples is considered to be responsible for the good thermoelectric behavior. • Low thermal conductivity: Sb 2 S 3 and V 2 S 3 secondary phases effectively scatter phonons leading to low lattice thermal conductivity. • High ZT throughout the whole temperature range: a ZT max of ~0.8 is achieved in the 2% V doped sample, and the ZT values keep high through the whole temperature range.