The anaerobic corrosion of carbon steel in compacted bentonite exposed to natural Opalinus Clay porewater containing native microbial populations

Abstract

ABSTRACTA long-term in situ corrosion experiment is ongoing in the Mont Terri Underground Research Laboratory in Switzerland to (i) measure the in situ corrosion behaviour of carbon steel in compacted bentonite under simulated repository conditions, (ii) study the effect of the bentonite buffer density on microbial activity and microbially influenced corrosion and (iii) study the effect of welding on the corrosion rate. Carbon steel corrosion coupons, with and without welds, were surrounded by compacted bentonite with a range of dry densities and mounted in modules allowing free exchange with the local anoxic groundwater. After about 20 months of exposure, corrosion coupons and bentonite were sampled. A complex corrosion product was identified, consisting predominantly of magnetite. The bentonite adjacent to the metal was finer grained, more dispersed and enriched in iron. Aerobic, anaerobic and sulphate-reducing bacteria were identified both in the porewater surrounding the modules and in the bentonite.This paper is part of a supplement on the 6th International Workshop on Long-Term Prediction of Corrosion Damage in Nuclear Waste Systems.