Abstract

The key role of polymer matrix–nanofiller interface surfaces in determination of the structure and properties of particulate-filled polymer nanocomposites is shown. Aggregation of the initial particles of the nanofiller results in a dramatic decrease in the surface area and can cause a transition of the originally postulated nanocomposite to the class of microcomposites. The suppression of aggregation provides a significant improvement in the characteristics of the polymer nanocomposites.

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