Abstract
AbstractThe new technique of differential viscometry measures directly the specific viscosity of a solution by subtracting the contribution of solvent in a balanced capillary bridge. The present work adapts the differential viscometry principle to the design of a viscosity detector for use in size‐exclusion chromatography. It is shown that the resulting viscosity detector possesses excellent sensitivity and baseline stability with a minimum detectable specific viscosity of 2.7 × 10−5. The viscosity detector can be operated together with a refractive index detector to determine the intrinsic viscosity of polymer solute fractions as they elute from the SEC column. The bandspreading of the viscosity detector is compared to the refractive index detector by measuring the peak width of a compound having a single discrete molecular weight. The peak width at half‐height was 0.29 mL for the viscosity detector and 0.25 mL for the refractive index detector.
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