Thermometric titration of the investigation of the formation of polyanions of polyanions of molybdenum(VI), tungsten(VI), vanadium(V) and chromium(VI)—IV Effects of salts on the polymerization of molybdate and the depolymerization of molybdic acid

Nobutoshi Kiba,Tsugio Takeuchi

doi:10.1016/0022-1902(75)80144-8

Thermometric titration of the investigation of the formation of polyanions of polyanions of molybdenum(VI), tungsten(VI), vanadium(V) and chromium(VI)—IV Effects of salts on the polymerization of molybdate and the depolymerization of molybdic acid

Nobutoshi Kiba, Tsugio Takeuchi

https://doi.org/10.1016/0022-1902(75)80144-8

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Journal: Journal of Inorganic and Nuclear Chemistry	Publication Date: Jan 1, 1975
Citations: 3

Affiliation: Nagoya University

#Presence Of Various Salts #Kind Of Salt + Show 6 more

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Abstract

Abstract The polymerization of molybdate and the depolymerization of molybduc acid were investigated in the presence of various salts by the thermometric titration. The infection points of the titration curves could help interpret the mechanism of the process, since the Z-value (H+/Mo) and P-value (OH−/Mo) of the inflection point vary with the amount as well as with the kind of salt. The salt-effect increases in the following order: LiCl

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