Abstract
AbstractPeroxy radicals such as ButOO· add to fullerenes efficiently to form isomerically pure multiadducts, for example, C60(OOBut)6. The fullerene‐ mixed peroxides exhibit rich chemical reactivity. Further transformation of the peroxy groups has resulted in fullereneols, open‐cage fullerenes, aza‐ and oxafullerenes and/or fulleroids. Practical applications such as photoinitiator remain to be explored for these fullerene‐mixed peroxides.
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