Abstract
A nucleation and growth mechanism of island formation based on the Oppenheim-Levine-Somorjai conjecture, in which the island shape and number are controlled via the adsorption process occurring at the island edges, is given to study the kinetics of the Langmuir-Hinshelwood reaction through Monte Carlo simulation. The calculated thermal programmed reaction (TPR) spectra yield the possibility to analyze (at least qualitatively) the behavior of real systems for which island formation is suspected.
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