The quantum nature of C-H···metal interaction: vibrational spectra and kinetic and geometric isotope effects of adsorbed cyclohexane.

Abstract

The nature of C-H···M (M = metal surface) interactions is reviewed based mainly on our recent investigations of cyclohexane on Rh(111). Infrared reflection-absorption spectroscopy measurements at low temperature (∼20 K) have shown that the softened CH stretching band consists of several sharp peaks. At temperatures above 80 K, each peak is broadened, most probably by anharmonic coupling with thermally excited low-energy frustrated translational modes. The origin of fine structure in this band and its similarity to that in hydrogen bond systems are discussed. In addition, novel isotope effects were observed in desorption kinetics and adsorption geometry of cyclohexane on Rh(111) using temperature programmed desorption, ultraviolet photoelectron spectroscopy, and spot profile analysis low-energy electron diffraction. The desorption energy of deuterated cyclohexane (C6 D12 ) is lower than that of C6 H12 (inverse kinetic isotope effect). In addition, the work function change by adsorbed C6 D12 is smaller than that by adsorbed C6 H12 . These results indicate that C6 D12 molecules are slightly more distant from the surface than C6 H12 molecules (vertical geometric isotope effect). A lateral geometric isotope effect was also observed for the two-dimensional cyclohexane superstructures as a result of the repulsive interaction between interfacial dipoles (= work function change). These isotope effects are ascribed to the quantum nature of hydrogen involved in the C-H···M interaction.