Abstract

The kinetics of the copper(II)/LIX64N system have been studied by a single drop method which highlights the direct dependence of the rate of reaction on interfacial area. The rate of the forward reaction depends on the ratio of the total copper to free proton concentration in the aqueous phase and that of the reverse (stripping) reaction on the product of the copper concentration in the organic phase and the free proton concentration in the aqueous phase. The form of these dependences, however, indicates that a study of the interfacial region is necessary for a detailed understanding of the system.

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