Abstract
The rate of the thermal, uncatalysed, [1,3] rearrangement of aromatic O-methyleneamino thiocarbamates to S-methyleneamino thiocarbamates in solution is insensitive to changes in both solvent polarity and substituent on ring and imino-carbon atoms, suggesting a transition state involving little charge separation. The occurrence of rearrangement via a radical pair is suggested by the detection by e.s.r. spectroscopy of aromatic iminyls, generated as transients during rearrangement.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
