Abstract
The cycloaddition reaction between tetracyanoethylene and vinyl alcohol has been studied by means of the MNDO method with CI. Catalytic and solvent effects have been simulated. It has been found that in the gas phase the mechanism is non-concerted with a biradical intermediate. In protic solvents, the intermediate has zwitterionic character and leads to the formation of an acetal.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of the Chemical Society, Perkin Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
