Abstract

We report precise measurement of volume changes as function of temperature in the one phase region of methanol + cyclohexane near the critical solution point. We find a value for the critical exponent α of 0.11 ± 0.07 in the region 11 Mk < T – T c < 6.4 K. This value agrees with the Ising value of 1 8 . For temperatures closer to Tc we observe a stronger divergence. In addition we observe unusual behavior over a small region of temperature centered at T – T c = 15 mK.

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