Three-fold Interpenetrating Diamondoid Frameworks with π–π Stacking of Alternate Coordinated and Uncoordinated Ligands: Crystal Structures of Copper(I) Coordination Compounds, [Cu(DMTPN)2]X(DMTPN)(thf) (DMTPN = 2,5-Dimethylterephthalonitrile; X = BF4,ClO4)

Abstract

Listen

Translate article

Abstract Two novel coordination polymer compounds, [Cu(DMTPN)2]X(DMTPN)(thf) (DMTPN = 2,5-dimethylterephthalonitrile, X = BF4 (l) and ClO4 (2)) are prepared and characterized by single crystal X-ray analysis; both are isostructural and have three-fold interpenetrated diamondoid structure with π–π stacking column of alternate coordinated and uncoordinated DMTPN.