Abstract

Five bound nd 1Δ g ( n = 11-15) electronic states have been investigated using optical-optical double resonance excitation followed by ionization detection using an ultrasensitive space charge limited diode, which detects ion signals (presumably K + 3 produced by associative ionization). The molecular constants and the Rydberg-Klein-Rees potential curves for these states have been generated. The dissociation energies, additional binding energies, and molecular constants due to the weakly bound Rydberg bonding δ g orbitals are discussed.

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