Abstract
Approximations to exact wave functions for the scattering of few-particle systems often involve components corresponding to the interaction of two of the particles “off the energy-shell”. Several examples arising in the collision of ions and photons with atoms are given. An expansion in partial waves leads to an off-shell radial wave function. The defining differential equation is solved here numerically with particular emphasis on the behaviour arising from two-body potentials of long-range Coulomb form. The transition to shell of the radial wave functions, Jost functions and solutions andT-matrix elements is discussed for both short-range and Coulomb potentials. It is shown that the approximation of a Coulomb potential by a shorter-range form involves little error when sufficiently far off the energy shell.
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