Abstract
The infra-red spectra of metal nitrates in tri-n-octyl phosphine oxide solution in carbon tetrachloride and in tri-n-octyl amine nitrate solution in benzene are reported. The splitting of the ν 3 band of the nitrate ion is followed and frequency shifts in the solvent molecule are discussed. A comparison is made with previous measurements in 100 per cent tri-n-butyl phosphate. From the results conclusions are drawn concerning species present in the amine nitrate phase. It is shown that the location of the NO asymmetric and symmetric stretch of the metal nitrate is independent of the solvent, but strongly dependent on the metal ion.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
