Abstract
Rare earth zirconates exhibit potential as thermal barrier coatings, but their limited toughness impedes their widespread use. To address this issue, rare earth aluminates are regarded as effective toughening agents for zirconates. However, the thermal conductivity of composites containing rare earth aluminates and zirconates tends to rise. To mitigate this issue, we have developed a series of Yb2O3-doped GAO-GZO composites. The introduction of Yb2O3 results in the formation of a fluorite phase, with Yb3+ ions occupying Gd sites in both GAO and GZO components. Although the fracture toughness remains relatively unchanged, the hardness of the composite improves. The thermal conductivity decreases with increasing Yb2O3 content due to enhanced phonon-defect scattering. Additionally, the coefficient of thermal expansion is reduced due to the stronger Yb-O bonding compared to Gd-O. This study presents a viable strategy for regulating the mechanical and thermal properties of rare earth zirconates reinforced with aluminates through defect engineering.
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