Abstract
The kinetics of hydrolysis of a series of (heteroarylmethyl)triphenylphosphonium bromides (V)—(VIII)[RPPh3Br–(R = 2- or 3-furylmethyl or 2- or 3-thenyl)] which produce triphenylphosphine oxide and the respective methyl-substituted heterocyclic compound, have been studied at different temperatures in aqueous 50% ethanol in the presence of potassium chloride, and the rate data have been compared with those for the hydrolysis of benzyltriphenylphosphonium bromide.
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