Expansivity of liquid (cyclohexane + acetic anhydride) near its critical solution point

Abstract

A simple volume dilatometer is described for the precise measurements of volume changes as a function of temperature in liquid mixtures. The expansivity of (cyclohexane + acetic anhydride) in the critical region was measured. The critical solution temperature T c was approached to within 9 mK. For T > ( T c + 0.3 K), the results results follow both a logarithmic and a power-law behaviour with an exponent ≈ 1 8 . But for T < ( T c + 0.3 K), the results seem to be affected possibly by gravity or temperature gradients. In this region, the expected expansivity anomaly is rounded off to a cusp. The expansivity shows a reduced anomaly for off-critical compositions. A discussion of the local extremum and a correlation between negative expansivity and the resistivity anomaly are also given.