Abstract
The half-life times for thermal rearrangement of a series of carcinogenic N, O-diacetyl- N-arylhydroxylamines have been studied. The rate of rearrangement within the series correlates with the extent of aryl conjugation and the degree of electron density in the N-aryl-moiety. Comparison between this rearrangement and the ortho- Claisen rearrangement is drawn and some biological implications of the rearrangement reaction are discussed.
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